Influence of the vessel materials and solvents on the stability of mixtures of bis(2,4,6-trichlorophenyl) oxalate and hydrogen peroxide for peroxyoxalate chemiluminescence

1989 ◽  
Vol 61 (11) ◽  
pp. 1298-1300 ◽  
Author(s):  
Nobuaki. Hanaoka
Keyword(s):  
Hydrogen Peroxide ◽  
Peroxyoxalate Chemiluminescence ◽  
The Stability

A review of lignin hydrogen peroxide oxidation chemistry with emphasis on aromatic aldehydes and acids

Holzforschung ◽  
2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Ajinkya More ◽  
Thomas Elder ◽  
Zhihua Jiang
Keyword(s):  
Hydrogen Peroxide ◽  
Oxidative Degradation ◽  
Reaction Medium ◽  
Dicarboxylic Acids ◽  
Aromatic Aldehydes ◽  
Product Distribution ◽  
Reaction Conditions ◽  
Alkaline Conditions ◽  
The Stability ◽  
Oxidation Chemistry

Abstract This review discusses the main factors that govern the oxidation processes of lignins into aromatic aldehydes and acids using hydrogen peroxide. Aromatic aldehydes and acids are produced in the oxidative degradation of lignin whereas mono and dicarboxylic acids are the main products. The stability of hydrogen peroxide under the reaction conditions is an important factor that needs to be addressed for selectively improving the yield of aromatic aldehydes. Hydrogen peroxide in the presence of heavy metal ions readily decomposes, leading to minor degradation of lignin. This degradation results in quinones which are highly reactive towards peroxide. Under these reaction conditions, the pH of the reaction medium defines the reaction mechanism and the product distribution. Under acidic conditions, hydrogen peroxide reacts electrophilically with electron rich aromatic and olefinic structures at comparatively higher temperatures. In contrast, under alkaline conditions it reacts nucleophilically with electron deficient carbonyl and conjugated carbonyl structures in lignin. The reaction pattern in the oxidation of lignin usually involves cleavage of the aromatic ring, the aliphatic side chain or other linkages which will be discussed in this review.

scholarly journals Ultramicrosensors based on transition metal hexacyanoferrates for scanning electrochemical microscopy

2013 ◽  
Vol 4 ◽  
pp. 649-654 ◽  
Author(s):  
Maria A Komkova ◽  
Angelika Holzinger ◽  
Andreas Hartmann ◽  
Alexei R Khokhlov ◽  
Christine Kranz ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Detection Limit ◽  
Transition Metal ◽  
Prussian Blue ◽  
Electrochemical Deposition ◽  
Mixed Layer ◽  
Scanning Electrochemical Microscopy ◽  
The Stability ◽  
Mixed Layers ◽  
Electrochemical Microscopy

We report here a way for improving the stability of ultramicroelectrodes (UME) based on hexacyanoferrate-modified metals for the detection of hydrogen peroxide. The most stable sensors were obtained by electrochemical deposition of six layers of hexacyanoferrates (HCF), more specifically, an alternating pattern of three layers of Prussian Blue and three layers of Ni–HCF. The microelectrodes modified with mixed layers were continuously monitored in 1 mM hydrogen peroxide and proved to be stable for more than 5 h under these conditions. The mixed layer microelectrodes exhibited a stability which is five times as high as the stability of conventional Prussian Blue-modified UMEs. The sensitivity of the mixed layer sensor was 0.32 A·M−1·cm−2, and the detection limit was 10 µM. The mixed layer-based UMEs were used as sensors in scanning electrochemical microscopy (SECM) experiments for imaging of hydrogen peroxide evolution.

Effect of potassium ion on the stability and release rate of hydrogen peroxide encapsulated in silica hydrogels

AIChE Journal ◽  
2016 ◽  
Vol 63 (2) ◽  
pp. 409-417 ◽  
Author(s):  
Ezgi Melis Dogan ◽  
Fulya Sudur Zalluhoglu ◽  
Nese Orbey
Keyword(s):  
Hydrogen Peroxide ◽  
Release Rate ◽  
Potassium Ion ◽  
Silica Hydrogels ◽  
The Stability

scholarly journals Choline Salicylate Analysis: Chemical Stability and Degradation Product Identification

Molecules ◽  
2019 ◽  
Vol 25 (1) ◽  
pp. 51
Author(s):  
Katarzyna B. Wróblewska ◽  
Szymon Plewa ◽  
Paweł Dereziński ◽  
Izabela Muszalska-Kolos
Keyword(s):  
Hydrogen Peroxide ◽  
Hplc Analysis ◽  
Degradation Products ◽  
Hydrolytic Degradation ◽  
Acid Media ◽  
Product Identification ◽  
The Stability ◽  
Degradation Degree ◽  
Effect Of Light

