A Facile Electrochemical Method for Simultaneous and On-Line Measurements of Glucose and Lactate in Brain Microdialysate with Prussian Blue as the Electrocatalyst for Reduction of Hydrogen Peroxide

2007 ◽  
Vol 79 (24) ◽  
pp. 9577-9583 ◽  
Author(s):  
Yuqing Lin ◽  
Kun Liu ◽  
Ping Yu ◽  
Ling Xiang ◽  
Xianchan Li ◽  
...  
Author(s):  
Swati Verma ◽  
Dipendra Singh Mal ◽  
Paulo R. Oliveira ◽  
Bruno Campos Janegitz ◽  
Jai Prakash ◽  
...  

Electrochemical method is the most effective, facile, and economical approach for the detection of small molecules. The present article deals with design and engineering of polymer-graphene based thin films through...


2013 ◽  
Vol 4 ◽  
pp. 649-654 ◽  
Author(s):  
Maria A Komkova ◽  
Angelika Holzinger ◽  
Andreas Hartmann ◽  
Alexei R Khokhlov ◽  
Christine Kranz ◽  
...  

We report here a way for improving the stability of ultramicroelectrodes (UME) based on hexacyanoferrate-modified metals for the detection of hydrogen peroxide. The most stable sensors were obtained by electrochemical deposition of six layers of hexacyanoferrates (HCF), more specifically, an alternating pattern of three layers of Prussian Blue and three layers of Ni–HCF. The microelectrodes modified with mixed layers were continuously monitored in 1 mM hydrogen peroxide and proved to be stable for more than 5 h under these conditions. The mixed layer microelectrodes exhibited a stability which is five times as high as the stability of conventional Prussian Blue-modified UMEs. The sensitivity of the mixed layer sensor was 0.32 A·M−1·cm−2, and the detection limit was 10 µM. The mixed layer-based UMEs were used as sensors in scanning electrochemical microscopy (SECM) experiments for imaging of hydrogen peroxide evolution.


2009 ◽  
Vol 54 (4) ◽  
Author(s):  
IVANILDO LUIZ DE MATTOS ◽  
MARCOS CAROLI ◽  
MADALENA AREIAS ◽  
MARCELO NAVARRO

2007 ◽  
Vol 4 (4) ◽  
pp. 571-582
Author(s):  
Baghdad Science Journal

This research work aims to the determination of molybdenum (VI) ion via the formation of peroxy molybdenum compounds which has red-brown colour with absorbance wave length at 455nm for the system of ammonia solution-hydrogen peroxide-molybdenum (VI) using a completely newly developed microphotometer based on the ON-Line measurement. Variation of responses expressed in millivolt. A correlation coefficient of 0.9925 for the range of 2.5-150 ?g.ml-1 with percentage linearity of 98.50%. A detection limit of 0.25 ?g.ml-1 was obtained. All physical and chemical variable were optimized interferences of cation and anion were studied classical method of measurement were done and compared well with newly on-line measurements. Application for the use of developed method on alloy samples, using standard addition method and agreed quite wall.


1997 ◽  
Vol 43 (7) ◽  
pp. 1246-1246 ◽  
Author(s):  
Sohji Nagase ◽  
Norio Ohkoshi ◽  
Atsushi Ueda ◽  
Kazumasa Aoyagi ◽  
Akio Koyama

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