Enhanced Serum Carbon Dioxide Measurements with a Silicone Rubber-Based Carbonate Ion-Selective Electrode and a High-pH Dilution Buffer

1996 ◽  
Vol 68 (1) ◽  
pp. 221-225 ◽  
Author(s):  
Jae Ho Shin ◽  
Dong Sik Sakong ◽  
Hakhyun Nam ◽  
Geun Sig Cha
2004 ◽  
Vol 48 (3) ◽  
pp. 266-272
Author(s):  
Mi-Kyoung Kim ◽  
In-Jun Yoon ◽  
Sung-Ho Cho ◽  
Hye-Ra Shin ◽  
Jong-Ho Han ◽  
...  

Chemosensors ◽  
2021 ◽  
Vol 9 (8) ◽  
pp. 236
Author(s):  
Chuqing Zhang ◽  
Yang He ◽  
Jianbo Wu ◽  
Manqing Ai ◽  
Wei Cai ◽  
...  

Real-time measurements of carbonate ion concentrations in the ocean are critical to advancing marine environmental monitoring and research into deep-sea hydrothermal activity. Herein, we report the first example of deep-sea hydrothermal field exploration using a carbonate ion-selective electrode (ISE). The novel carbonate ISE was composed of a Ni wire as substrate, carbon film as transducers and carbonate-selective membrane layers. This paper describes the preparation process of the electrode and characterises its performance via scanning electron microscopy (SEM) and electrochemical analysis. The detection limit of the electrode for CO32− is 2.821 × 10−6 mol/L, the linear response range is 1.0 × 10−5–1.0 × 10−1 mol/L and the Nernst slope was −30.4 mV/decade. In April 2021, the carbonate ISE was mounted on multi-parameter sensors with pH and Eh (redox) electrodes for the search of hydrothermal activity at the Southwest Indian Ridge. The simultaneous potential anomalies appeared at this carbonate electrode with the pH and Eh electrodes when passing through the hydrothermal field. The study of the hydrothermal field was supported by the in situ camera video and the sulphide samples. Additionally, the carbonate electrode provides enhanced information of water chemistry for the study of the hydrothermal field.


2003 ◽  
Vol 18 (2-3) ◽  
pp. 245-253 ◽  
Author(s):  
Johan Bobacka ◽  
Magdalena Maj-Zurawska ◽  
Andrzej Lewenstam

1968 ◽  
Vol 46 (4) ◽  
pp. 481-485 ◽  
Author(s):  
E. B. Tregunna ◽  
E. Ann Thomas

An infrared carbon dioxide analyzer was used to measure the pCO2 of air in equilibrium with seawater. From the pCO2 and pH of the seawater, the amount of bicarbonate plus carbonate ion could be calculated. These values were also obtained by acidifying the seawater and measuring the amount of carbon dioxide that was released. These methods provide accurate measurements of the concentrations of inorganic carbon which are available for photosynthesis by marine plants. For example, these techniques showed that Iridaea cordatum used bicarbonate ion rather than CO2 during photosynthesis at high pH.


1985 ◽  
Vol 31 (3) ◽  
pp. 435-438 ◽  
Author(s):  
R H Ng ◽  
M Altaffer ◽  
R Ito ◽  
B E Statland

Abstract We evaluated the Technicon RA-1000 "random-access" analyzer for the measurements of sodium, potassium, and carbon dioxide by an indirect potentiometric method (ion-selective electrode) and for chloride by a colorimetric method (mercuric thiocyanate). For various concentrations of control materials the total precision (CV) ranged from 0.9 to 1.2% for sodium, 1.1 to 1.3% for potassium, 1.0 to 1.2% for chloride, and 2.8 to 3.8% for carbon dioxide. The system demonstrated acceptable performance in linearity and carryover. Patients' results from the RA-1000 correlated well with those from the Beckman ASTRA-8. In a study on potential interferences, we found that high concentrations of salicylate and bromide significantly affected measurements of carbon dioxide and chloride, respectively. The RA-1000 requires only 30 microL of sample for all four tests and it offers a high throughout (30 specimens analyzed for the four tests in 25 min). This precise, easy-to-use, random-access analyzer requires minimal maintenance.


2016 ◽  
Vol 32 (4) ◽  
pp. 655-660 ◽  
Author(s):  
Yue Zhao ◽  
Chenhua Han ◽  
Yuanfeng Huang ◽  
Wenli Qin ◽  
Xiao Zhang ◽  
...  

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