scholarly journals Provenance signals in metaturbidites of the Paleoproterozoic greenstone belt of the Guiana Shield in Suriname

2016 ◽  
Vol 95 (4) ◽  
pp. 467-489 ◽  
Author(s):  
R. Naipal ◽  
S.B. Kroonenberg

AbstractThe sedimentological, metamorphic, petrographic and geochemical characteristics of the Armina Formation, part of the Paleoproterozoic Greenstone Belt of Suriname in South America, are described, based on field, geochemical and petrographic evidence obtained through fieldwork along the Marowijne River and study of diamond drill cores from Rosebel Gold Mine (RGM). The metagreywackes show characteristic features of deposition by turbidity currents: coarse-grained, poorly sorted graded greywackes, covered by fine-grained, parallel-laminated phyllitic beds, often with convolute structures and climbing ripples. Their immature character and composition suggest deposition in an arc-trench environment. In the Marowijne River three different facies of metagreywackes are distinguished: (1) the greyish Bonnidoro Falls facies, characterised by common red millimetre-sized pseudomorphs after siderite in the finer beds, (2) the green Paroe Tabiki metagreywacke facies, with decimetre-sized calcsilicate nodules, both metamorphosed in the lower greenschist facies with chlorite as the main mafic mineral, and (3) the grey Armina Falls metagreywacke facies, geochemically similar to the Bonnidoro type but of higher metamorphic grade with biotite as the main mafic mineral. The metagreywackes from the Marowijne River show a predominance of quartz, plagioclase and lithic (tonalitic) clasts, suggesting exhumation of tonalite–trondhjemite–granodiorite plutons before deposition of the turbidites. There is a slight increase in maturity from (1) to (3), suggesting increasing weathering in the source areas. The metagreywackes of the RGM (JZone) have a predominantly metavolcanic origin, suggesting that they have a different provenance area than the Marowijne metagreywackes. Geochemically the spread in composition within each facies is larger than between the facies because of the wide range in grain sizes in each turbidite sequence. A large part of the rocks from the RGM, classified by previous authors as arenites, are geochemically and petrographically metagreywackes. Only a few RGM samples are real arenites, and plot as a separate cluster in geochemical factor score plots because of their low Fe and Na contents.

2018 ◽  
Author(s):  
Roberto Köferstein

The formation of BaCeO3 by a co-precipitation method is described herein. The coprecipitationroute leads to an orange (BaCe)-precursor powder (1). To improve the sinteringbehaviour, a small amount of Ge4+ was incorporated, leading to a (BaCe0.95/Ge0.05)-precursor(2). Both precursor powders results in fine-grained preceramic powders (1A, 2A) aftercalcination. The shrinkage and sintering behaviour of resulting powder compacts were studiedin comparison to a coarse-grained mixed-oxide BaCeO3 powder (3). Compacts of 2A reach arelative density of 90 % after sintering at 1350 °C with grain-sizes between 0.9−3.2 μm. Onthe other hand ceramics of 1A and 3 have, after sintering at 1500 °C (10 h), relative densitiesof 85 % and 76 %, respectively. Ceramic bodies of 1A consisted of phase-pure orthorhombicBaCeO3, whereas bodies of 2A show reflections of BaCeO3 and a Ba2GeO4 phase. DTAinvestigations of samples 1A and 2A reveal three phase transitions at 255 °C (1A) and 256 °C (2A) as well as 383 °C (1A) and 380 °C (2A). A very weak one can be obtained in the range880−910 °C


