Second solvation sphere effects on chromium(III) cation exchange processes in water-methanol solvents

1976 ◽  
Vol 48 (2) ◽  
pp. 435-442 ◽  
Author(s):  
Cleon M. Melsa ◽  
Richard J. Baltisberger
2020 ◽  
Vol 272 ◽  
pp. 111082
Author(s):  
Laís G.M. Silva ◽  
Francisca C. Moreira ◽  
Maria Alice P. Cechinel ◽  
Luciana P. Mazur ◽  
Antônio A. Ulson de Souza ◽  
...  

2019 ◽  
Vol 48 (25) ◽  
pp. 9376-9387 ◽  
Author(s):  
Isabel Hanghofer ◽  
Bernhard Gadermaier ◽  
Alexandra Wilkening ◽  
Daniel Rettenwander ◽  
H. Martin R. Wilkening

7Li NMR reveals rapid cation exchange processes in NASICON-type Li1.4Ca0.2Zr1.8(PO4)3 on a local length scale.


2017 ◽  
Vol 33 (2) ◽  
pp. 413-418 ◽  
Author(s):  
Quan-Jun WANG ◽  
◽  
Hong-Juan SUN ◽  
Tong-Jiang PENG ◽  
Ming-Zhu FENG ◽  
...  

2012 ◽  
Vol 46 (17) ◽  
pp. 5472-5482 ◽  
Author(s):  
Mario Schaffer ◽  
Hilmar Börnick ◽  
Karsten Nödler ◽  
Tobias Licha ◽  
Eckhard Worch

1956 ◽  
Vol 13 (3) ◽  
pp. 273-289 ◽  
Author(s):  
Milton Kirsch

The variation in the K+/Na+ and Ca++/Na+ ratios in highly diluted sea waters near the heads of two British Columbia inlets has been determined flame photometrically. Although the values agree in general with those calculated from the effect of dilution, discrepancies larger than the analytical error appear. These discrepancies may be explained by cation exchange processes taking place where the silt suspended in the river meets the sea.


2017 ◽  
Vol 5 (46) ◽  
pp. 24116-24125 ◽  
Author(s):  
Jianmin Chen ◽  
Junying Chen ◽  
Yingwei Li

A novel approach, combining sulfurization and cation-exchange processes, is developed to fabricate hollow ZnCdS rhombic dodecahedral cages from ZIF-8, which exhibit superior catalytic activity and durability for hydrogen evolution from water splitting under cocatalyst-free and visible-light driven conditions.


2021 ◽  
Author(s):  
Hadar Nasi ◽  
Maria Chiara di Gregorio ◽  
Qiang Wen ◽  
Linda J. W. Shimon ◽  
Ifat Kaplan-Ashiri ◽  
...  

Crystals are among the most challenging materials to design, both at the molecular and macroscopic levels. We show here that metal-organic frameworks, based on tetrahedral pyridyl ligands, can be used as a morpho-logical and structural mold to form a series of other isostructural crystals having different metal ions. The cati-on exchange is versatile, based on the use of diverse first-row metals; it occurs with retention of the morpholo-gy. Different morphologies were obtained by a direct reaction between the ligand and metal salts. An iterative crystal-to-crystal conversion has also been demonstrated by two consecutive cation exchange processes. The primary manganese-based crystals have a complex connectivity characterized by a rare space group (P622). The molecular structure generates two types of homochiral channels that span longitudinally the entire hex-agonal prism. These channels mediate the cation exchange, as indicated by energy-dispersive X-ray spectros-copy combined with scanning electron microscopy measurements on microtome-sectioned crystals. The occur-rence of the observed cation exchange is in excellent agreement with the Irving-Williams series (Mn < Fe < Co < Ni < Cu > Zn) that are associated with the relative stability of the resulting coordination nodes. The overall approach allows for the predictability of the structural properties of rare metal-organic frameworks based on tetrahedral pyridyl ligands at different hierarchies: from elemental composition, molecular packing, and mor-phology to the bulk properties.


1990 ◽  
Vol 51 (12) ◽  
pp. 1405-1411 ◽  
Author(s):  
M.A. Hefni ◽  
N. Nagasundaram ◽  
D. Kreszowski ◽  
A.H. Francis

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