scholarly journals The asymptotics of the moving contact line: cracking an old nut

2015 ◽  
Vol 764 ◽  
pp. 445-462 ◽  
Author(s):  
David N. Sibley ◽  
Andreas Nold ◽  
Serafim Kalliadasis

AbstractFor contact line motion where the full Stokes flow equations hold, full matched asymptotic solutions using slip models have been obtained for droplet spreading and more general geometries. These solutions to the singular perturbation problem in the slip length, however, all involve matching through an intermediate region that is taken to be separate from the outer–inner regions. Here, we show that the intermediate region is in fact an overlap region representing extensions of both the outer and the inner region, allowing direct matching to proceed. In particular, we investigate in detail how a previously seen result of the matching of the cubes of the free surface slope is justified in the lubrication setting. We also extend this two-region direct matching to the more general Stokes flow case, offering a new perspective on the asymptotics of the moving contact line problem.

2013 ◽  
Vol 715 ◽  
pp. 283-313 ◽  
Author(s):  
Yi Sui ◽  
Peter D. M. Spelt

AbstractUsing a slip-length-based level-set approach with adaptive mesh refinement, we have simulated axisymmetric droplet spreading for a dimensionless slip length down to $O(1{0}^{\ensuremath{-} 4} )$. The main purpose is to validate, and where necessary improve, the asymptotic analysis of Cox (J. Fluid Mech., vol. 357, 1998, pp. 249–278) for rapid droplet spreading/dewetting, in terms of the detailed interface shape in various regions close to the moving contact line and the relation between the apparent angle and the capillary number based on the instantaneous contact-line speed, $\mathit{Ca}$. Before presenting results for inertial spreading, simulation results are compared in detail with the theory of Hocking & Rivers (J. Fluid Mech., vol. 121, 1982, pp. 425–442) for slow spreading, showing that these agree very well (and in detail) for such small slip-length values, although limitations in the theoretically predicted interface shape are identified; a simple extension of the theory to viscous exterior fluids is also proposed and shown to yield similar excellent agreement. For rapid droplet spreading, it is found that, in principle, the theory of Cox can predict accurately the interface shapes in the intermediate viscous sublayer, although the inviscid sublayer can only be well presented when capillary-type waves are outside the contact-line region. However, $O(1)$ parameters taken to be unity by Cox must be specified and terms be corrected to ${\mathit{Ca}}^{+ 1} $ in order to achieve good agreement between the theory and the simulation, both of which are undertaken here. We also find that the apparent angle from numerical simulation, obtained by extrapolating the interface shape from the macro region to the contact line, agrees reasonably well with the modified theory of Cox. A simplified version of the inertial theory is proposed in the limit of negligible viscosity of the external fluid. Building on these results, weinvestigate the flow structure near the contact line, the shear stress and pressure along the wall, and the use of the analysis for droplet impact and rapid dewetting. Finally, we compare the modified theory of Cox with a recent experiment for rapid droplet spreading, the results of which suggest a spreading-velocity-dependent dynamic contact angle in the experiments. The paper is closed with a discussion of the outlook regarding the potential of using the present results in large-scale simulations wherein the contact-line region is not resolved down to the slip length, especially for inertial spreading.


1976 ◽  
Vol 77 (4) ◽  
pp. 665-684 ◽  
Author(s):  
E. B. Dussan V.

The singularity at the contact line which is present when the usual fluidmechanical modelling assumptions are made is removed by permitting the fluid to slip along the wall. The aim of this study is to assess the sensitivity of the overall flow field to the form of the slip boundary condition. Explicit solutions are obtained for three different slip boundary conditions. Two length scales emerge: the slip length scale and the meniscus length scale. It is found that on the slip length scale the flow fields are quite different; however, when viewed on the meniscus length scale, i.e. the length scale on which almost all fluidmechanical measurements are made, all of the flow fields appear the same. It is found that the characteristic of the slip boundary condition which affects the overall flow field is the magnitude of the slip length.


