scholarly journals Isotopic variations of meltwater from ice by isotopic exchange between liquid water and ice

2019 ◽  
Vol 65 (254) ◽  
pp. 1035-1043 ◽  
Author(s):  
Ji-Young Ham ◽  
Soon Do Hur ◽  
Won Sang Lee ◽  
Yeongcheol Han ◽  
Hyejung Jung ◽  
...  
Keyword(s):  
Rate Constant ◽  
Liquid Water ◽  
Isotopic Exchange ◽  
Water Saturation ◽  
Isotopic Ratio ◽  
Cold Room ◽  
Exchange Rate Constant ◽  
Oxygen Isotopic ◽  
Two Parameters ◽  
Ice Water

AbstractPredicting the isotopic modification of ice by melting processes is important for improving the accuracy in paleoclimate reconstruction. To this end, we present results from cold room laboratory observations of changes in the isotopic ratio (D/H and 18O/16O) of ice cubes by isotopic exchange between liquid water and ice in nearly isothermal conditions. A 1-D model was fit to the isotopic results by adjusting the values of two parameters, the isotopic exchange rate constant (kr) and the fraction of ice participating in the exchange (f). We found that the rate constant for hydrogen isotopic exchange between liquid water and ice may be greater (up to 40%) than that for the oxygen isotopic exchange. The range of the rate constant obtained from four melt experiments is from 0.21 to 0.82 h–1. The model results also suggest that f decreases with the increasing wetness of the ice. This is because with increasing water saturation in ice, water may be present only in the small pores or some of the water that was exchanged with ice may be bypassed, decreasing the effective surface area over which the isotopic exchange can occur. The relationship between the two water isotopes (δ18O vs δD) was observed and modeled and the slope was <8, which is significantly different from the slope of the meteoric waterline. We note that these slopes were obtained without considering the sublimation process.

Stable isotopic exchange rate constant between snow and liquid water

2009 ◽  
Vol 260 (1-2) ◽  
pp. 57-62 ◽  
Author(s):  
Jeonghoon Lee ◽  
Xiahong Feng ◽  
Eric S. Posmentier ◽  
Anthony M. Faiia ◽  
Susan Taylor
Keyword(s):  
Exchange Rate ◽  
Rate Constant ◽  
Liquid Water ◽  
Isotopic Exchange ◽  
Stable Isotopic ◽  
Exchange Rate Constant

scholarly journals Measuring ice- and liquid-water properties in mixed-phase cloud layers at the Leipzig Cloudnet station

2016 ◽  
Vol 16 (16) ◽  
pp. 10609-10620 ◽  
Author(s):  
Johannes Bühl ◽  
Patric Seifert ◽  
Alexander Myagkov ◽  
Albert Ansmann
Keyword(s):  
Water Content ◽  
Liquid Water ◽  
Mass Flux ◽  
Mixed Phase ◽  
Cloud Base ◽  
Doppler Velocity ◽  
Special Focus ◽  
Data Set ◽  
Ice Water Content ◽  
Ice Water

Abstract. An analysis of the Cloudnet data set collected at Leipzig, Germany, with special focus on mixed-phase layered clouds is presented. We derive liquid- and ice-water content together with vertical motions of ice particles falling through cloud base. The ice mass flux is calculated by combining measurements of ice-water content and particle Doppler velocity. The efficiency of heterogeneous ice formation and its impact on cloud lifetime is estimated for different cloud-top temperatures by relating the ice mass flux and the liquid-water content at cloud top. Cloud radar measurements of polarization and Doppler velocity indicate that ice crystals formed in mixed-phase cloud layers with a geometrical thickness of less than 350 m are mostly pristine when they fall out of the cloud.

