scholarly journals A New Approach to Measuring Protein Backbone Protection with High Spatial Resolution Using H/D Exchange and Electron Capture Dissociation

2013 ◽  
Vol 85 (19) ◽  
pp. 9173-9180 ◽  
Author(s):  
Rinat R. Abzalimov ◽  
Cedric E. Bobst ◽  
Igor A. Kaltashov
Keyword(s):  
Electron Capture ◽  
Spatial Resolution ◽  
Electron Capture Dissociation ◽  
High Spatial Resolution ◽  
Protein Backbone ◽  
New Approach

scholarly journals Precipitation Atlas for Germany (GePrA)

Atmosphere ◽  
2019 ◽  
Vol 10 (12) ◽  
pp. 737
Author(s):  
Christopher Jung ◽  
Dirk Schindler
Keyword(s):  
Spatial Resolution ◽  
Large Scale ◽  
High Spatial Resolution ◽  
Spline Interpolation ◽  
Absolute Error ◽  
Coefficient Of Determination ◽  
Small Scale ◽  
Monthly Precipitation ◽  
New Approach ◽  
Very High Spatial Resolution

A new approach for modeling daily precipitation (RR) at very high spatial resolution (25 m × 25 m) was introduced. It was used to develop the Precipitation Atlas for Germany (GePrA). GePrA is based on 2357 RR time series measured in the period 1981–2018. It provides monthly percentiles (p) of the large-scale RR patterns which were mapped by a thin plate spline interpolation (TPS). A least-squares boosting (LSBoost) approach and orographic predictor variables (PV) were applied to integrate the small-scale precipitation variability in GePrA. Then, a Weibull distribution (Wei) was fitted to RRp. It was found that the mean monthly sum of RR ( R R ¯ s u m ) is highest in July (84 mm) and lowest in April (49 mm). A great dependency of RR on the elevation (ε) was found and quantified. Model validation at 425 stations showed a mean coefficient of determination (R2) of 0.80 and a mean absolute error (MAE) of less than 10 mm in all months. The high spatial resolution, including the effects of the local orography, make GePrA a valuable tool for various applications. Since GePrA does not only describe R R ¯ s u m , but also the entire monthly precipitation distributions, the results of this study enable the seasonal differentiation between dry and wet period at small scales.

scholarly journals NanoSIMS imaging: an approach for visualizing and quantifying lipids in cells and tissues

2016 ◽  
Vol 65 (3) ◽  
pp. 669-672 ◽  
Author(s):  
Cuiwen He ◽  
Loren G Fong ◽  
Stephen G Young ◽  
Haibo Jiang
Keyword(s):  
Mass Spectrometry ◽  
Spatial Resolution ◽  
Mass Spectrometry Imaging ◽  
Secondary Ion Mass Spectrometry ◽  
High Spatial Resolution ◽  
High Sensitivity ◽  
New Approach ◽  
The Past ◽  
Secondary Ion ◽  
In Cells

Over the past few decades, several approaches have been used to image lipids in cells and tissues, but most have limited spatial resolution and sensitivity. Here, we discuss a relatively new approach, nanoscale secondary ion mass spectrometry imaging, that makes it possible to visualize lipids in cells and tissues in a quantitative fashion and with high spatial resolution and high sensitivity.

scholarly journals A new approach to accurate validation of remote sensing retrieval of evapotranspiration based on data fusion

2010 ◽  
Vol 7 (2) ◽  
pp. 1745-1784 ◽  
Author(s):  
C. Sun ◽  
D. Jiang ◽  
J. Wang ◽  
Y. Zhu
Keyword(s):  
Remote Sensing ◽  
Data Fusion ◽  
Spatial Resolution ◽  
Hydrological Model ◽  
Assessment Tool ◽  
High Spatial Resolution ◽  
Meteorological Data ◽  
New Method ◽  
Distributed Hydrological Model ◽  
New Approach