2021 ◽  
Author(s):  
◽  
Clifford Barrie Atkins

<p>Linear abrasion features on rock surfaces are produced by interacting rock particles in relative motion. The most common examples are striae produced by temperate glaciers, and as a consequence, striae have long been used as a means of identifying the passage of past glaciers. However, there are many non-glacial processes that can produce striae. These have been sporadically documented in the geological literature but have failed to make a lasting impression on the wider Earth Sciences community. These non-glacial processes include tectonic deformation, meltwater flow, non-glacial ice, wind action, volcanic blasting, mass movements of rock debris, among many others. Many produce coarse-grained deposits similar in character to glacial tills and there are several instances where non-glacial deposits and striae have been misinterpreted as glacial in origin. This thesis examines linear abrasion features (mostly striae) from five different environments, three glacial (temperate, polythermal and cold) and two non-glacial environments (mass movement and tectonic) to characterise the striae from different origins. The aim was to assess if there are readily observable and measurable differences in striae character between environments and to develop field-based criteria that allow a sound judgement of their origin in the geological record. Over 760 measurements of individual striae were made (orientation and size) on around 20 representative clasts and characteristic features of about 50 striated clasts from the various environments are illustrated in an "Atlas of linear abrasion features". In addition clast shape and striae occurrence were measured on 1260 clasts from deposits and about 100 bedrock linear abrasions from a cold-based glacier were recorded. The results show that some striae are diagnostic of certain environments but a combination of clast shape and striae characteristics is the most reliable method of correctly interpreting coarse-grained deposits with striated clasts. Results also highlight the wide range of striae characteristics within each environment and the importance of lithology in striae generation. This is evident even within the well-known temperate glacial environment where there is a marked contrast between striae formed within a thick debris layer and those formed in thin debris-rich basal ice. There appears to be little difference in striae formed by temperate and polyhermal glaciers, but glacial striae are readily distinguishable from striae found in various mass movement deposits or tectonically deformed conglomerates. Glacial striae tend to be sub-parallel to the clast long axes and show a high density on individual surfaces, whereas those in non-glacial origin typically show a lower density of slightly shorter, wider striae and show either no preferred orientation or weak grouping. The survivability of glacial abrasion features of clasts once they have entered a fluvial system has been assessed in a small South Island glacier fed river. This has provided a basis for estimating the proximity of a glaciofluvial deposit to the glacier front. Striae are found to survive only 1 to 2 km and glacial facets are mostly removed within 6 km. The study has also documented previously undescribed linear abrasion features from a cold-based glacier in Antarctica. This discovery is a significant advance in understanding cold glacial processes, and has provided new criteria for recognising the passage of cold-based glaciers in polar areas or regions where cold-based ice may have existed in the past.</p>


1981 ◽  
Vol 32 (6) ◽  
pp. 935 ◽  
Author(s):  
DR Hudson ◽  
RA Hunter ◽  
DW Peter

Grain size of elemental selenium is a major factor controlling the long-term effectiveness of intraruminal selenium pellets. Microscope studies of polished sections of new and used selenium pellets showed that two commercially manufactured pellets contained selenium with average grain sizes about 4 and 40 �m respectively. Plasma selenium concentrations in sheep treated with pellets containing the coarse-grained selenium were maintained at higher levels over longer periods of time than those measured for sheep treated with pellets with fine-grained selenium. Pellets removed from sheep after 2, 4, 8, 16 and 28 days showed a progressive increase in the degree of alteration of selenium to a compound of average composition (g/100 g) iron, 33.7; selenium, 51.3 ; oxygen, 15.0. After 28 days only a small percentage of elemental selenium remained in pellets with fine-grained selenium, whereas about 50% remained in pellets with coarse-grained selenium. CSIRO prototype pellets, for which long-term effectiveness had been established, also contained coarse-grained selenium, and remnants of selenium were found in pellets that had been in sheep for periods up to 3 years. Selenium, administered in gelatin capsules or as sachets containing glass-selenium mixtures, was stable under the pH-Eh conditions of the rumen, but was rendered unstable in selenium pellets or iron-selenium mixtures by the presence of iron. It is probable that the most rapid release of selenium to the sheep occurs as a result of a chemical reaction involving the oxidation of iron and concomitant alteration of elemental selenium to iron selenide.


MRS Advances ◽  
2016 ◽  
Vol 1 (12) ◽  
pp. 811-816 ◽  
Author(s):  
Myeong-heom Park ◽  
Akinobu Shibata ◽  
Nobuhiro Tsuji

ABSTRACTIt is well-known that dual phase (DP) steels composed of ferrite and martensite have good ductility and plasticity as well as high strength. Due to their excellent mechanical properties, DP steels are widely used in the industrial field. The mechanical properties of DP steels strongly depend on several factors such as fraction, distribution and grain size of each phase. In this study, the grain size effect on mechanical properties of DP steels was investigated. In order to obtain DP structures with different grain sizes, intercritical heat treatment in ferrite + austenite two-phase region was carried out for ferrite-pearlite structures having coarse and fine ferrite grain sizes. These ferrite-pearlite structures with coarse and fine grains were fabricated by two types of heat treatments; austenitizing heat treatment and repetitive heat treatment. Ferrite grain sizes of the specimens heat-treated by austenitizing and repetitive heat treatment were 47.5 µm (coarse grain) and 4.5 µm (fine grain), respectively. The ferrite grain sizes in the final DP structures fabricated from the coarse-grained and fine-grained ferrite-pearlite structures were 58.3 µm and 4.1µm, respectively. The mechanical behavior of the DP structures with different grain sizes was evaluated by an uniaxial tensile test at room temperature. The local strain distribution in the specimens during tensile test was obtained by a digital image correlation (DIC) technique. Results of the tensile test showed that the fine-grained DP structure had higher strength and larger elongation than the coarse-grained DP structure. It was found by the DIC analysis that the fine-grained DP structure showed homogeneous deformation compared with the coarse-grained DP structure.


Solid Earth ◽  
2019 ◽  
Vol 10 (4) ◽  
pp. 1099-1121 ◽  
Author(s):  
Károly Hidas ◽  
Carlos J. Garrido ◽  
Guillermo Booth-Rea ◽  
Claudio Marchesi ◽  
Jean-Louis Bodinier ◽  
...  

