Pyrolysis characteristics and kinetics of residue from China Shenhua industrial direct coal liquefaction plant

2014 ◽  
Vol 589 ◽  
pp. 1-10 ◽  
Author(s):  
Long Xu ◽  
Mingchen Tang ◽  
Lin’e Duan ◽  
Baolin Liu ◽  
Xiaoxun Ma ◽  
...  
Keyword(s):  
Coal Liquefaction ◽  
Pyrolysis Characteristics ◽  
Direct Coal Liquefaction ◽  
Kinetics Of ◽  
Liquefaction Plant

Effects of Direct Coal Liquefaction Residue Additions on Low-Rank Pulverized Coal during Co-Pyrolysis

2020 ◽  
Vol 999 ◽  
pp. 167-177
Author(s):  
Ning Yin ◽  
Yong Hui Song ◽  
Jun Zhou ◽  
Yu Hong Tian ◽  
Ai Wu Yang
Keyword(s):  
Weight Loss ◽  
Free Radical ◽  
Loss Rate ◽  
Coal Liquefaction ◽  
Low Rank ◽  
Coke Yield ◽  
Weight Loss Rate ◽  
Pyrolysis Characteristics ◽  
Direct Coal Liquefaction ◽  
Coal Liquefaction Residue

This study examined the co-pyrolysis characteristics of low-rank coal (SJC) and direct coal liquefaction residue (DCLR) through thermogravimetric analysis coupled with Fourier transform infrared spectrometry. It also investigated the influences of different mass fractions of DCLR to SJC on the co-pyrolysis characteristics and release regulation of gas phase components. Results showed that with increasing DCLR content, coke yield initially decreased and then increased, but tar and gas yield reversed. Different addition of DCLR changed the composition of the pyrolysis gas in various degrees, and reduced the content of-OH and nitrogen compounds in coke. The H2 content in the gas gradually increased. When 40% DCLR was added, the maximum tar yield was 22.79%, and the maximum H2 yield was 37.12%. At 60% DCLR, the lowest semi-coke yield was 65.01%, and the highest gas yield was 14.65%. The co-pyrolysis of SJC and DCLR can be divided into three stages. The first was the dry degassing stage, during which the adsorbed gas and small-molecule gas were removed on the coal surface at room temperature to 350 °C. The second stage (350 °C–650 °C) was the intense pyrolysis reaction stage, during which a large number of volatiles were obtained. The substantial weight loss rate peak appeared around 450 °C. The weight loss rate of pyrolysis gradually increased with increasing DCLR dosage. The co-pyrolysis of SJC and DCLR was not a simple sum between SJC and DCLR, which indicated a synergistic effect in the co-pyrolysis. The synergistic effect between SJC and DCLR enhances the interaction between free-radical fragments, thereby increasing the yield of pyrolysis tar. The third stage was the shrinkage of semi-coke from 650 °C to the end of the reaction. The polycondensation reaction between free-radical fragments to form solid coke with higher aromaticity, and H2 released.

Isothermal Stage Kinetics of Direct Coal Liquefaction for Shenhua Shendong Bituminous Coal

2015 ◽  
Vol 29 (11) ◽  
pp. 7526-7531 ◽  
Author(s):  
Hongbo Jiang ◽  
Xiuhui Wang ◽  
Xiangen Shan ◽  
Kejian Li ◽  
Xuwen Zhang ◽  
...  
Keyword(s):  
Bituminous Coal ◽  
Coal Liquefaction ◽  
Direct Coal Liquefaction ◽  
Kinetics Of

Hydrotreatment of Heavy Oil from Direct Coal Liquefaction on a Sulfided Ni-W/AC Catalyst

2012 ◽  
Vol 34 (24) ◽  
pp. 2287-2295 ◽  
Author(s):  
Z. P. Lei ◽  
L. J. Gao ◽  
H. F. Shui ◽  
Z. C. Wang ◽  
S. B. Ren
Keyword(s):  
Heavy Oil ◽  
Coal Liquefaction ◽  
Direct Coal Liquefaction

Study on pyrolysis characteristics and kinetics of mixed plastic waste

2021 ◽  
Author(s):  
Fengfu Yin ◽  
Qianxiao Zhuang ◽  
Tianhao Chang ◽  
Chao Zhang ◽  
Huadong Sun ◽  
...  
Keyword(s):  
Plastic Waste ◽  
Pyrolysis Characteristics ◽  
Kinetics Of

Compositions of distillate recycle solvents derived from direct coal liquefaction in the SRC-I process

Fuel ◽  
1985 ◽  
Vol 64 (2) ◽  
pp. 242-254 ◽  
Author(s):  
Mieczyslaw M. Boduszynski ◽  
Robert J. Hurtubise ◽  
Todd W. Allen ◽  
Howard F. Silver
Keyword(s):  
Coal Liquefaction ◽  
Direct Coal Liquefaction
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