scholarly journals The kinetics of ice-lens growth in porous media

2012 ◽  
Vol 692 ◽  
pp. 482-498 ◽  
Author(s):  
Robert W. Style ◽  
Stephen S. L. Peppin
Keyword(s):  
Growth Rate ◽  
Porous Medium ◽  
Porous Media ◽  
Coarse Grained ◽  
Interfacial Resistance ◽  
Significant Drop ◽  
Ice Growth ◽  
External Pressures ◽  
Lens Growth ◽  
Kinetics Of

AbstractWe analyse the growth rate of segregated ice (ice lenses) in freezing porous media. For typical colloidal materials such as soils we show that the commonly employed Clapeyron equation is not valid macroscopically at the interface between the ice lens and the surrounding porous medium owing to the viscous dynamics of flow in premelted films. The flow in these films gives rise to an ‘interfacial resistance’ to flow towards the growing ice which causes a significant drop in predicted ice-growth (heave) rates. This explains why many previous models predict ice-growth rates that are much larger than those seen in experiments. We derive an explicit formula for the ice-growth rate in a given porous medium, and show that this only depends on temperature and on the external pressures imposed on the freezing system. This growth-rate formula contains a material-specific function which can be calculated (with knowledge of the geometry and material of the porous medium), but which is also readily experimentally measurable. We apply the formula to plate-like particles, and show that the results can be matched with previous experimental data. Finally we show how the interfacial resistance explains the observation that the maximum heave rate in soils occurs in medium-grained particles such as silts, while heave rates are smaller for fine- and coarse-grained particles.

scholarly journals Porous Medium Typology Influence on the Scaling Laws of Confined Aquifer Characteristic Parameters

Water ◽  
2020 ◽  
Vol 12 (4) ◽  
pp. 1166 ◽  
Author(s):  
Carmine Fallico ◽  
Agostino Lauria ◽  
Francesco Aristodemo
Keyword(s):  
Porous Medium ◽  
Porous Media ◽  
Hydraulic Conductivity ◽  
Scaling Laws ◽  
Scale Parameter ◽  
Effective Porosity ◽  
Coarse Grained ◽  
Characteristic Parameters ◽  
Porous Aquifer ◽  
Aquifer Characteristic

An accurate measurement campaign, carried out on a confined porous aquifer, expressly reproduced in laboratory, allowed the determining of hydraulic conductivity values by performing a series of slug tests. This was done for four porous medium configurations with different granulometric compositions. At the scale considered, intermediate between those of the laboratory and the field, the scalar behaviors of the hydraulic conductivity and the effective porosity was verified, determining the respective scaling laws. Moreover, assuming the effective porosity as scale parameter, the scaling laws of the hydraulic conductivity were determined for the different injection volumes of the slug test, determining a new relationship, valid for coarse-grained porous media. The results obtained allow the influence that the differences among the characteristics of the porous media considered exerted on the scaling laws obtained to be highlighted. Finally, a comparison was made with the results obtained in a previous investigation carried out at the field scale.

Numerical Approach to Statistical Mechanics of Surfactants in Porous Media: A Coarse Grained Description

1997 ◽  
Vol 08 (06) ◽  
pp. 1335-1343
Author(s):  
Prabal K. Maiti ◽  
Debashish Chowdhury
Keyword(s):  
Monte Carlo Simulation ◽  
Porous Medium ◽  
Porous Media ◽  
Monte Carlo ◽  
Numerical Scheme ◽  
Numerical Approach ◽  
Coarse Grained ◽  
Vycor Glass ◽  
Oil Water ◽  
Dynamical Scheme

We present a numerical scheme for Monte Carlo Simulation (MC) of ternary microemulsions, which consist of oil, water and surfactants, confined inside a porous medium such as vycor glass. The model porous medium has been created using the Cell Dynamical Scheme (CDS) while the microemulsion has been modeled following the Larson prescription.

