Optimization of ion exchange membrane structures for Donnan dialysis

1982 ◽  
Vol 54 (7) ◽  
pp. 1153-1157 ◽  
Author(s):  
J. A. Cox ◽  
R. Gajek ◽  
G. R. Litwinski ◽  
J. Carnahan ◽  
W. Trochimczuk
Keyword(s):  
Ion Exchange ◽  
Ion Exchange Membrane ◽  
Membrane Structures ◽  
Donnan Dialysis ◽  
Exchange Membrane

Removal of bromate, perchlorate and nitrate from drinking water in an ion exchange membrane bioreactor

2005 ◽  
Vol 5 (5) ◽  
pp. 9-14 ◽  
Author(s):  
C.T. Matos ◽  
S. Velizarov ◽  
J.G. Crespo ◽  
M.A.M. Reis
Keyword(s):  
Drinking Water ◽  
Ion Exchange ◽  
Membrane Bioreactor ◽  
Ion Exchange Membrane ◽  
Microbial Culture ◽  
Experimental Conditions ◽  
Biological Reduction ◽  
Permselective Membrane ◽  
Donnan Dialysis ◽  
Exchange Membrane

The presence of anionic micropollutants, such as bromate, perchlorate and nitrate, in drinking water supplies represents a risk for public health. This work evaluates the applicability of the ion exchange membrane bioreactor (IEMB) concept for their removal. The IEMB concept combines the transport of anionic pollutants, through a dense mono-anion permselective membrane, with their simultaneous biodegradation to harmless products by a suitable microbial culture in a separated biocompartment. The transport of the pollutant counter-ions (anions) is governed by the Donnan equilibrium principle and, therefore, it is possible to enhance it by using a more concentrated driving counter-ion (e.g. chloride) added to the biocompartment. The IEMB process proved to selectively remove nitrate and perchlorate to concentrations below the recommended levels of 4 ppb for ClO4− and 25 ppm of NO3−, from a model polluted stream containing 100 ppb of ClO4− and 60 ppm of NO3−. Transport studies, made under Donnan dialysis conditions, showed bromate fluxes comparable to those obtained for nitrate under similar experimental conditions. However, the rate of biological reduction of bromate was about one order of magnitude slower than that of nitrate.

Removal of nitrate from water in a novel ion exchange membrane bioreactor

2002 ◽  
Vol 2 (2) ◽  
pp. 161-167 ◽  
Author(s):  
S. Velizarov ◽  
J.G. Crespo ◽  
M.A. Reis
Keyword(s):  
Ion Exchange ◽  
Removal Efficiency ◽  
Removal Rate ◽  
Ion Exchange Membrane ◽  
Polluted Water ◽  
Water Conductivity ◽  
Water Stream ◽  
Permselective Membrane ◽  
Donnan Dialysis ◽  
Exchange Membrane

Biological denitrification in a novel ion exchange membrane reactor (IEMB) has been investigated. The polluted water was separated from the mixed denitrifying culture by a non-porous, mono-anion permselective membrane providing continuous exchange of nitrate for chloride added as a counter-ion to the biocompartment. A removal efficiency of 87% and a surface removal rate of about 1,400 mg NO3- m-2h-1 was achieved at a nitrate concentration of 150 mg NO3- L-1. The treated water stream was essentially free of ethanol, used as a carbon source, and NO2- ions whereas the original water conductivity was completely preserved due to very efficient Donnan exclusion of the cations present in the two solutions from the membrane used. The IEMB process showed higher removal efficiency and better nitrate selectivity compared to a Donnan dialysis process operated under similar conditions.

Ion exchange membrane adsorption in Donnan dialysis

2019 ◽  
Vol 226 ◽  
pp. 252-258 ◽  
Author(s):  
Anna Breytus ◽  
David Hasson ◽  
Raphael Semiat ◽  
Hilla Shemer
Keyword(s):  
Ion Exchange ◽  
Ion Exchange Membrane ◽  
Donnan Dialysis ◽  
Exchange Membrane

