Determination of electrochemical heterogeneous electron-transfer reaction rates from steady-state measurements at ultramicroelectrodes

1986 ◽  
Vol 58 (14) ◽  
pp. 2961-2964 ◽  
Author(s):  
Andrea. Russell ◽  
Kari. Repka ◽  
Timothy. Dibble ◽  
Jamal. Ghoroghchian ◽  
Jerry J. Smith ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Steady State ◽  
Transfer Reaction ◽  
Reaction Rates ◽  
Electron Transfer Reaction ◽  
Heterogeneous Electron Transfer

Self-assembled monolayers formed by [M(CN)5(pyS)]4−(M = Fe, Ru) on gold: a comparative study on stability and efficiency to assess the cyt c heterogeneous electron transfer reaction

2003 ◽  
pp. 2231-2236 ◽  
Author(s):  
Izaura Cirino Nogueira Diógenes ◽  
Jackson Rodrigues de Sousa ◽  
Idalina Maria Moreira de Carvalho ◽  
Márcia Laudelina Arruda Temperini ◽  
Auro Atsushi Tanaka ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Comparative Study ◽  
Transfer Reaction ◽  
Electron Transfer Reaction ◽  
Self Assembled Monolayers ◽  
Heterogeneous Electron Transfer ◽  
Assembled Monolayers ◽  
Cyt C ◽  
Self Assembled

Possible use of chronopotentiometry at the interface between two immiscible liquid phases to the studies of homogeneous chemical reactions

1985 ◽  
Vol 50 (8) ◽  
pp. 1636-1641
Author(s):  
Emanuel Makrlík
Keyword(s):  
Electron Transfer ◽  
Chemical Reactions ◽  
Transfer Reaction ◽  
Electron Transfer Reaction ◽  
Immiscible Liquid ◽  
Liquid Phases ◽  
Homogeneous Chemical ◽  
The Given ◽  
Galvanostatic Conditions

The theoretical potential-time dependence corresponding to the electron transfer reaction proceeding at the interface between two immiscible liquid phases with the redox pairs O1/R1 in the aqueous (aq) phase and O2/R2 in the non-aqueous (non) phase, that is complicated by the reaction R1(aq) + Z(aq) → O1(aq) in the aqueous phase, has been derived under the galvanostatic conditions. Moreover, a method for the determination of the formal rate constant kf for the given homogeneous chemical reaction is proposed.

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