Asymptotic solution of shock tube flows with homogeneous condensation

1995 ◽  
Vol 287 ◽  
pp. 93-118 ◽  
Author(s):  
Can F. Delale ◽  
Günter H. Schnerr ◽  
Jürgen Zierep
Keyword(s):  
Shock Wave ◽  
Asymptotic Solution ◽  
Shock Tube ◽  
Complete Solution ◽  
Nucleation Theory ◽  
Classical Nucleation Theory ◽  
Droplet Growth ◽  
Homogeneous Condensation ◽  
Shock Fitting ◽  
Supercritical Flows

The asymptotic solution of shock tube flows with homogeneous condensation is presented for both smooth, or subcritical, flows and flows with an embedded shock wave, or supercritical flows. For subcritical flows an analytical expression, independent of the particular theory of homogeneous condensation to be employed, that determines the condensation wave front in the rarefaction wave is obtained by the asymptotic analysis of the rate equation along pathlines. The complete solution is computed by an algorithm which utilizes the classical nucleation theory and the Hertz–Knudsen droplet growth law. For supercritical flows four distinct flow regimes are distinguished along pathlines intersecting the embedded shock wave analogous to supercritical nozzle flows. The complete global solution for supercritical flows is discussed only qualitatively owing to the lack of a shock fitting technique for embedded shock waves. The results of the computations obtained by the subcritical algorithm show that most of the experimental data available exhibit supercritical flow behaviour and thereby the predicted onset conditions in general show deviations from the measured values. The causes of these deviations are reasoned by utilizing the qualitative global asymptotic solution of supercritical flows.

The Feasibility of an Euler-Lagrange Approach for the Modelling of Wet Steam

2020 ◽  
Author(s):  
Tim Wittmann ◽  
Christoph Bode ◽  
Jens Friedrichs
Keyword(s):  
Optimal Parameter ◽  
Nucleation Theory ◽  
Classical Nucleation Theory ◽  
Droplet Growth ◽  
Wet Steam ◽  
Discrete Phase Model ◽  
Ansys Fluent ◽  
Validation Data ◽  
Numerical Validation ◽  
Lagrange Approach

Abstract This study investigates the applicability of an Euler-Lagrange approach for the calculation of nucleation and condensation of steam flows. Supersonic nozzles are used as generic validation cases, as their high expansion rates replicate the flow conditions in real turbines. Experimental and numerical validation data for these nozzles are provided by the International Wet Steam Modelling Project of Starzmann et al. (2018). In contrast to most participants of that project, an Euler-Lagrange approach is utilized for this study. Therefore, the classical nucleation theory with corrections and different droplet growth laws is incorporated into the Discrete Phase Model of ANSYS Fluent. Suggestions for an efficient implementation are presented. The Euler-Lagrange results show a good agreement with the experimental and numerical validation data. The sensitivities of the Euler-Lagrange approach to modelling parameters are analysed. Finally, an optimal parameter set for the calculation of nucleation and condensation is proposed.

The Feasibility of an Euler–Lagrange Approach for the Modeling of Wet Steam

2021 ◽  
Vol 143 (4) ◽  
Author(s):  
Tim Wittmann ◽  
Christoph Bode ◽  
Jens Friedrichs
Keyword(s):  
Optimal Parameter ◽  
Nucleation Theory ◽  
Classical Nucleation Theory ◽  
Droplet Growth ◽  
Wet Steam ◽  
Discrete Phase Model ◽  
Validation Data ◽  
Numerical Validation ◽  
Discrete Phase ◽  
Lagrange Approach

Abstract This study investigates the applicability of an Euler–Lagrange approach for the calculation of nucleation and condensation of steam flows. Supersonic nozzles are used as generic validation cases, as their high expansion rates replicate the flow conditions in real turbines. Experimental and numerical validation data for these nozzles are provided by the International Wet Steam Modeling Project of Starzmann et al. (2018, “Results of the International Wet Steam Modeling Project,” Proc. Inst. Mech. Eng. A, 232(5), pp. 550–570). In contrast to most participants of that project, an Euler–Lagrange approach is utilized for this study. Therefore, the classical nucleation theory with corrections and different droplet growth laws is incorporated into the discrete phase model of ansysfluent. Suggestions for an efficient implementation are presented. The Euler–Lagrange results show a good agreement with the experimental and numerical validation data. The sensitivities of the Euler–Lagrange approach to modeling parameters are analyzed. Finally, an optimal parameter set for the calculation of nucleation and condensation is proposed.