The role of ion exchange membrane in vanadium oxygen fuel cell

2021 ◽  
Vol 629 ◽  
pp. 119271
Author(s):  
Jiří Charvát ◽  
Petr Mazúr ◽  
Martin Paidar ◽  
Jaromír Pocedič ◽  
Jiří Vrána ◽  
...  
Keyword(s):  
Fuel Cell ◽  
Ion Exchange ◽  
Ion Exchange Membrane ◽  
Exchange Membrane ◽  
Oxygen Fuel

scholarly journals Transparent Ion-Exchange Membrane Exhibiting Intense Emission under a Specific pH Condition Based on Polypyridyl Ruthenium(II) Complex with Two Imidazophenanthroline Groups

Membranes ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 400
Author(s):  
Hajime Kamebuchi ◽  
Satoshi Tamaki ◽  
Atsushi Okazawa ◽  
Norimichi Kojima
Keyword(s):  
Ion Exchange ◽  
Emission Intensity ◽  
Density Functional ◽  
Emission Spectra ◽  
Density Functional Theory Calculations ◽  
Ion Exchange Membrane ◽  
Quantum Yields ◽  
Relative Emission Intensity ◽  
Nafion Film ◽  
Exchange Membrane

The development and the photophysical behavior of a transparent ion-exchange membrane based on a pH-sensitive polypyridyl ruthenium(II) complex, [(bpy)2RuII(H2bpib)RuII(bpy)2](ClO4)4 (bpy = 2,2′-bipyridine, H2bpib = 1,4-bis([1,10]phenanthroline[5,6-d]-imidazol-2-yl)benzene), are experimentally and theoretically reported. The emission spectra of [(bpy)2RuII(H2bpib)RuII(bpy)2]@Nafion film were observed between pH 2 and pH 11 and showed the highest relative emission intensity at pH 5 (λmaxem = 594.4 nm). The relative emission intensity of the film significantly decreased down to 75% at pH 2 and 11 compared to that of pH 5. The quantum yields (Φ) and lifetimes (τ) showed similar correlations with respect to pH, Φ = 0.13 and τ = 1237 ns at pH 5, and Φ = 0.087 and τ = 1014 ns and Φ = 0.069 and τ = 954 ns at pH 2 and pH 11, respectively. These photophysical data are overall considerably superior to those of the solution, with the radiative- (kr) and non-radiative rate constants (knr) at pH 5 estimated to be kr = 1.06 × 105 s−1 and knr = 7.03 × 105 s−1. Density functional theory calculations suggested the contribution of ligand-to-ligand- and intraligand charge transfer to the imidazolium moiety in Ru-H3bpib species, implying that the positive charge on the H3bpib ligand works as a quencher. The Ru-Hbpib species seems to enhance non-radiative deactivation by reducing the energy of the upper-lying metal-centered excited state. These would be responsible for the pH-dependent “off-on-off” emission behavior.

scholarly journals Fabrication of a lead ion selective membrane based on a polycarbazole Sn(iv) arsenotungstate nanocomposite and its ion exchange membrane (IEM) kinetic studies

RSC Advances ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 4210-4220
Author(s):  
Mohd. Zeeshan ◽  
Rais Ahmad ◽  
Asif Ali Khan ◽  
Aftab Aslam Parwaz Khan ◽  
Guillermo C. Bazan ◽  
...  
Keyword(s):  
Ion Exchange ◽  
Polyvinyl Chloride ◽  
Cation Exchanger ◽  
Kinetic Studies ◽  
Ion Exchange Membrane ◽  
Lead Ion ◽  
Solution Technique ◽  
Casting Solution ◽  
Selective Membrane ◽  
Exchange Membrane

A polycarbazole-Sn(iv) arsenotungstate (Pcz-SnAT) nanocomposite cation exchanger membrane (CEM) was prepared via the casting solution technique utilizing polycarbazole-Sn(iv) arsenotungstate and PVC (polyvinyl chloride) as a binder.

Synthesis of ion exchange membrane by radiation grafting of acrylic acid onto polyethylene

1981 ◽  
Vol 18 (5-6) ◽  
pp. 899-905 ◽  
Author(s):  
I. Ishigaki ◽  
T. Sugo ◽  
K. Senoo ◽  
T. Takayama ◽  
S. Machi ◽  
...  
Keyword(s):  
Ion Exchange ◽  
Acrylic Acid ◽  
Ion Exchange Membrane ◽  
Radiation Grafting ◽  
Exchange Membrane
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