Migration of ion-exchange particles driven by a uniform electric field

2010 ◽  
Vol 655 ◽  
pp. 105-121 ◽  
Author(s):  
EHUD YARIV
Keyword(s):  
Zeta Potential ◽  
Electric Field ◽  
Boundary Conditions ◽  
Salt Concentration ◽  
Ion Selectivity ◽  
Particle Surface ◽  
Dirichlet Condition ◽  
Transport Processes ◽  
Electrokinetic Flow ◽  
Particle Boundary

A cation-selective conducting particle is suspended in an electrolyte solution and is exposed to a uniformly applied electric field. The electrokinetic transport processes are described in a closed mathematical model, consisting of differential equations, representing the physical transport in the electrolyte, and boundary conditions, representing the physicochemical conditions on the particle boundary and at large distances away from it. Solving this mathematical problem would in principle provide the electrokinetic flow about the particle and its concomitant velocity relative to the otherwise quiescent fluid.Using matched asymptotic expansions, this problem is analysed in the thin-Debye-layer limit. A macroscale description is extracted, whereby effective boundary conditions represent appropriate asymptotic matching with the Debye-scale fields. This description significantly differs from that corresponding to a chemically inert particle. Thus, ion selectivity on the particle surface results in a macroscale salt concentration polarization, whereby the electric potential is rendered non-harmonic. Moreover, the uniform Dirichlet condition governing this potential on the particle surface is transformed into a non-uniform Dirichlet condition on the macroscale particle boundary. The Dukhin–Derjaguin slip formula still holds, but with a non-uniform zeta potential that depends, through the cation-exchange kinetics, upon the salt concentration and electric field distributions. For weak fields, an approximate solution is obtained as a perturbation to a reference state. The linearized solution corresponds to a uniform zeta potential; it predicts a particle velocity which is proportional to the applied field. The associated electrokinetic flow is driven by two different agents, electric field and salinity gradients, which are of comparable magnitude. Accordingly, this flow differs significantly from that occurring in electrophoresis of chemically inert particles.

A class of driven, dissipative, energy-conserving magnetohydrodynamic equilibria with flow

1998 ◽  
Vol 60 (3) ◽  
pp. 587-625 ◽  
Author(s):  
MICHAEL L. GOODMAN
Keyword(s):  
Heat Flux ◽  
Electric Field ◽  
Boundary Conditions ◽  
Current Density ◽  
Hydrogen Plasma ◽  
Transport Coefficients ◽  
Outer Region ◽  
Radial Electric Field ◽  
Axial Current ◽  
Transport Processes

The classical transport coefficients provide an accurate description of transport processes in collision-dominated plasmas. These transport coefficients are used in a cylindrically symmetric, electrically driven, steady-state magnetohydrodynamic (MHD) model with flow and an energy equation to study the effects of transport processes on MHD equilibria. The transport coefficients, which are functions of number density, temperature and magnetic field strength, are computed self-consistently as functions of radius R. The model has plasma-confining solutions characterized by the existence of an inner region of plasma with values of temperature, pressure and current density that are orders of magnitude larger than in the surrounding, outer region of plasma that extends outward to the boundary of the cylinder at R=a. The inner and outer regions are separated by a boundary layer that is an electric-dipole layer in which the relative charge separation is localized, and in which the radial electric field, temperature, pressure and axial current density vary rapidly. By analogy with laboratory fusion plasmas in confinement devices, the plasma in the inner region is confined plasma, and the plasma in the outer region is unconfined plasma. The solutions studied demonstrate that the thermoelectric current density, driven by the temperature gradient, can make the main contribution to the current density, and that the thermoelectric component of the electron heat flux, driven by an effective electric field, can make a large contribution to the total heat flux. These solutions also demonstrate that the electron pressure gradient and Hall terms in Ohm's law can make dominant contributions to the radial electric field. These results indicate that the common practice of neglecting thermoelectric effects and the Hall and electron pressure-gradient terms in Ohm's law is not always justified, and can lead to large errors. The model has three, intrinsic, universal values of β at which qualitative changes in the solutions occur. These values are universal in that they only depend on the ion charge number and the electron-to-ion mass ratio. The first such value of β (about 3.2% for a hydrogen plasma), when crossed, signals a change in sign of the radial gradient of the number density, and must be exceeded in order that a plasma-confining solution exist for a plasma with no flow. The second such value of β (about 10.4% for a hydrogen plasma), when crossed, signals a change in sign of the poloidal current density. Some of the solutions presented exhibit this current reversal. The third such value of β is about 2.67 for a hydrogen plasma. When β is greater than or equal to this value, the thermoelectric, effective electric-field-driven component of the electron heat flux cancels 50% or more of the temperature-gradient-driven ion heat flux. If appropriate boundary conditions are given on the axis R=0 of the cylinder, the equilibrium is uniquely determined. Analytical evidence is presented that, together with earlier work, strongly suggests that if appropriate boundary conditions are enforced at the outer boundary R=a then the equilibrium exhibits a bifurcation into two states, one of which exhibits plasma confinement and carries a larger axial current than the other state, which is close to global thermodynamic equilibrium, and so is not plasma-confining. Exact expressions for the two values of the axial current in the bifurcation are presented. Whether or not a bifurcation can occur is determined by the values of a critical electric field determined by the boundary conditions at R=a, and the constant driving electric field, which is specified. An exact expression for the critical electric field is presented. Although the ranges of the physical quantities computed by the model are a subset of those describing fusion plasmas in tokamaks, the model may be applied to any two-component, electron–ion, collision-dominated plasma for which the ion cyclotron frequency is much larger than the ion–ion Coulomb collision frequency, such as the plasma in magnetic flux tubes in the solar interior, photosphere, lower transition region, and possibly the upper transition region and lower corona.