Abstract. Subduction-transform edge propagator (STEP) faults are the locus of continual lithospheric tearing at slab edges, resulting in sharp changes in the lithospheric and crustal thickness and triggering lateral and/or near-vertical mantle flow. However, the mechanisms at the lithospheric mantle scale are still poorly understood. Here, we present the microstructural study of olivine-rich lherzolite, harzburgite and wehrlite mantle xenoliths from the Oran volcanic field (Tell Atlas, northwest Algeria). This alkali volcanic field occurs along a major STEP fault responsible for the Miocene westward slab retreat in the westernmost Mediterranean. Mantle xenoliths provide a unique opportunity to investigate the microstructures in the mantle section of a STEP fault system. The microstructures of mantle xenoliths show a variable grain size ranging from coarse granular to fine-grained equigranular textures uncorrelated with lithology. The major element composition of the mantle peridotites provides temperature estimates in a wide range (790–1165 ∘C) but in general, the coarse-grained and fine-grained peridotites suggest deeper and shallower provenance depth, respectively. Olivine grain size in the fine-grained peridotites depends on the size and volume fraction of the pyroxene grains, which is consistent with pinning of olivine grain growth by pyroxenes as second-phase particles. In the coarse-grained peridotites, well-developed olivine crystal-preferred orientation (CPO) is characterized by orthorhombic and [100]-fiber symmetries, and orthopyroxene has a coherent CPO with that of olivine, suggesting their coeval deformation by dislocation creep at high temperature. In the fine-grained microstructures, along with the weakening of the fabric strength, olivine CPO symmetry exhibits a shift towards [010] fiber and the [010] and [001] axes of orthopyroxene are generally distributed subparallel to those of olivine. These data are consistent with deformation of olivine in the presence of low amounts of melts and the precipitation of orthopyroxenes from a melt phase. The bulk CPO of clinopyroxene mimics that of orthopyroxene via a topotaxial relationship of the two pyroxenes. This observation points to a melt-related origin of most clinopyroxenes in the Oran mantle xenoliths. The textural and geochemical record of the peridotites are consistent with interaction of a refractory harzburgite protolith with a high-Mg no. melt at depth (resulting in the formation of coarse-grained clinopyroxene-rich lherzolite and wehrlite) and with a low-Mg no. evolved melt in the shallow subcontinental lithospheric mantle (forming fine-grained harzburgite). We propose that pervasive melt–peridotite reaction – promoted by lateral and/or near-vertical mantle flow associated with lithospheric tearing – resulted in the synkinematic crystallization of secondary lherzolite and wehrlite and had a key effect on grain size reduction during the operation of the Tell–Rif STEP fault. Melt–rock reaction and secondary formation of lherzolite and wehrlite may be widespread in other STEP fault systems worldwide.


2007 ◽  
Vol 586 ◽  
pp. 119-145 ◽  
Author(s):  
SVETLANA KOSTIC ◽  
GARY PARKER

Turbidity currents act to sculpt the submarine environment through sediment erosion and deposition. A sufficiently swift turbidity current on a steep slope can be expected to be supercritical in the sense of the bulk Richardson number; a sufficiently tranquil turbidity current on a mild slope can be expected to be subcritical. The transition from supercritical to subcritical flow is accomplished through an internal hydraulic jump. Consider a steady turbidity current flowing from a steep canyon onto a milder fan, and then exiting the fan down another steep canyon. The flow might be expected to undergo a hydraulic jump to subcritical flow near the canyon–fan break, and then accelerate again to critical flow at the fan–canyon break downstream. The problem of locating the hydraulic jump is here termed the ‘jump problem’. Experiments with fine-grained sediment have confirmed the expected behaviour outlined above. Similar experiments with coarse-grained sediment suggest that if the deposition rate is sufficiently high, this ‘jump problem’ may have no solution with the expected behaviour, and in particular no solution with a hydraulic jump. In such cases, the flow either transits the length of the low-slope fan as a supercritical flow and shoots off the fan–canyon break without responding to it, or dissipates as a supercritical flow before exiting the fan. The analysis presented below confirms the existence of a range associated with rapid sediment deposition where no solution to the ‘jump problem’ can be found. The criterion for this range is stated in terms of an order-one dimensionless parameter involving the fall velocity of the sediment. The criterion is tested and confirmed against the experiments mentioned above. A sample field application is presented.