Choline salicylate (CS) as a derivative of acetylsalicylic acid is commonly used in different drug forms. In medicine, it is applied topically to inflammation of the oral cavity mucosa and in laryngology. However, this substance in the form of an ionic liquid has not been investigated enough. There are no literature studies on stability tests constituting a stage of pre-formulation research. HPLC (Nucleosil C18, 4.6 × 150 mm, 5 μm; methanol-water-acetic acid 60:40:1, 230 nm or 270 nm) and UV (276 nm) methods for the determination of CS in 2% (g/mL) aqueous solutions were developed. Under stress conditions, CS susceptibility to hydrolytic degradation in aqueous medium, hydrochloric acid, sodium hydroxide, and hydrogen peroxide, and the effect of light on the stability of CS solutions were studied with HPLC analysis. The degradation degree of CS and the purity of the solutions were also tested. Choline salicylate has been qualified as practically stable in neutral and acid media, stable in an alkaline medium, very stable in an oxidizing environment, and photolabile in solution. The HPLC-MS/MS method was used to identify 2,3- and 2,5-dihydroxybenzoic acids as degradation products of CS under the tested conditions.

scholarly journals STUDIES ON OXIDATION AND REDUCTION BY PNEUMOCOCCUS

1924 ◽  
Vol 39 (5) ◽  
pp. 745-755 ◽  
Author(s):  
Oswald T. Avery ◽  
James M. Neill
Keyword(s):  
Hydrogen Peroxide ◽  
Molecular Oxygen ◽  
Hemolytic Activity ◽  
Active Agent ◽  
Organic Peroxide ◽  
Cell Extract ◽  
The Other ◽  
Cell Extracts ◽  
Other Hand ◽  
The Stability

In the present work on oxidation and reduction by sterile extracts of pneumococcus, the preparations employed contain among other constituents, a hemolytic substance the properties of which have been described by Cole (1, 2) in his studies on pneumococcus hemotoxin. Pneumococcus extracts prepared by the methods described are actively hemolytic, 0.005 cc. of extract causing complete lysis of 2.5 cc. of a 1 per cent suspension of red cells from rabbit blood. This hemolytic property of pneumococcus extracts is destroyed by 10 minutes exposure to 55°C. When pneumotoxin-containing extracts are protected from the action of molecular oxygen, their hemolytic activity remains unimpaired for considerable periods of time. In the presence of air, on the other hand, the stability of the hemolytic substance depends upon whether the particular type of extract contains a "complete" or "incomplete" oxidation-reduction system. Sterile broth extracts of unwashed pneumococci are reactive with molecular oxygen, and as a result of this union peroxide is formed whenever these extracts are exposed to air. The hemolytic activity of "complete" extracts of this type is rapidly decreased and finally destroyed in the presence of molecular oxygen. On the other hand, the "incomplete" type of extract prepared by saline extraction of washed pneumococci may be exposed to air with little or no loss of hemolytic power. This "incomplete" washed cell extract, unless reactivated, does not undergo autoxidation in the presence of air; under these circumstances peroxide is not formed and the hemolytic activity of this type of extract is not impaired by exposure to air. The stability of the hemolytic agent in the "incomplete" type of extract is evidence that this substance is itself not reactive with or affected by molecular oxygen, even in the presence of the cell enzymes. The destruction of the same hemolytic substance in extracts capable of undergoing autoxidation may be ascribed to the action of some peroxide formed by the union of molecular oxygen with easily oxidized or autoxidizable substances of the extract. It is now known that a peroxide, having the reactions of hydrogen peroxide, accumulates in sterile pneumococcus extracts during oxidation. It has been shown in the present study that the addition of preformed hydrogen peroxide destroys the hemolytic activity of pneumococcus extracts, although higher concentrations were required than were detected in oxidized extracts themselves. These facts and the known action of superoxides in analogous types of reaction make it seem not unlikely that the active agent in the destruction of pneumotoxin in oxidized cell extracts may be a peroxide; either hydrogen peroxide or some higher organic peroxide formed during autoxidation of the extract.

The effect of oxine (8-hydroxyquinoline) on the stability of glycerite of hydrogen peroxide*

1948 ◽  
Vol 37 (1) ◽  
pp. 34-36 ◽  
Author(s):  
Ethan Allan Brown ◽  
Wilfred B. Krabek ◽  
Rita E. Skiffington ◽  
George A. Cruickshank
Keyword(s):  
Hydrogen Peroxide ◽  
The Stability
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