Instabilities and bifurcation of non-equilibrium two-phase flows

1997 ◽  
Vol 348 ◽  
pp. 1-28 ◽  
Author(s):  
STEPHAN ADAM ◽  
GÜNTER H. SCHNERR
Keyword(s):  
Equilibrium Phase ◽  
Practical Interest ◽  
Nucleation Theory ◽  
Classical Nucleation Theory ◽  
Droplet Growth ◽  
Sudden Increase ◽  
Pressure Amplitude ◽  
Two Phase ◽  
Supersonic Wind Tunnel ◽  
Non Equilibrium

New instabilites of unsteady transonic flows with non-equilibrium phase transition are presented including unsymmetric flow patterns with moving oblique shock systems in supersonic nozzles with perfectly symmetric shapes. The phenomena were first detected when performing experiments in our supersonic wind tunnel with atmospheric supply and could be perfectly reproduced by numerical simulations based on the Euler equations, i.e. neglecting the viscosity of the fluid. The formation of the liquid phase is modelled using the classical nucleation theory for the steady state together with the Hertz–Knudsen droplet growth law and yields qualitatively and quantitatively excellent agreement with experiments in the unsteady flow regime with high-frequency oscillations including the unstable transient change of the structure from symmetric to unsymmetric flow.For engineering applications the sudden increase or decrease of the frequency by a factor 2 or more and of the pressure amplitude at the bifurcation limits is of immediate practical interest, e.g. for flutter excitation of turbomachinery blading.

Classical Nucleation Theory and Its Application to Condensing Steam Flow Calculations

2005 ◽  
Vol 219 (12) ◽  
pp. 1315-1333 ◽  
Author(s):  
F Bakhtar ◽  
J B Young ◽  
A J White ◽  
D A Simpson
Keyword(s):  
Predictive Accuracy ◽  
Nucleation Theory ◽  
Classical Nucleation Theory ◽  
Droplet Radius ◽  
Droplet Growth ◽  
Wide Range ◽  
Recent Developments ◽  
Judicious Choice ◽  
The Many ◽  
Low Pressures

The paper discusses the classical theory of the homogeneous nucleation of water droplets from supersaturated vapour and its application in predicting condensation in steam nozzles. The first part consists of a review of classical nucleation theory, focusing on the many modifications made to the original Becker-Döring theory and providing some new insights into recent developments. It is concluded that the predictive accuracy required for engineering calculations is not yet attainable with a theory derived from first principles. The areas that require most attention relate to the properties of small molecular clusters and the energy transfer processes in the non-isothermal theory. Experiments in converging-diverging nozzles provide the best means for validation at the very high nucleation rates of interest, but measurements of pressure distribution and the Sauter mean droplet radius are insufficient to provide independent checks on the separate theories of nucleation and droplet growth. Nevertheless, a judicious choice for the nucleation rate equation, in combination with a standard droplet growth model and a suitable equation of state for steam, can provide accurate predictions over a wide range of conditions. The exception is at very low pressures where there is evidence that the droplet growth rate in the nucleation zone is underestimated.

The Influence of Condensation on the Performance Map of a Fuel Cell Turbocharger Turbine

2021 ◽  
Author(s):  
Tim Wittmann ◽  
Sebastian Lück ◽  
Tim Hertwig ◽  
Christoph Bode ◽  
Jens Friedrichs
Keyword(s):  
Fuel Cell ◽  
Pressure Ratio ◽  
Nucleation Theory ◽  
Classical Nucleation Theory ◽  
Droplet Growth ◽  
Pressure Potential ◽  
Automotive Fuel ◽  
Performance Map ◽  
A Minor ◽  
Gas Expansion