Regulation of valine catabolism by ammonium in Streptomyces ambofaciens, producer of spiramycin

1995 ◽  
Vol 41 (9) ◽  
pp. 800-808 ◽  
Author(s):  
Anissa Lounès ◽  
Ahmed Lebrihi ◽  
Chouki Benslimane ◽  
Gérard Lefebvre ◽  
Pierre Germain
Keyword(s):  
Growth Rate ◽  
Growth Phase ◽  
Uptake Rate ◽  
Specific Growth ◽  
Ammonium Excretion ◽  
Ammonium Ions ◽  
Significant Drop ◽  
Streptomyces Ambofaciens ◽  
Negative Effect ◽  
Kinetics Of

In Streptomyces ambofaciens, valine favored spiramycin biosynthesis by supplying aglycone precursors. The kinetics of valine consumption and isobutyrate production showed that isobutyrate accumulated in the cell during the growth phase, was excreted in the stationary phase, and then was reassimilated during spiramycin production. When valine was in excess, its deamination led to high ammonium excretion and to a significant drop in spiramycin production. We demonstrated that ammonium ions were the cause of the negative effect. Addition of a chelator agent, Ca3(PO4)2, improved spiramycin production by sixfold. In contrast, addition of ammonium, between 0 and 48 h, severely reduced spiramycin production. The negative effect of ammonium was reversed by addition of a catabolic intermediate of valine, isobutyrate. In addition to stimulating the specific growth rate, ammonium ions slowed down valine catabolism: the specific valine uptake rate, excretion, and reassimilation of isobutyrate were lowered by the pulse of ammonium. Our study showed that in addition to valine dehydrogenase, which provided the nitrogen necessary to the cell, ammonium ions repressed ketoisovalerate dehydrogenase, which introduced valine as carbon, energy, and aglycone precursor sources. However, valine dehydrogenase and ketoisovalerate dehydrogenase did not constitute the principal enzymatic targets of the negative effect of ammonium in spiramycin production.Key words: spiramycin, Streptomyces ambofaciens, valine catabolism, ammonium.

Conservative solute transport with periodic velocity and sinusoidal source concentration in semi-infinite porous media: An analytical solution

2014 ◽  
Vol 6 (1) ◽  
pp. 1024-1031
Author(s):  
R R Yadav ◽  
Gulrana Gulrana ◽  
Dilip Kumar Jaiswal
Keyword(s):  
Porous Medium ◽  
Porous Media ◽  
Laplace Transformation ◽  
Seepage Velocity ◽  
Transformation Technique ◽  
Numerical Examples ◽  
One Dimensional ◽  
Porous Domain ◽  
Conservative Solute Transport ◽  
Source Concentration

The present paper has been focused mainly towards understanding of the various parameters affecting the transport of conservative solutes in horizontally semi-infinite porous media. A model is presented for simulating one-dimensional transport of solute considering the porous medium to be homogeneous, isotropic and adsorbing nature under the influence of periodic seepage velocity. Initially the porous domain is not solute free. The solute is initially introduced from a sinusoidal point source. The transport equation is solved analytically by using Laplace Transformation Technique. Alternate as an illustration; solutions for the present problem are illustrated by numerical examples and graphs.

Analysis of process of emulsions transport in hydrophilic/oleophilic granular porous media driven by capillary force

2018 ◽  
Vol 2 (21) ◽  
pp. 85-101
Author(s):  
Olga Shtyka ◽  
Łukasz Przybysz ◽  
Mariola Błaszczyk ◽  
Jerzy P. Sęk
Keyword(s):  
Porous Media ◽  
Experimental Research ◽  
Granular Media ◽  
Single Phase ◽  
Influential Factor ◽  
Dispersed Phase ◽  
Porous Structures ◽  
Phase Concentration ◽  
Granular Porous Media ◽  
Kinetics Of

The research focuses on the issues concerning a process of multiphase liquids transport in granular porous media driven by the capillary pressure. The current publication is meant to introduce the results of experimental research conducted to evaluate the kinetics of the imbibition and emulsions behavior inside the porous structures. Moreover, the influence of the dispersed phase concentration and granular media structure on the mentioned process was considered. The medium imbibition with emulsifier-stabilized emulsions composed of oil as the dispersed phase in concentrations of 10 vol%, 30 vol%, and 50 vol%, was investigated. The porous media consisted of oleophilic/hydrophilic beads with a fraction of 200–300 and 600–800 μm. The experimental results provided that the emulsions imbibition in such media depended stronger on its structure compare to single-phase liquids. The increase of the dispersed phase concentration caused an insignificant mass decreasing of the imbibed emulsions and height of its penetration in a sorptive medium. The concentrations of the imbibed dispersions exceeded their initial values, but reduced with permeants front raise in the granular structures that can be defined as the influential factor for wicking process kinetics.

