Flow injection gas-diffusion method for preconcentration and determination of trace sulfide

1988 ◽  
Vol 60 (24) ◽  
pp. 2791-2796 ◽  
Author(s):  
Emil B. Milosavljevic ◽  
Ljiljana. Solujic ◽  
James L. Hendrix ◽  
John H. Nelson
1961 ◽  
Vol 16 (6) ◽  
pp. 1065-1070 ◽  
Author(s):  
Hadley L. Conn

In vitro and in vivo studies were made of the equilibrium distribution of radioxenon in various organs and tissues of the dog and the xenon uptake compared with a water standard. Tissue-blood partition coefficients were calculated. The radioxenon-hemoglobin association curve was determined for dog and human hemoglobin and methemoglobin. The uptake of radioxenon by blood, due in particular to xenon-hemoglobin affinity, was appreciably greater than uptake either by water or by most other body tissues. Fat and brain were notable exceptions. Consequently, tissue-blood partition coefficients were about eight for fat, one for brain, and significantly less than one for other tissues studied. Acceptable accuracy for blood flow determinations with a radioxenon inert gas diffusion method would seem to depend on the use of a partition coefficient correction in turn corrected at least for the existing hemoglobin concentration. The uptake of xenon by hemoglobin had the characteristics of a solubility or a quasi-solubility phenomenon. The problem of the nature of the interaction is apparently not resolved. Submitted on June 19, 1961


1995 ◽  
Vol 17 (6) ◽  
pp. 205-212 ◽  
Author(s):  
Stuart W. Gibb ◽  
John W. Wood ◽  
R. Fauzi ◽  
C. Mantoura

The automation and improved design and performance of Flow Injection Gas Diffusion-Ion Chromatography (FIGD-IC), a novel technique for the simultaneous analysis of trace ammonia (NH3) and methylamines (MAs) in aqueous media, is presented. Automated Flow Injection Gas Diffusion (FIGD) promotes the selective transmembrane diffusion of MAs and NH3from aqueous sample under strongly alkaline (pH > 12, NaOH), chelated (EDTA) conditions into a recycled acidic acceptor stream. The acceptor is then injected onto an ion chromatograph where NH3and the MAs are fully resolved as their cations and detected conductimetrically. A versatile PC interfaced control unit and data capture unit (DCU) are employed in series to direct the selonoid valve switching sequence, IC operation and collection of data. Automation, together with other modifications improved both linearily (R2> 0.99 MAs 0-100 nM, NH30-1000 nM) and precision (<8%) of FIGD-IC at nanomolar concentrations, compared with the manual procedure. The system was successfully applied to the determination of MAs and NH3in seawater and in trapped particulate and gaseous atmospheric samples during an oceanographic research cruise.


2018 ◽  
Author(s):  
N. H. Sulimai ◽  
Rozina Abdul Rani ◽  
Z. Khusaimi ◽  
S. Abdullah ◽  
M. J. Salifairus ◽  
...  

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