Electrokinetic flows about conducting drops

2013 ◽  
Vol 722 ◽  
pp. 394-423 ◽  
Author(s):  
Ory Schnitzer ◽  
Itzchak Frankel ◽  
Ehud Yariv
Keyword(s):  
Zeta Potential ◽  
Electric Field ◽  
Boundary Conditions ◽  
Double Layer ◽  
Double Layers ◽  
Closed Form Expression ◽  
Neumann Condition ◽  
Debye Layer ◽  
Electrokinetic Flows ◽  
Weak Fields

AbstractWe consider electrokinetic flows about a freely suspended liquid drop, deriving a macroscale description in the thin-double-layer limit where the ratio $\delta $ between Debye width and drop size is asymptotically small. In this description, the electrokinetic transport occurring within the diffuse part of the double layer (the ‘Debye layer’) is represented by effective boundary conditions governing the pertinent fields in the electro-neutral bulk, wherein the generally non-uniform distribution of $\zeta $, the dimensionless zeta potential, is a priori unknown. We focus upon highly conducting drops. Since the tangential electric field vanishes at the drop surface, the viscous stress associated with Debye-scale shear, driven by Coulomb body forces, cannot be balanced locally by Maxwell stresses. The requirement of microscale stress continuity therefore brings about a unique velocity scaling, where the standard electrokinetic scale is amplified by a ${\delta }^{- 1} $ factor. This reflects a transition from slip-driven electro-osmotic flows to shear-induced motion. The macroscale boundary conditions display distinct features reflecting this unique scaling. The effective shear-continuity condition introduces a Lippmann-type stress jump, appearing as a product of the local charge density and electric field. This term, representing the excess Debye-layer shear, follows here from a systematic coarse-graining procedure starting from the exact microscale description, rather than from thermodynamic considerations. The Neumann condition governing the bulk electric field is inhomogeneous, representing asymptotic matching with transverse ionic fluxes emanating from the Debye layer; these fluxes, in turn, are associated with non-uniform tangential ‘surface’ currents within this layer. Their appearance at leading order is a manifestation of dominant advection associated with the large velocity scale. For weak fields, the linearized macroscale equations admit an analytic solution, yielding a closed-form expression for the electrophoretic velocity. When scaled by Smoluchowski’s speed, it reads $${\delta }^{- 1} \frac{\sinh ( \overline{\zeta } / 2)/ \overline{\zeta } }{1+ { \textstyle\frac{3}{2} }\mu + 2\alpha {\mathop{\sinh }\nolimits }^{2} ( \overline{\zeta } / 2)} ,$$ wherein $ \overline{\zeta } $, the ‘drop zeta potential’, is the uniform value of $\zeta $ in the absence of an applied field, $\mu $ the ratio of drop to electrolyte viscosities, and $\alpha $ the ionic drag coefficient. The difference from solid-particle electrophoresis is manifested in two key features: the ${\delta }^{- 1} $ scaling, and the effect of ionic advection, as represented by the appearance of $\alpha $. Remarkably, our result differs from the small-$\delta $ limit of the mobility expression predicted by the weak-field model of Ohshima, Healy & White (J. Chem. Soc. Faraday Trans. 2, vol. 80, 1984, pp. 1643–1667). This discrepancy is related to the dominance of advection on the bulk scale, even for weak fields, which feature cannot be captured by a linear theory. The order of the respective limits of thin double layers and weak applied fields is not interchangeable.

scholarly journals Towards bio-inspired artificial muscle: a mechanism based on electro-osmotic flow simulated using dissipative particle dynamics

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Ramin Zakeri
Keyword(s):  
Zeta Potential ◽  
Electric Field ◽  
Dissipative Particle Dynamics ◽  
Artificial Muscle ◽  
Particle Dynamics ◽  
Polymer Membrane ◽  
Channel Width ◽  
Micro Channel ◽  
Osmotic Flow ◽  
Electro Osmotic Flow