2010 ◽  
Vol 652 ◽  
pp. 149-154 ◽  
Author(s):  
Ondrej Muránsky ◽  
Matthew R. Barnett ◽  
David G. Carr ◽  
Sven C. Vogel ◽  
E.C. Oliver

In the present work in situ neutron diffraction and acoustic emission were used concurrently to study deformation twinning in two ZM20 Mg alloys with significantly different grain sizes at room temperature. The combination of these techniques allows differentionation between the twin nucleation and the twin growth mechanisms. It is shown, that yielding and immediate post-yielding plasticity in compression is governed primarily by twin nucleation, whereas the plasticity at higher strains is governed by twin growth. The current results further suggest that yielding by twinning happens in a slightly different manner in the fine-grained as compared to the coarse-grained alloy.


2010 ◽  
Vol 654-656 ◽  
pp. 294-297 ◽  
Author(s):  
Ghasem Dini ◽  
Rintaro Ueji ◽  
Abbas Najafizadeh

The effect of grain size on the flow stress in TWinning Induced Plasticity (TWIP) steel was investigated via the X-ray diffraction (XRD) measurements of dislocation density. The results indicated that the hardening behavior of fine grained samples (mean grain sizes in the range of 2.1-3.8μm) can be described as typical dislocation interactions. However in coarse grained samples (mean grain sizes in the range of 4.7-38.5μm) where extensive mechanical twinning occurs, another strengthening mechanism is required. Consequently, the effect of grain size on the flow stress parameters of the proposed equation was considered and it was found that in the fine grained samples, the Holloman analysis can describe the hardening behavior. However, in coarse grained samples, a second hardening term due to the strengthening effect of mechanical twin boundaries needs to be added to the Holloman equation.


2007 ◽  
Vol 46 (3) ◽  
pp. 295-309 ◽  
Author(s):  
David R. Sharpe ◽  
Susan E. Pullan ◽  
Timothy A. Warman

ABSTRACT Information from a wide range of sources is integrated in a basin analysis of the Wabigoon Basin, a Quaternary clay basin located on the Canadian Shield in northwestern Ontario. The basin sediments were deposited between 10.9 ka and 9.5 ka, along the margin of the Rainy Lobe of the Laurentide Ice Sheet, which formed the northern boundary of proglacial Lake Agassiz. The basin architecture is dominated by four major elements: end moraines, eskers, kames and a clay plain, all of which overlie irregular bedrock topography. End moraines, eskers and kames are composed mainly of a fining upward sequence of gravels and sands. The geometry of these sedimentary units, and their sedimentary structures indicates they were deposited mainly by high and low-density turbidity currents, on ice-marginal subaqueous outwash fans. Eskers contain a core of coarse gravel and sand deposited within subglacial meltwater conduits, overlain by subaqueous fan sediments deposited at the conduit mouth. Esker ridges were formed during conduit filling events and flanking deposits were formed when a conduit remained in use during ice-marginal retreat. Where conduits were shortlived, isolated subaqueous fans (kames) were formed. A depositional model is proposed which relates moraine formation to catastrophic releases of subglacial meltwater and sediment simultaneously along the entire margin of the Rainy Lobe. The clay plain forms a broad blanket of fine-grained, rhythmically-bedded sediment which obscures bedrock topography, and often buries esker and kame deposits. Seismic profiles and overburden drilling reveal deep (50-70 m) bedrock lows beneath the clay plain. These lows, oriented sub-parallel to the ice margin, acted as sediment traps, and were infilled by the deposits of underflows generated at the ice margin.


Clay Minerals ◽  
2016 ◽  
Vol 51 (3) ◽  
pp. 309-324 ◽  
Author(s):  
Ian Wilson ◽  
John Keeling

AbstractHalloysite with tubular morphology is formed in a wide range of geological environments from the alteration of various rock types. Intrusive acidic coarse-grained rocks, such as granites, pegmatites and anorthosite, with large potash and sodic feldspars contents, are subsequently altered to kaolinite, halloysite and other clay minerals by weathering or shallow hydrothermal fluid activity. Processing to separate the halloysite-kaolinite fraction from the altered host rock provides a product which can be used as a paper filler and in ceramics and fibreglass, among other uses, with various deposits in Brazil, China, Thailand and elsewhere. In the Kerikeri-Matauri Bay district of Northland, North Island, New Zealand, volcanic alkali rhyolite was extruded as domes and cooled rapidly with fine-grained feldspar subsequently altered to halloysite. The IMERYS plant in Matauri Bay separates the clay from the quartz-cristobalite matrix with an ∼20% yield of halloysite. The principal market is for high-quality porcelain and bone china that require low levels of Fe2O3 and TiO2. Deposits with high levels of halloysite occur in China, Turkey and the USA. The Dragon mine in Utah, USAwas recently reopened by Applied Minerals Inc. and now produces halloysite from zones of up to 100% white halloysite. Smaller occurrences of tubular halloysite are mined in China, Turkey and elsewhere from masses of comparatively pure clay that appear to have crystallized directly from solutions in which Al and Si were soluble.


Sign in / Sign up

Export Citation Format

Share Document