Author(s):  
Shaofan Li ◽  
Houfu Fan

In this paper, a multiscale moving contact line (MMCL) theory is presented and employed to simulate liquid droplet spreading and capillary motion. The proposed MMCL theory combines a coarse-grained adhesive contact model with a fluid interface membrane theory, so that it can couple molecular scale adhesive interaction and surface tension with hydrodynamics of microscale flow. By doing so, the intermolecular force, the van der Waals or double layer force, separates and levitates the liquid droplet from the supporting solid substrate, which avoids the shear stress singularity caused by the no-slip condition in conventional hydrodynamics theory of moving contact line. Thus, the MMCL allows the difference of the surface energies and surface stresses to drive droplet spreading naturally. To validate the proposed MMCL theory, we have employed it to simulate droplet spreading over various elastic substrates. The numerical simulation results obtained by using MMCL are in good agreement with the molecular dynamics results reported in the literature.


2015 ◽  
Vol 788 ◽  
pp. 209-227 ◽  
Author(s):  
H. Kusumaatmaja ◽  
E. J. Hemingway ◽  
S. M. Fielding

We reconcile two scaling laws that have been proposed in the literature for the slip length associated with a moving contact line in diffuse interface models, by demonstrating each to apply in a different regime of the ratio of the microscopic interfacial width $l$ and the macroscopic diffusive length $l_{D}=(M{\it\eta})^{1/2}$, where ${\it\eta}$ is the fluid viscosity and $M$ the mobility governing intermolecular diffusion. For small $l_{D}/l$ we find a diffuse interface regime in which the slip length scales as ${\it\xi}\sim (l_{D}l)^{1/2}$. For larger $l_{D}/l>1$ we find a sharp interface regime in which the slip length depends only on the diffusive length, ${\it\xi}\sim l_{D}\sim (M{\it\eta})^{1/2}$, and therefore only on the macroscopic variables ${\it\eta}$ and $M$, independent of the microscopic interfacial width $l$. We also give evidence that modifying the microscopic interfacial terms in the model’s free energy functional appears to affect the value of the slip length only in the diffuse interface regime, consistent with the slip length depending only on macroscopic variables in the sharp interface regime. Finally, we demonstrate the dependence of the dynamic contact angle on the capillary number to be in excellent agreement with the theoretical prediction of Cox (J. Fluid Mech., vol. 168, 1986, p. 169), provided we allow the slip length to be rescaled by a dimensionless prefactor. This prefactor appears to converge to unity in the sharp interface limit, but is smaller in the diffuse interface limit. The excellent agreement of results obtained using three independent numerical methods, across several decades of the relevant dimensionless variables, demonstrates our findings to be free of numerical artefacts.


2020 ◽  
Vol 229 (10) ◽  
pp. 1897-1921 ◽  
Author(s):  
Uǧis Lācis ◽  
Petter Johansson ◽  
Tomas Fullana ◽  
Berk Hess ◽  
Gustav Amberg ◽  
...  

Abstract The movement of the triple contact line plays a crucial role in many applications such as ink-jet printing, liquid coating and drainage (imbibition) in porous media. To design accurate computational tools for these applications, predictive models of the moving contact line are needed. However, the basic mechanisms responsible for movement of the triple contact line are not well understood but still debated. We investigate the movement of the contact line between water, vapour and a silica-like solid surface under steady conditions in low capillary number regime. We use molecular dynamics (MD) with an atomistic water model to simulate a nanoscopic drop between two moving plates. We include hydrogen bonding between the water molecules and the solid substrate, which leads to a sub-molecular slip length. We benchmark two continuum methods, the Cahn–Hilliard phase-field (PF) model and a volume-of-fluid (VOF) model, against MD results. We show that both continuum models reproduce the statistical measures obtained from MD reasonably well, with a trade-off in accuracy. We demonstrate the importance of the phase-field mobility parameter and the local slip length in accurately modelling the moving contact line.


2004 ◽  
Vol 16 (5) ◽  
pp. 1647-1659 ◽  
Author(s):  
Ali Mazouchi ◽  
C. M. Gramlich ◽  
G. M. Homsy

2001 ◽  
Vol 11 (PR6) ◽  
pp. Pr6-199-Pr6-212 ◽  
Author(s):  
Y. Pomeau

Sign in / Sign up

Export Citation Format

Share Document