A new method for generation of non-stabilized α-amino-substituted carbanions by the reaction of magnesium carbenoids with N-lithio arylamines: their reactivity and a new synthesis of α-amino acid derivatives

Tetrahedron ◽  
2006 ◽  
Vol 62 (33) ◽  
pp. 7892-7901 ◽  
Author(s):  
Tsuyoshi Satoh ◽  
Atsushi Osawa ◽  
Tohru Ohbayashi ◽  
Atsushi Kondo
2006 ◽  
Vol 47 (44) ◽  
pp. 7771-7774 ◽  
Author(s):  
David J. Hyett ◽  
Mara Didonè ◽  
Thierry J.A. Milcent ◽  
Quirinus B. Broxterman ◽  
Bernard Kaptein

2021 ◽  
Vol 66 (9) ◽  
pp. 1390-1395
Author(s):  
A. V. Nelyubin ◽  
N. A. Selivanov ◽  
I. N. Klyukin ◽  
A. Yu. Bykov ◽  
A. P. Zhdanov ◽  
...  

Abstract A new multistage synthesis of the N-borylated dipeptide B12-PheGlyOH has been proposed. The approach is based on the reaction of nucleophilic addition of amino acid derivatives to the [B12H11NCCH3]– anion. The products of each stage have been characterized by multinuclear NMR spectroscopy, IR absorption spectroscopy, and ESI mass spectrometry.


1998 ◽  
Vol 63 (11) ◽  
pp. 3528-3529 ◽  
Author(s):  
Richard S. Fornicola ◽  
Eric Oblinger ◽  
John Montgomery

2015 ◽  
Vol 51 (5) ◽  
pp. 832-835 ◽  
Author(s):  
Xiao-Hong Wei ◽  
Gang-Wei Wang ◽  
Shang-Dong Yang

A new method for the synthesis of chiral α-amino acid derivatives by enantioselective C–H arylation of N-aryl glycine esters with aryl boric acids by direct C–H oxidative cross-coupling has been performed. This work successfully integrates the direct C–H oxidation with asymmetric arylation and exhibits excellent enantioselectivity.


ChemInform ◽  
2007 ◽  
Vol 38 (7) ◽  
Author(s):  
David J. Hyett ◽  
Mara Didone ◽  
Thierry J. A. Milcent ◽  
Quirinus B. Broxterman ◽  
Bernard Kaptein

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