Spot Test Detection and Colorimetric Determination of Aromatic Amines and Imino Heteroaromatic Compounds with 3-Methyl-2benzothiazolone Hydrazone

1961 ◽  
Vol 33 (6) ◽  
pp. 722-725 ◽  
Author(s):  
I. R. Cohen ◽  
A. P. Altschuller
1986 ◽  
Vol 22 (4) ◽  
pp. 405-416 ◽  
Author(s):  
Richard A. Glenister ◽  
Thomas A. LaRue

SUMMARYThe ureides allantoic acid and allantoin form a bright pink compound with acidic p-dimethylamino cinnamaldehyde. It is possible to estimate the ureide content of a soyabean petiole segment by crushing it on filter paper and developing the colour with this reagent. There is a strong correlation between the spot test and estimates from colorimetric determination of ureides. In field grown soyabeans, there was a positive correlation between the petiole ureide content during pod fill and the integrated seasonal acetylene reduction activity. The spot test can be used to identify plants with low nitrogen fixation activity.


1983 ◽  
Vol 81 (5-6) ◽  
pp. 301-306 ◽  
Author(s):  
J. A. Vinson ◽  
J. F. Evans ◽  
H. E. Holets

1962 ◽  
Vol 35 (3) ◽  
pp. 676-683 ◽  
Author(s):  
Otto Lorenz ◽  
C. R. Parks

Abstract Three types of p-phenylenediamine derivatives used extensively as antioxidants and antiozonants in rubber compounds are N,N′-di-sec-alkyl-, N-sec-alkyl-N′-aryl-, and N,N′-diaryl-p-phenylenediamines. Available methods for these compounds are based mainly on a colorimetric determination of their colored oxidation products, the Wurster's salts or the p-quinonediimines. The deep coloration of the Wurster's salts was used as the basis of a spot test for the rapid detection of these diamines in rubber compounds. This test permits one to differentiate the three types of p-phenylenediamines. An investigation of the neutralization of p-phenylenediamines in nonaqueous solvents showed that N,N′-di-sec-alkyl- and N-sec-alkyl-N′-aryl-p-phenylenediamines could be determined readily in this way. The N,N′-diaryl derivatives did not give satisfactory titration curves because of their low basicity. By the addition of chloranil, however, diaryl-p-phenylenediamines were oxidized to the Wurster's salts with the formation of one equivalent of base which could be neutralized by acid. A similar procedure was applicable to the determination of N,N′-diaryl-p-quinonediimines, or mixtures of these diamines and diimines.


1959 ◽  
Vol 36 (2) ◽  
pp. 193-201 ◽  
Author(s):  
Julius A. Goldbarg ◽  
Esteban P. Pineda ◽  
Benjamin M. Banks ◽  
Alexander M. Rutenburg

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