Conformational preferences of the structures, and energetics of the molecular complexes of boron trifluoride with some hydrogen halides, halogens and interhalogens

2006 ◽  
Vol 771 (1-3) ◽  
pp. 157-164 ◽  
Author(s):  
Geoffrey A. Yeo ◽  
Thomas A. Ford
Keyword(s):  
Boron Trifluoride ◽  
Molecular Complexes ◽  
Hydrogen Halides ◽  
Conformational Preferences

Molecular complexes of heteroaromatic N-oxides with boron trifluoride

2014 ◽  
Vol 84 (2) ◽  
pp. 255-258
Author(s):  
V. P. Andreev ◽  
V. A. Tafeenko ◽  
S. N. Ivashevskaya
Keyword(s):  
Boron Trifluoride ◽  
Molecular Complexes

Complex fluoroanions in solution. IX. BF3–anion complexes and their disproportionation

1978 ◽  
Vol 56 (21) ◽  
pp. 2764-2767 ◽  
Author(s):  
S. Brownstein ◽  
G. Latremouille
Keyword(s):  
Boron Trifluoride ◽  
Coupling Constants ◽  
Hydrogen Halides ◽  
Anion Complexes ◽  
Strong Acids

Complex fluoroanions have been prepared with boron trifluoride and perchlorate, nitrate, nitrite, acetate, formate, azide, cyanide, cyanate, thiocyanate, and thiophenolate ions. The complexes formed from the anions of the strong acids, except the hydrogen halides, do not disproportionate to BF2(anion)2−. Complexes of anions of weaker acids may disproportionate and, or, complex a second molecule of BF3. Regularities in fluorine–boron coupling constants are tabulated.

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