Specific Cooperative Effect of a Macrocyclic Receptor for Metal Ion Transfer into an Ionic Liquid

2012 ◽  
Vol 84 (21) ◽  
pp. 9332-9339 ◽  
Author(s):  
Hiroyuki Okamura ◽  
Atsushi Ikeda-Ohno ◽  
Takumi Saito ◽  
Noboru Aoyagi ◽  
Hirochika Naganawa ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Metal Ion ◽  
Cooperative Effect ◽  
Ion Transfer

scholarly journals Molecular origin of high free energy barriers for alkali metal ion transfer through ionic liquid–graphene electrode interfaces

2016 ◽  
Vol 18 (2) ◽  
pp. 1302-1310 ◽  
Author(s):  
Vladislav Ivaništšev ◽  
Trinidad Méndez-Morales ◽  
Ruth M. Lynden-Bell ◽  
Oscar Cabeza ◽  
Luis J. Gallego ◽  
...  
Keyword(s):  
Molecular Dynamics ◽  
Free Energy ◽  
Ionic Liquid ◽  
Ionic Liquids ◽  
Metal Ion ◽  
Ion Transfer ◽  
Charged Surfaces ◽  
Ion Interactions ◽  
Molecular Origin ◽  
Dynamics Simulations

We study mechanisms of solvent-mediated ion interactions with charged surfaces in ionic liquids by molecular dynamics simulations, in an attempt to reveal the main trends that determine ion–electrode interactions in ionic liquids.

scholarly journals Recent Advance in Ionic‐Liquid‐Based Electrolytes for Rechargeable Metal‐Ion Batteries

2021 ◽  
pp. 2004490
Author(s):  
Wenjun Zhou ◽  
Meng Zhang ◽  
Xiangyue Kong ◽  
Weiwei Huang ◽  
Qichun Zhang
Keyword(s):  
Ionic Liquid ◽  
Metal Ion

scholarly journals Investigating the Proton and Ion Transfer Properties of Supported Ionic Liquid Membranes Prepared for Bioelectrochemical Applications Using Hydrophobic Imidazolium-Type Ionic Liquids

Membranes ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 359
Author(s):  
László Koók ◽  
Piroska Lajtai-Szabó ◽  
Péter Bakonyi ◽  
Katalin Bélafi-Bakó ◽  
Nándor Nemestóthy
Keyword(s):  
Mass Transfer ◽  
Ionic Liquid ◽  
Ionic Liquids ◽  
Microbial Fuel Cells ◽  
Transport Numbers ◽  
Liquid Membranes ◽  
Ion Transfer ◽  
Supported Ionic Liquid ◽  
Supported Ionic Liquid Membranes ◽  
Transfer Properties

Hydrophobic ionic liquids (IL) may offer a special electrolyte in the form of supported ionic liquid membranes (SILM) for microbial fuel cells (MFC) due to their advantageous mass transfer characteristics. In this work, the proton and ion transfer properties of SILMs made with IL containing imidazolium cation and [PF6]− and [NTf2]− anions were studied and compared to Nafion. It resulted that both ILs show better proton mass transfer and diffusion coefficient than Nafion. The data implied the presence of water microclusters permeating through [hmim][PF6]-SILM to assist the proton transfer. This mechanism could not be assumed in the case of [NTf2]− containing IL. Ion transport numbers of K+, Na+, and H+ showed that the IL with [PF6]− anion could be beneficial in terms of reducing ion transfer losses in MFCs. Moreover, the conductivity of [bmim][PF6]-SILM at low electrolyte concentration (such as in MFCs) was comparable to Nafion.