Diffusion model for deposition of epitaxial GaAs layers prepared by the MOCVD method

1991 ◽  
Vol 56 (10) ◽  
pp. 2020-2029
Author(s):  
Jindřich Leitner ◽  
Petr Voňka ◽  
Josef Stejskal ◽  
Přemysl Klíma ◽  
Rudolf Hladina
Keyword(s):  
Experimental Data ◽  
Growth Rate ◽  
Kinetic Model ◽  
Gas Phase ◽  
Substrate Surface ◽  
Deposition Process ◽  
Hydrogen Atmosphere ◽  
Epitaxial Gaas ◽  
Kinetics Of ◽  
Good Agreement

The authors proposed and treated quantitatively a kinetic model for deposition of epitaxial GaAs layers prepared by reaction of trimethylgallium with arsine in hydrogen atmosphere. The transport of gallium to the surface of the substrate is considered as the controlling process. The influence of the rate of chemical reactions in the gas phase and on the substrate surface on the kinetics of the deposition process is neglected. The calculated dependence of the growth rate of the layers on the conditions of the deposition is in a good agreement with experimental data in the temperature range from 600 to 800°C.

Capillary Imbibition Dynamics in Porous Media

2014 ◽  
Author(s):  
Swayamdipta Bhaduri ◽  
Pankaj Sahu ◽  
Siddhartha Das ◽  
Aloke Kumar ◽  
Sushanta K. Mitra
Keyword(s):  
Porous Medium ◽  
Porous Media ◽  
Paper Strip ◽  
Capillary Imbibition ◽  
Flow Physics ◽  
Fundamental Understanding ◽  
Paper Based Microfluidics ◽  
To Come

The phenomenon of capillary imbibition through porous media is important both due to its applications in several disciplines as well as the involved fundamental flow physics in micro-nanoscales. In the present study, where a simple paper strip plays the role of a porous medium, we observe an extremely interesting and non-intuitive wicking or imbibition dynamics, through which we can separate water and dye particles by allowing the paper strip to come in contact with a dye solution. This result is extremely significant in the context of understanding paper-based microfluidics, and the manner in which the fundamental understanding of the capillary imbibition phenomenon in a porous medium can be used to devise a paper-based microfluidic separator.

scholarly journals Data-Driven Reduced-Order Modeling of Convective Heat Transfer in Porous Media

Fluids ◽  
2021 ◽  
Vol 6 (8) ◽  
pp. 266
Author(s):  
Péter German ◽  
Mauricio E. Tano ◽  
Carlo Fiorina ◽  
Jean C. Ragusa
Keyword(s):  
Heat Transfer ◽  
Porous Medium ◽  
Porous Media ◽  
Steady State ◽  
Convective Heat Transfer ◽  
Convective Heat ◽  
Data Driven ◽  
Reduced Order ◽  
Medium Formulation ◽  
Flow Resistances

This work presents a data-driven Reduced-Order Model (ROM) for parametric convective heat transfer problems in porous media. The intrusive Proper Orthogonal Decomposition aided Reduced-Basis (POD-RB) technique is employed to reduce the porous medium formulation of the incompressible Reynolds-Averaged Navier–Stokes (RANS) equations coupled with heat transfer. Instead of resolving the exact flow configuration with high fidelity, the porous medium formulation solves a homogenized flow in which the fluid-structure interactions are captured via volumetric flow resistances with nonlinear, semi-empirical friction correlations. A supremizer approach is implemented for the stabilization of the reduced fluid dynamics equations. The reduced nonlinear flow resistances are treated using the Discrete Empirical Interpolation Method (DEIM), while the turbulent eddy viscosity and diffusivity are approximated by adopting a Radial Basis Function (RBF) interpolation-based approach. The proposed method is tested using a 2D numerical model of the Molten Salt Fast Reactor (MSFR), which involves the simulation of both clean and porous medium regions in the same domain. For the steady-state example, five model parameters are considered to be uncertain: the magnitude of the pumping force, the external coolant temperature, the heat transfer coefficient, the thermal expansion coefficient, and the Prandtl number. For transient scenarios, on the other hand, the coastdown-time of the pump is the only uncertain parameter. The results indicate that the POD-RB-ROMs are suitable for the reduction of similar problems. The relative L2 errors are below 3.34% for every field of interest for all cases analyzed, while the speedup factors vary between 54 (transient) and 40,000 (steady-state).

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