Variational Assimilation of Cloud Liquid/Ice Water Path and Its Impact on NWP

2015 ◽  
Vol 54 (8) ◽  
pp. 1809-1825 ◽  
Author(s):  
Yaodeng Chen ◽  
Hongli Wang ◽  
Jinzhong Min ◽  
Xiang-Yu Huang ◽  
Patrick Minnis ◽  
...  
Keyword(s):  
Data Assimilation ◽  
Liquid Water ◽  
Weather Prediction ◽  
Wrf Model ◽  
Liquid Water Path ◽  
Cloud Liquid Water ◽  
Water Path ◽  
Ice Water Path ◽  
Ice Water ◽  
The Impact

AbstractAnalysis of the cloud components in numerical weather prediction models using advanced data assimilation techniques has been a prime topic in recent years. In this research, the variational data assimilation (DA) system for the Weather Research and Forecasting (WRF) Model (WRFDA) is further developed to assimilate satellite cloud products that will produce the cloud liquid water and ice water analysis. Observation operators for the cloud liquid water path and cloud ice water path are developed and incorporated into the WRFDA system. The updated system is tested by assimilating cloud liquid water path and cloud ice water path observations from Global Geostationary Gridded Cloud Products at NASA. To assess the impact of cloud liquid/ice water path data assimilation on short-term regional numerical weather prediction (NWP), 3-hourly cycling data assimilation and forecast experiments with and without the use of the cloud liquid/ice water paths are conducted. It is shown that assimilating cloud liquid/ice water paths increases the accuracy of temperature, humidity, and wind analyses at model levels between 300 and 150 hPa after 5 cycles (15 h). It is also shown that assimilating cloud liquid/ice water paths significantly reduces forecast errors in temperature and wind at model levels between 300 and 150 hPa. The precipitation forecast skills are improved as well. One reason that leads to the improved analysis and forecast is that the 3-hourly rapid update cycle carries over the impact of cloud information from the previous cycles spun up by the WRF Model.

scholarly journals Selecting Characteristic Raman Wavelengths to Distinguish Liquid Water, Water Vapor, and Ice Water

2010 ◽  
Vol 14 (3) ◽  
pp. 209-214 ◽  
Author(s):  
Sun-Ho Park ◽  
Yong-Gi Kim ◽  
Duk-Hyeon Kim ◽  
Hai-Du Cheong ◽  
Won-Seok Choi ◽  
...  
Keyword(s):  
Water Vapor ◽  
Liquid Water ◽  
Ice Water

scholarly journals Snow dielectric properties: from DC to microwave X-band

1994 ◽  
Vol 19 ◽  
pp. 92-96 ◽  
Author(s):  
TH. Achammer ◽  
A. Denoth
Keyword(s):  
Grain Size ◽  
Dielectric Properties ◽  
Water Content ◽  
Liquid Water ◽  
Liquid Water Content ◽  
Frequency Range ◽  
Snow Density ◽  
Cold Room ◽  
X Band ◽  
Grain Size And Shape

Broadband measurements of dielectric properties of natural snow samples near or at 0°C are reported. Measurement quantities are: dielectric permittivity, loss factor and complex propagation factor for electromagnetic waves. X-band measurements were made in a cold room in the laboratory; measurements at low and intermediate frequencies were carried out both in the field (Stubai Alps, 3300 m; Hafelekar near Innsbruck, 2100 m) and in the cold room. Results show that in the different frequency ranges the relative effect on snow dielectric properties of the parameters: density, grain-size and shape, liquid water content, shape and distribution of liquid inclusions and content of impurities, varies significantly. In the low-frequency range the influence of grain-size and shape and snow density dominates; in the medium-frequency range liquid water content and density are the dominant parameters. In the microwave X-band the influence of the amount, shape and distribution of liquid inclusions and snow density is more important than that of the remaining parameters.

scholarly journals The Impacts of Atmospheric and Surface Parameters on Long-Term Variations in the Planetary Albedo

2018 ◽  
Vol 31 (21) ◽  
pp. 8705-8718 ◽  
Author(s):  
Bida Jian ◽  
Jiming Li ◽  
Guoyin Wang ◽  
Yongli He ◽  
Ying Han ◽  
...  
Keyword(s):  
Liquid Water ◽  
Surface Albedo ◽  
Cloud Fraction ◽  
Liquid Water Path ◽  
Water Path ◽  
Ice Water Path ◽  
Planetary Albedo ◽  
Ice Water ◽  
Long Term Variations