Abstract. The study presented a new method of validating the remote-sensing (RS) retrieval of evapotranspiration (ET) under the support of a distributed hydrological model: Soil and Water Assessment Tool (SWAT). In this method, the output runoff data based on a fusion of ET data, meteorological data and rainfall data, etc. were compared with the observed runoff data, so as to carry out validation analysis. A new pattern of validating the ET data obtained from RS retrieval, which was more appropriate than the conventional means of observing the ET at several limited stations based on eddy covariance, was proposed. It has integrated the advantage of high requirement of ET with high spatial resolution in the distributed hydrological model and that of the capacity of providing ET with high spatial resolution in RS methods. First, the ET data in five years (2000–2004) were retrieved with RS according to the principle of energy balance. The temporal/spatial ditribution of monthly ET data and related causes were analyzed in the year of 2000, and the monthly ET in the five years was calculated according to the PM model. Subsequently, the results of the RS retrieval of ET and the PM-based ET calculation were compared and validated. Finnaly, the ET data obtained from RS retrieval was evaluated with the new method, under the support of SWAT, meteorologic data, Digital Elevation Model (DEM), landuse data and soil data, etc. as the input, being compared with the PM-based ET. According to the ET data analysis, it can be inferred that the ET obtained from RS retrieval was more continuous and stable with less saltation, while the PM-based ET presented saltation, especially in the year of 2000 and 2001. The correlation coefficient between the monthly ET in two methods reaches 0.8914, which could be explained by the influence from clouds and the inadequate representativeness of the meteorologic stations. Moreover, the PM-based ET was smaller than the ET obtained from RS retrieval, which was in accordance with previous studies (Jamieson, 1982; Dugas and Ainsworth, 1985; Benson et al., 1992; Pereira and Nova, 1992). After the data fusion, the correlation (R2=0.8516) between the monthly runoff obtained from the simulation based on ET retrieval and the observed data was higher than that (R2=0.8411) between the data obtained from the PM-based ET simulation and the observed data. As for the RMSE, the result (RMSE=26.0860) between the simulated runoff based on ET retrieval and the observed data was also superior to the result (RMSE=35.71904) between the simulated runoff obtained with PM-based ET and the observed data. As for the MBE parameter, the result (MBE=−8.6578) for the RS retrieval method was obviously better than that (MBE=−22.7313) for the PM-based method. The comparison of them showed that the RS retrieval had better adaptivity and higher accuracy than the PM-based method, and the new approach based on data fusion and the distributed hydrological model was feasible, reliable and worth being studied further.

Electron Capture Dissociation Produces Many More Protein Backbone Cleavages Than Collisional and IR Excitation

2000 ◽  
pp. 111-120 ◽  
Author(s):  
Roman A. Zubarev ◽  
Einar K. Fridriksson ◽  
David M. Horn ◽  
Neil L. Kelleher ◽  
Nathan A. Kruger ◽  
...  
Keyword(s):  
Electron Capture ◽  
Electron Capture Dissociation ◽  
Protein Backbone

High spatial resolution AEM observations of yttrium segregation in chromia scales grown on Co-45%Cr

1986 ◽  
Vol 44 ◽  
pp. 518-519
Author(s):  
K. Przybylski ◽  
A. J. Garratt-Reed ◽  
G. J. Yurek
Keyword(s):  
Spatial Resolution ◽  
Outer Surface ◽  
Maximum Concentration ◽  
High Spatial Resolution ◽  
Reactive Elements ◽  
Chromia Scales

The addition of so-called “reactive” elements such as yttrium to alloys is known to enhance the protective nature of Cr2O3 or Al2O3 scales. However, the mechanism by which this enhancement is achieved remains unclear. An A.E.M. study has been performed of scales grown at 1000°C for 25 hr. in pure O2 on Co-45%Cr implanted at 70 keV with 2x1016 atoms/cm2 of yttrium. In the unoxidized alloys it was calculated that the maximum concentration of Y was 13.9 wt% at a depth of about 17 nm. SIMS results showed that in the scale the yttrium remained near the outer surface.

Integration of Core-Edge Spectroscopy Methods for the Study of Polymers

1996 ◽  
Vol 54 ◽  
pp. 154-155
Author(s):  
E. G. Rightor
Keyword(s):  
Excited State ◽  
Polymer Blends ◽  
Gas Phase ◽  
Spatial Resolution ◽  
High Spatial Resolution ◽  
Electronic States ◽  
Core Electron ◽  
Bulk Solids ◽  
Development Application

Core edge spectroscopy methods are versatile tools for investigating a wide variety of materials. They can be used to probe the electronic states of materials in bulk solids, on surfaces, or in the gas phase. This family of methods involves promoting an inner shell (core) electron to an excited state and recording either the primary excitation or secondary decay of the excited state. The techniques are complimentary and have different strengths and limitations for studying challenging aspects of materials. The need to identify components in polymers or polymer blends at high spatial resolution has driven development, application, and integration of results from several of these methods.

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