Mercury-free disposable lead sensors based on potentiometric stripping analysis of gold-coated screen-printed electrodes

1993 ◽  
Vol 65 (11) ◽  
pp. 1529-1532 ◽  
Author(s):  
Joseph. Wang ◽  
Baomin. Tian
2013 ◽  
Vol 46 (16) ◽  
pp. 2479-2502 ◽  
Author(s):  
Xiangheng Niu ◽  
Minbo Lan ◽  
Hongli Zhao ◽  
Chen Chen ◽  
Yuxiu Li ◽  
...  

Chemosensors ◽  
2018 ◽  
Vol 6 (3) ◽  
pp. 37
Author(s):  
Carlo Dossi ◽  
Damiano Monticelli ◽  
Andrea Pozzi ◽  
Sandro Recchia

Decentralization of on-site and in-site trace metal analysis has been a key topic over the last 30 years, owing to the increasing need for environmental protection as well as industrial and health-based field applications. In trace (and ultratrace) metal analysis, electrochemical stripping analysis with mercury (or bismuth) screen-printed film electrodes has shown a fast growth in popularity thanks to the good limits of detection, the ease of application in the field, and the low cost. Moreover, the availability of new wall-jet flow cells has opened the opportunity for their use in in situ industrial monitoring. The analytical figures of merit in stripping voltammetry with screen-printed electrodes (SPEs) under decentralized conditions and/or with sensor arrays are heavily affected by some analytical factors, primarily the presence of a pseudo-reference electrode, the efficiency of mass transport during the preconcentration step, and the need for external calibration. A careful model investigation of the analytical parameters for an efficient use of SPEs in decentralized conditions has been undertaken and discussed. Different instrumental approaches were investigated, comparing optimized batch conditions and flow cell operation under either continuous flow or stopped-flow sample injection. The stripping efficiency under wall-jet flow conditions was found to be high and comparable to that in batch conditions, leading to sub-ppb (μg/L) limit of detection (LOD) figures. Finally, external calibration in stripping voltammetry was studied as a viable alternative to conventional standard addition quantitation. Results showed, indeed, that external calibration was demonstrated to be reliable for quantitation of Pb and Cd in real water samples.


2014 ◽  
Vol 26 (5) ◽  
pp. 931-939 ◽  
Author(s):  
Stefano Cinti ◽  
Sara Politi ◽  
Danila Moscone ◽  
Giuseppe Palleschi ◽  
Fabiana Arduini

2011 ◽  
Vol 56 (11) ◽  
pp. 3988-3995 ◽  
Author(s):  
Elena Jubete ◽  
Kamila Żelechowska ◽  
Oscar A. Loaiza ◽  
Pedro J. Lamas ◽  
Estibalitz Ochoteco ◽  
...  

Author(s):  
Robert D. Crapnell ◽  
Whitchuta Jesadabundit ◽  
Alejandro García-Miranda Ferrari ◽  
Nina C. Dempsey-Hibbert ◽  
Marloes Peeters ◽  
...  

2021 ◽  
pp. 101055
Author(s):  
Dora Domnica Baciu ◽  
Ruxandra Bîrjega ◽  
Valentina Mărăscu ◽  
Rodica Zăvoianu ◽  
Andreea Matei ◽  
...  

Nahrung/Food ◽  
1997 ◽  
Vol 41 (2) ◽  
pp. 111-113 ◽  
Author(s):  
Z. J. Suturović ◽  
N. J. Marjanović ◽  
N. M. Dostanić

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