Multivariate relationships between gas chromatographic retention index and molecular connectivity of mononitrated polycyclic aromatic hydrocarbons

1986 ◽  
Vol 58 (9) ◽  
pp. 2072-2077 ◽  
Author(s):  
Albert. Robbat ◽  
Nicholas P. Corso ◽  
Philip J. Doherty ◽  
Durwood. Marshall
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Retention Index ◽  
Aromatic Hydrocarbons ◽  
Chromatographic Retention ◽  
Molecular Connectivity ◽  
Multivariate Relationships ◽  
Polycyclic Aromatic

scholarly journals Retention Behaviour of Alkylated and Non-Alkylated Polycyclic Aromatic Hydrocarbons on Different Types of Stationary Phases in Gas Chromatography

Separations ◽  
2019 ◽  
Vol 6 (1) ◽  
pp. 7 ◽  
Author(s):  
Ewa Skoczyńska ◽  
Jacob de Boer
Keyword(s):  
Molecular Weight ◽  
Gas Chromatography ◽  
Ionic Liquid ◽  
Polycyclic Aromatic Hydrocarbons ◽  
Aromatic Hydrocarbons ◽  
Stationary Phases ◽  
Chromatographic Retention ◽  
Retention Behaviour ◽  
Polycyclic Aromatic ◽  
Alkylated Pahs

The gas chromatographic retention behaviour of 16 polycyclic aromatic hydrocarbons (PAHs) and alkylated PAHs on a new ionic liquid stationary phase, 1,12-di(tripropylphosphonium) dodecane bis(trifluoromethanesulfonyl)imide (SLB®-ILPAH) intended for the separation of PAH mixtures, was compared with the elution pattern on more traditional stationary phases: a non-polar phenyl arylene (DB-5ms) and a semi-polar 50% phenyl dimethyl siloxane (SLB PAHms) column. All columns were tested by injections of working solutions containing 20 parental PAHs from molecular weight of 128 to 278 g/mol and 48 alkylated PAHs from molecular weight of 142 to 280 g/mol on a one dimensional gas chromatography-mass spectrometry (GC-MS) system. The SLB PAHms column allowed separation of most isomers. The SLB®-ILPAH column showed a rather different retention pattern compared to the other two columns and, therefore, provided a potential for use in comprehensive two-dimensional GC (GC×GC). The ionic liquid column and the 50% phenyl column showed good thermal stability with a low bleed profile, even lower than that of the phenyl arylene “low bleed” column.

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