Diglycolamide-Based Solvent Systems in Room Temperature Ionic Liquids for Actinide Ion Extraction: A Review

2015 ◽  
Vol 10 (2) ◽  
pp. 135-145 ◽  
Author(s):  
Prasanta Kumar Mohapatra
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Metal Ion ◽  
Room Temperature ◽  
Review Article ◽  
Metal Ion Extraction ◽  
Ion Extraction ◽  
Radiolytic Stability ◽  
Solvent Systems ◽  
Functionalized Ligands

Abstract This review article gives a comprehensive account of the extraction of actinide ions using room temperature ionic liquid-based solvent systems containing diglycolamide (DGA) or functionalized DGA extractants. These extractants include multiple DGA-functionalized ligands such as tripodal DGA (T-DGA) and DGA-functionalized calix [4]arenes (C4DGA). Apart from metal ion extraction behaviour, other important features of the ionic liquid-based solvent systems such as separation behaviour, luminescence spectroscopic results, thermodynamics of extraction and radiolytic stability of the ionic liquid-based solvents are also reviewed. Results from studies on DGA-functionalized task-specific ionic liquids (TSIL) are also included in this review article.

scholarly journals Voltammetric Methods in Metallothionein Research

2005 ◽  
Vol 3 (1-2) ◽  
pp. 43-53 ◽  
Author(s):  
Ivana Šestáková ◽  
Tomáš Navrátil
Keyword(s):  
Metal Ion ◽  
Composite Electrode ◽  
Differential Pulse ◽  
Carbon Composite ◽  
Ion Transfer ◽  
Adsorbed State ◽  
Carbon Composite Electrode ◽  
Pulse Voltammetry ◽  
Voltammetric Methods

The application of voltammetric methods using different rates of polarisation on HMDE reveal inert or labile behaviour of Cd- or Zn- complexes in the presence of excessive cadmium or zinc ions in solution. This phenomenon was demonstrated first on the simplest phytochelatin – complex of peptide(γ-Glu-Cys)2Glywith cadmium, later on rabbit liver metallothioneins –Cd7MTin the presence of cadmium andCd5Zn2MTin the presence of zinc. Voltammetric methods can distinguish between labile and inert complexes present simultaneously and therefore could elucidate their role in reactions of metal ion transfer.Another method using different rates of polarisation – elimination voltammetry with linear scan – proved that S-tetracoordinated complexes of Cd(II) or Zn(II) in the above-mentioned metallothioneins on HMDE are reduced in the adsorbed state. This implies the possibility of increasing the sensitivity of identification or determination of the above complexes. On carbon composite electrode, similar behaviour of Cd-complexes as on HMDE was observed using differential pulse voltammetry.

Benzene-centred tripodal diglycolamides for the sequestration of trivalent actinides: metal ion extraction and luminescence spectroscopic investigations in a room temperature ionic liquid

2017 ◽  
Vol 46 (34) ◽  
pp. 11355-11362 ◽  
Author(s):  
Seraj Ahmad Ansari ◽  
Prasanta Kumar Mohapatra ◽  
Andrea Leoncini ◽  
Jurriaan Huskens ◽  
Willem Verboom
Keyword(s):  
Ionic Liquid ◽  
Liquid Medium ◽  
Metal Ion ◽  
Room Temperature ◽  
Room Temperature Ionic Liquid ◽  
Metal Ion Extraction ◽  
Ion Extraction ◽  
Spectroscopic Investigations ◽  
Trivalent Actinides ◽  
Ionic Liquid Medium

Three benzene-centred tripodal diglycolamide (Bz-T-DGA) ligands were evaluated for actinide ion extraction/complexation in an ionic liquid medium.

Reductive amination of levulinic acid to N-substituted pyrrolidones over RuCl3 metal ion anchored in ionic liquid immobilized on graphene oxide

2020 ◽  
Vol 383 ◽  
pp. 206-214 ◽  
Author(s):  
Amol B. Raut ◽  
Vaishali S. Shende ◽  
Takehiko Sasaki ◽  
Bhalchandra M. Bhanage
Keyword(s):  
Ionic Liquid ◽  
Graphene Oxide ◽  
Metal Ion ◽  
Levulinic Acid ◽  
Reductive Amination
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