AbstractOne of the unresolved issues in physiology is how exactly myosin moves in a filament as the smallest responsible organ for contracting of a natural muscle. In this research, inspired by nature, a model is presented consisting of DPD (dissipative particle dynamics) particles driven by electro-osmotic flow (EOF) in micro channel that a thin movable impermeable polymer membrane has been attached across channel width, thus momentum of fluid can directly transfer to myosin stem. At the first, by validation of electro-osmotic flow in micro channel in different conditions with accuracy of less than 10 percentage error compared to analytical results, the DPD results have been developed to displacement of an impermeable polymer membrane in EOF. It has been shown that by the presence of electric field of 250 V/m and Zeta potential − 25 mV and the dimensionless ratio of the channel width to the thickness of the electric double layer or kH = 8, about 15% displacement in 8 s time will be obtained compared to channel width. The influential parameters on the displacement of the polymer membrane from DPD particles in EOF such as changes in electric field, ion concentration, zeta potential effect, polymer material and the amount of membrane elasticity have been investigated which in each cases, the radius of gyration and auto correlation velocity of different polymer membrane cases have been compared together. This simulation method in addition of probably helping understand natural myosin displacement mechanism, can be extended to design the contraction of an artificial muscle tissue close to nature.

DIFFUSION APPROXIMATION FOR TRANSPORT PROCESSES WITH GENERAL REFLECTION BOUNDARY CONDITIONS

2006 ◽  
Vol 16 (05) ◽  
pp. 717-762 ◽  
Author(s):  
CRISTINA COSTANTINI ◽  
THOMAS G. KURTZ
Keyword(s):  
Boundary Conditions ◽  
Stochastic Averaging ◽  
Transport Processes ◽  
Collision Kernel ◽  
Diffusion Approximations ◽  
Transport Models ◽  
Scattering Kernel ◽  
Reflection Boundary ◽  
Averaging Techniques ◽  
Number Of Particles

Diffusion approximations are obtained for space inhomogeneous linear transport models with reflection boundary conditions. The collision kernel is not required to satisfy any balance condition and the scattering kernel on the boundary is general enough to include all examples of boundary conditions known to the authors (with conservation of the number of particles) and, in addition, to model the Debye sheath. The mathematical approach does not rely on Hilbert expansions, but rather on martingale and stochastic averaging techniques.

Electric-Field Induced Formation of Superconducting Granular Balls

2002 ◽  
Vol 16 (17n18) ◽  
pp. 2529-2535
Author(s):  
R. Tao ◽  
X. Xu ◽  
Y. C. Lan
Keyword(s):  
Surface Energy ◽  
Electric Field ◽  
Liquid Nitrogen ◽  
Applied Electric Field ◽  
Strong Electric Field ◽  
Particle Surface ◽  
Cooper Pairs ◽  
Surface Charges

When a strong electric field is applied to a suspension of micron-sized high T c superconducting particles in liquid nitrogen, the particles quickly aggregate together to form millimeter-size balls. The balls are sturdy, surviving constant heavy collisions with the electrodes, while they hold over 106 particles each. The phenomenon is a result of interaction between Cooper pairs and the strong electric field. The strong electric field induces surface charges on the particle surface. When the applied electric field is strong enough, Cooper pairs near the surface are depleted, leading to a positive surface energy. The minimization of this surface energy leads to the aggregation of particles to form balls.

Simulations of electric field at the initiation altitudes of sprites and halos generated by the thundercloud charge structure and lightning channels of causative return strokes

2021 ◽  
Author(s):  
Petr Kaspar ◽  
Ivana Kolmasova ◽  
Ondrej Santolik ◽  
Martin Popek ◽  
Pavel Spurny ◽  
...  
Keyword(s):  
Electromagnetic Field ◽  
Electric Field ◽  
Boundary Conditions ◽  
Free Space ◽  
Nonlinear Effects ◽  
Charge Structure ◽  
Transient Luminous Events ◽  
Lightning Channel ◽  
Free Parameters

<p><span>Sprites and halos are transient luminous events occurring above thunderclouds. They can be observed simultaneously or they can also appear individually. Circumstances leading to initiation of these events are still not completely understood. In order to clarify the role of lightning channels of causative lightning return strokes and the corresponding thundercloud charge structure, we have developed a new model of electric field amplitudes at halo/sprite altitudes. It consists of electrostatic and inductive components of the electromagnetic field generated by the lightning channel in free space at a height of 15 km. Above this altitude we solve Maxwell’s equations self-consistently including the nonlinear effects of heating and ionization/attachment of the electrons. At the same time, we investigate the role of a development of the thundercloud charge structure and related induced charges above the thundercloud. We show how these charges lead to the different distributions of the electric field at the initiation heights of the halos and sprites. We adjust free parameters of the model using observations of halos and sprites at the Nydek TLE observatory and using measurements of luminosity curves of the corresponding return strokes measured by an array of fast photometers. The latter measurements are also used to set the boundary conditions of the model.</span></p>

scholarly journals Dissipationof Energyofan AC Electric Fieldina Semi-Infinit Electron Plasma with Diffusive Boundary Conditions

2020 ◽  
Vol 14 ◽  
Keyword(s):  
Electric Field ◽  
Boundary Conditions ◽  
Electron Plasma ◽  
Surface Absorption ◽  
Ac Electric Field ◽  
Plasma Response ◽  
Diffusive Boundary

Let us consider the electron plasma response with an arbitary degree of degeneracy to an external ac electric field. Surface absorption of the energy of an electric field is calculated.

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