Planetary albedo (PA; shortwave broadband albedo) and its long-term variations, which are controlled in a complex way by various atmospheric and surface properties, play a key role in controlling the global and regional energy budget. This study investigates the contributions of different atmospheric and surface properties to the long-term variations of PA based on 13 years (2003–15) of albedo, cloud, and ice coverage datasets from the Clouds and the Earth’s Radiant Energy System (CERES) Single Scanner Footprint edition 4A product, vegetation product from Moderate Resolution Imaging Spectroradiometer (MODIS), and surface albedo product from the Cloud, Albedo, and Radiation dataset, version 2 (CLARA-A2). According to the temporal correlation analysis, statistical results indicate that variations in PA are closely related to the variations of cloud properties (e.g., cloud fraction, ice water path, and liquid water path) and surface parameters (e.g., ice/snow percent coverage and normalized difference vegetation index), but their temporal relationships vary among the different regions. Generally, the stepwise multiple linear regression models can capture the observed PA anomalies for most regions. Based on the contribution calculation, cloud fraction dominates the variability of PA in the mid- and low latitudes while ice/snow percent coverage (or surface albedo) dominates the variability in the mid- and high latitudes. Changes in cloud liquid water path and ice water path are the secondary dominant factor over most regions, whereas change in vegetation cover is the least important factor over land. These results verify the effects of atmospheric and surface factors on planetary albedo changes and thus may be of benefit for improving the parameterization of the PA and determining the climate feedbacks.

Predicting Liquid Water Saturation Through Differently Structured Cathode Gas Diffusion Media of a Proton Exchange Membrane Fuel Cell

2012 ◽  
Vol 9 (2) ◽  
Author(s):  
N. Akhtar ◽  
P. J. A. M. Kerkhof
Keyword(s):  
Fuel Cell ◽  
Liquid Water ◽  
Proton Exchange Membrane ◽  
Water Saturation ◽  
Catalyst Layer ◽  
Gas Diffusion ◽  
Proton Exchange ◽  
Diffusion Media ◽  
Exchange Membrane

The role of gas diffusion media with differently structured properties have been examined with emphasis on the liquid water saturation within the cathode of a proton exchange membrane fuel cell (PEMFC). The cathode electrode consists of a gas diffusion layer (GDL), a micro-porous layer and a catalyst layer (CL). The liquid water saturation profiles have been calculated for varying structural and physical properties, i.e., porosity, permeability, thickness and contact angle for each of these layers. It has been observed that each layer has its own role in determining the liquid water saturation within the CL. Among all the layers, the GDL is the most influential layer that governs the transport phenomena within the PEMFC cathode. Besides, the thickness of the CL also affects the liquid water saturation and it should be carefully controlled.

Pressure effect on hydrogen isotope exchange kinetics in chymotrypsinogen investigated by FT-IR spectroscopy

1991 ◽  
Vol 69 (11) ◽  
pp. 1699-1704 ◽  
Author(s):  
P. T. T. Wong
Keyword(s):  
High Pressure ◽  
Exchange Rate ◽  
Rate Constant ◽  
Bound Water ◽  
Pressure Effects ◽  
Protein Molecules ◽  
Fast Exchange ◽  
Exchange Rate Constant ◽  
Hydrogen Deuterium ◽  
Exchange Kinetics

Hydrogen/deuterium (H/D) exchange rate constants in chymotrypsinogen have been determined at several pressures up to 28.9 kbar by FTIR spectroscopy. The secondary structure of the protein molecules was monitored simultaneously at the corresponding pressures by the intensity redistribution of the infrared amide I band at these pressures. As in other proteins, the labile protons on the amide groups in chymotrypsinogen can, to a good approximation, be separated into two classes, each with distinct first order H/D exchange rates constants in the time period from 10 min to ~24 h. The fast exchange rate constant increases while the slow exchange rate constant decreases with increasing pressure. The increase in the fast exchange rate constant at high pressure is largely associated with the pressure-induced unfolding of the protein molecules. At extremely high pressure (12.8 kbar), in addition to the unfolding of protein molecules, pressure induced a distortion and weakening of the hydrogen bonds of the fold protein segments also contribute to an increase in the overall H/D exchange rate. The present results confirm that when chymotrypsinogen is dissolved in D2O, a considerable amount of D2O molecules is bound to the protein molecules on the surface as well as in the interior cavities of the molecules. The H/D exchange takes place between these bound D2O and the protons in the protein molecules. The mechanism of the H/D exchange and the interior dynamics in proteins are discussed on the basis of the present results. Key words: hydrogen/deuterium exchange, exchange kinetics, rate constant, pressure effects, infrared spectroscopy, protein, conformation structure, bound water.

Sign in / Sign up

Export Citation Format

Share Document