Contact Mechanics Modeling of Pull-Off Measurements:  Effect of Solvent, Probe Radius, and Chemical Binding Probability on the Detection of Single-Bond Rupture Forces by Atomic Force Microscopy

2002 ◽  
Vol 74 (13) ◽  
pp. 3096-3104 ◽  
Author(s):  
Hjalti Skulason ◽  
C. Daniel Frisbie
Keyword(s):  
Atomic Force Microscopy ◽  
Contact Mechanics ◽  
Bond Rupture ◽  
Single Bond ◽  
Chemical Binding ◽  
Force Microscopy ◽  
Effect Of Solvent ◽  
Probe Radius ◽  
Atomic Force ◽  
Binding Probability

Determination of Single-Bond Forces from Contact Force Variances in Atomic Force Microscopy

Langmuir ◽  
1996 ◽  
Vol 12 (5) ◽  
pp. 1291-1295 ◽  
Author(s):  
John M. Williams ◽  
Taejoon Han ◽  
Thomas P. Beebe
Keyword(s):  
Atomic Force Microscopy ◽  
Contact Force ◽  
Single Bond ◽  
Force Microscopy ◽  
Atomic Force

Single asperity tribochemical wear of silicon by atomic force microscopy

2009 ◽  
Vol 24 (1) ◽  
pp. 173-178 ◽  
Author(s):  
Futoshi Katsuki
Keyword(s):  
Atomic Force Microscopy ◽  
Frictional Force ◽  
Ph Value ◽  
Ph Dependence ◽  
Bond Rupture ◽  
Solution Ph ◽  
Crystal Silicon ◽  
Force Microscopy ◽  
Single Asperity ◽  
Atomic Force

Measurements of single asperity wear on oxidized silicon surface in aqueous potassium hydroxide (KOH) using atomic force microscopy (AFM), where the single crystal silicon tip was used both to tribologically load and image the surface, is presented. AFM was also operating in the lateral (frictional) force mode to investigate the pH dependence of kinetic friction between the tip and the SiO2 surface. It was shown that the Si tip wear amount strongly depended on the solution pH value and was at a maximum at around pH 10. It was also found that the Si removal volume in mol was approximately equal to that of SiO2 irrespective of the solution pH value. This equality implies that the formation of the Si–O–Si bridge between one Si atom of the tip and one SiO2 molecule of the specimen at the wear interface. The surface of the Si tip is then oxidized. Finally, the bond rupture by the tip movement will occur, the dimeric silica (OH)3Si–O–Si(OH)3, including the Si–O–Si bridge, is dissolved in the KOH solution. The frictional signal is also sensitive to the pH values of the solution and peaked at around pH 10. These results indicate that the removal behavior of the Si tip and SiO2 surface would be affected by the frictional force between the Si and the SiO2, because of an increased liquid temperature and a compressive stress in Si and SiO2 networks. Strong influence is observed by the pH of the ambient solution confirming the important role of the OH− in the wear mechanism. Pressure dependence of the microwear behavior under aqueous electrolyte solutions has also been investigated. A microscopic removal mechanism, which is determined by interplay of the diffusion of water in Si and SiO2, is presented.

Nanoscale-resolved elasticity: contact mechanics for quantitative contact resonance atomic force microscopy

Nanoscale ◽  
2014 ◽  
Vol 6 (12) ◽  
pp. 6898-6910 ◽  
Author(s):  
A. M. Jakob ◽  
J. Buchwald ◽  
B. Rauschenbach ◽  
S. G. Mayr
Keyword(s):  
Atomic Force Microscopy ◽  
Contact Mechanics ◽  
Surface Analysis ◽  
Force Microscopy ◽  
Atomic Force ◽  
Contact Resonance

Abilities of quantitative nanomechanical surface analysis are improved by a deeper understanding of influences on nanoscale contact physics.

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