Uranium Speciation in Solution by Time-Resolved Laser-Induced Fluorescence

1995 ◽  
Vol 67 (2) ◽  
pp. 348-353 ◽  
Author(s):  
Christophe. Moulin ◽  
Pierre. Decambox ◽  
Valerie. Moulin ◽  
Jean Gary. Decaillon
Polyhedron ◽  
2013 ◽  
Vol 55 ◽  
pp. 92-101 ◽  
Author(s):  
Albert Martínez-Torrents ◽  
Sandra Meca ◽  
Nils Baumann ◽  
Vicenç Martí ◽  
Javier Giménez ◽  
...  

1998 ◽  
Vol 52 (4) ◽  
pp. 528-535 ◽  
Author(s):  
Christophe Moulin ◽  
Ivan Laszak ◽  
Valérie Moulin ◽  
Christian Tondre

Time-resolved laser-induced fluorescence is a unique method for direct uranium speciation at low level in the framework of environmental studies. By varying pH and uranium concentration in the absence of carbonate ions and at fixed ionic strength, it was possible, together with free uranyl UO22+, to identify spectrally and temporally all the uranium-hydroxo complexes, namely, UO2OH+, UO2(OH)2, UO2(OH)3−, (UO2)2(OH)22+, (UO2)3(OH)5+, and (UO2)3(OH)7−.


1994 ◽  
Vol 48 (9) ◽  
pp. 1118-1124 ◽  
Author(s):  
Sara Agrup ◽  
Marcus Aldén

Time-resolved laser-induced fluorescence (LIF) from CO molecules in hydrocarbon flames was studied. Collisional quenching constants were evaluated on the basis of the exponential decays. Effective lifetime in a methane/oxygen flame was observed to vary between 250 and 400 ps depending on the position within the flame, and from 400 to 600 ps in the non-sooty parts of an ethylene/air flame. Fluorescence, constituting simultaneous spatially and temporally resolved decays, was also registered from various sections along a laser beam that probed different parts of the flame. Spectral recordings revealed not only the expected CO peaks but also, in the ethylene flame, laser-induced emission from C2 Swan bands and from polyaromatic hydrocarbon (PAH) emission that affected the fluorescence time decay in the sooty part of the flame.


2010 ◽  
Vol 142 (6) ◽  
pp. 838-844 ◽  
Author(s):  
Jeremy D. Meier ◽  
Hongtao Xie ◽  
Yang Sun ◽  
Yinghua Sun ◽  
Nisa Hatami ◽  
...  

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