Abstract Exhaust gas of an automotive fuel cell is enriched with water vapour and has a pressure potential which can be utilized by a turbine. The gas expansion in the turbine leads to droplet nucleation and condensation. This results in a release of latent heat and a decrease of the gaseous mass flow which has a considerable influence on the turbine performance. This study aims to numerically investigate the influence of these phenomena on the performance map of the radial turbine of an automotive fuel cell turbocharger. For this purpose, the classical nucleation theory and Young’s droplet growth law are integrated into an Euler-Lagrange approach. The results show an almost linear relation between the pressure ratio and the condensation while the specific aerodynamics of an operating point has only a minor influence. At 80 % relative humidity of the inflow, the investigated turbine showed condensation above a total-to-static pressure ratio of 1.8. Condensation leads to thermal throttling of the turbine and to a temperature increase of the rotor outflow of up to 50 K. Increasing humidity of the inflow increases the power output, but condensation losses reduce the efficiency.

scholarly journals Phase-field modeling of grain evolutions in additive manufacturing from nucleation, growth, to coarsening

2021 ◽  
Vol 7 (1) ◽  
Author(s):  
Min Yang ◽  
Lu Wang ◽  
Wentao Yan
Keyword(s):  
Additive Manufacturing ◽  
Phase Field ◽  
Field Model ◽  
Three Dimensional ◽  
Phase Field Model ◽  
Nucleation Theory ◽  
Experimental Result ◽  
Classical Nucleation Theory ◽  
Validation Experiment ◽  
Powder Particles

AbstractA three-dimensional phase-field model is developed to simulate grain evolutions during powder-bed-fusion (PBF) additive manufacturing, while the physically-informed temperature profile is implemented from a thermal-fluid flow model. The phase-field model incorporates a nucleation model based on classical nucleation theory, as well as the initial grain structures of powder particles and substrate. The grain evolutions during the three-layer three-track PBF process are comprehensively reproduced, including grain nucleation and growth in molten pools, epitaxial growth from powder particles, substrate and previous tracks, grain re-melting and re-growth in overlapping zones, and grain coarsening in heat-affected zones. A validation experiment has been carried out, showing that the simulation results are consistent with the experimental results in the molten pool and grain morphologies. Furthermore, the grain refinement by adding nanoparticles is preliminarily reproduced and compared against the experimental result in literature.

scholarly journals On the Role of Poly-Glutamic Acid in the Early Stages of Iron(III) (Oxy)(hydr)oxide Formation

Minerals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 715
Author(s):  
Miodrag J. Lukić ◽  
Felix Lücke ◽  
Teodora Ilić ◽  
Katharina Petrović ◽  
Denis Gebauer
Keyword(s):  
Fourier Transform ◽  
Infrared Spectroscopy ◽  
Phase Separation ◽  
Fourier Transform Infrared Spectroscopy ◽  
Fourier Transform Infrared ◽  
Nucleation Theory ◽  
Classical Nucleation Theory ◽  
Oxide Formation ◽  
Early Stages ◽  
Titration Assay

Nucleation of minerals in the presence of additives is critical for achieving control over the formation of solids in biomineralization processes or during syntheses of advanced hybrid materials. Herein, we investigated the early stages of Fe(III) (oxy)(hydr)oxide formation with/without polyglutamic acid (pGlu) at low driving force for phase separation (pH 2.0 to 3.0). We employed an advanced pH-constant titration assay, X-ray diffraction, thermal analysis with mass spectrometry, Fourier Transform infrared spectroscopy, and scanning electron microscopy. Three stages were observed: initial binding, stabilization of Fe(III) pre-nucleation clusters (PNCs), and phase separation, yielding Fe(III) (oxy)(hydr)oxide. The data suggest that organic–inorganic interactions occurred via binding of olation Fe(III) PNC species. Fourier Transform Infrared Spectroscopy (FTIR) analyses revealed a plausible interaction motif and a conformational adaptation of the polypeptide. The stabilization of the aqueous Fe(III) system against nucleation by pGlu contrasts with the previously reported influence of poly-aspartic acid (pAsp). While this is difficult to explain based on classical nucleation theory, alternative notions such as the so-called PNC pathway provide a possible rationale. Developing a nucleation theory that successfully explains and predicts distinct influences for chemically similar additives like pAsp and pGlu is the Holy Grail toward advancing the knowledge of nucleation, early growth, and structure formation.

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