scholarly journals Simultaneous DSC-FTIR spectroscopy: Comparison of cross-linking kinetics of an epoxy/amine resin system

2012 ◽  
Vol 543 ◽  
pp. 9-17 ◽  
Author(s):  
Surya D. Pandita ◽  
Liwei Wang ◽  
Ramani S. Mahendran ◽  
Venkata R. Machavaram ◽  
Muhammad S. Irfan ◽  
...  
Keyword(s):  
Ftir Spectroscopy ◽  
Cross Linking ◽  
Resin System ◽  
Epoxy Amine ◽  
Kinetics Of

Cure Monitoring of Epoxy Resin by Simultaneous DSC/FTIR

2014 ◽  
Vol 881-883 ◽  
pp. 905-908
Author(s):  
Li Wei Wang ◽  
Gerard F. Fernando
Keyword(s):  
Cross Linking ◽  
Resin System ◽  
Fibre Optic ◽  
Cure Monitoring ◽  
Epoxy Amine ◽  
Fibre Optic Probe ◽  
The Cross ◽  
Optic Probe ◽  
Conventional Dsc ◽  
Kinetics Of

The cross-linking kinetics of an epoxy/amine resin system was studied using the conventional DSC and FTIR spectroscopy, respectively. Conventional DSC was modified to accommodate two fibre optic probes which could be used to monitor the spectra of epoxy/amine resin system during cure. The cross-linking kinetics for the epoxy/amine resin system obtained via the conventional DSC and FTIR and simultaneous DSC/FTIR were similar. The feasibility of using a simple bifurcated fibre optic probe to link the DSC to the FTIR spectrometer was demonstrated.

Thermal Decomposition of Li(NTO)·2H2O and Na(NTO)·H2O (NTO = Anion of 3-Nitro-1,2,4-triazol-5-one): Kinetics Derived from T-jump/FTIR Spectroscopy

2006 ◽  
Vol 71 (1) ◽  
pp. 129-137 ◽  
Author(s):  
Yuanhua Sun ◽  
Tonglai Zhang ◽  
Jianguo Zhang ◽  
Xiaojing Qiao ◽  
Li Yang ◽  
...  
Keyword(s):  
Ftir Spectroscopy ◽  
Energetic Material ◽  
Burning Surface ◽  
High Sensitivity ◽  
Control Voltage ◽  
Differential Scanning Colorimetry ◽  
Voltage Trace ◽  
Dsc Method ◽  
Phase Chemistry ◽  
Kinetics Of

A "snapshot" simulation of the surface reaction zone is captured by a thin film of material heated rapidly to temperatures characteristic of the burning surface by using the T-jump/FTIR spectroscopy. The time-to-exotherm (tx) kinetics method derived from the control voltage trace of the Pt filament can be introduced to resolve the kinetics of an energetic material owing to its high sensitivity to the thermochemical reactions. The kinetic parameters of the two title compounds are determined under different pressures. The results show that Li(NTO)·2H2O and Na(NTO)·H2O (NTO = anion of 3-nitro-1,2,4-triazol-5-one) exhibit weak pressure dependence, their decomposition is dominated by the condensed phase chemistry irrespective of the pressure in the 0.1-1.1 MPa range. The values of Ea determined here are smaller than those given by a traditional non-isothermal differential scanning colorimetry (DSC) method, which might be resembled as the surface of explosion more closely and enabled the pyrolysis surface to be incorporated into models of steady and possibly unsteady combustion. The kinetics can also be successfully used to understand the behavior of the energetic material in practical combustion problems.

scholarly journals Kinetics of Cross-Linking of Peptidoglycan in Bacillus megaterium

1974 ◽  
Vol 249 (8) ◽  
pp. 2478-2482
Author(s):  
William D. Fordham ◽  
Charles Gilvarg
Keyword(s):  
Bacillus Megaterium ◽  
Cross Linking ◽  
Kinetics Of

scholarly journals Viscometric analysis of the gelation of Acanthamoeba extracts and purification of two gelation factors.

1980 ◽  
Vol 85 (2) ◽  
pp. 414-428 ◽  
Author(s):  
S D MacLean-Fletcher ◽  
T D Pollard
Keyword(s):  
Crude Extract ◽  
Cross Linking ◽  
Cross Link ◽  
Gelation Process ◽  
Optimum Ph ◽  
Kinetics Of ◽  
Low Shear

We have studied the kinetics of the gelation process that occurs upon warming cold extracts of Acanthamoeba using a low-shear falling ball assay. We find that the reaction has at least two steps, requires 0.5 mM ATP and 1.5 mM MgCl2, and is inhibited by micromolar Ca++. The optimum pH is 7.0 and temperature, 25 degrees-30 degrees C. The rate of the reaction is increased by cold preincubation with both MgCl2 and ATP. Nonhydrolyzable analogues of ATP will not substitute for ATP either in this "potentiation reaction" or in the gelation process. Either of two purified or any one of four partially purified Acanthamoeba proteins will cross-link purified actin to form a gel, but none can account for the dependence of the reaction in the crude extract on Mg-ATP or its regulation by Ca++. This suggests that the extract contains, in addition to actin-cross-linking proteins, factors dependent on Mg-ATP and Ca++ that regulate the gelation process.

scholarly journals Single-sided NMR for the measurement of the degree of cross-linking and curing

2018 ◽  
Vol 7 (1) ◽  
pp. 21-30 ◽  
Author(s):  
Norbert Halmen ◽  
Christoph Kugler ◽  
Eduard Kraus ◽  
Benjamin Baudrit ◽  
Thomas Hochrein ◽  
...  
Keyword(s):  
Relaxation Times ◽  
Curing Kinetics ◽  
Cross Linking ◽  
Scanning Calorimetry ◽  
First Results ◽  
Non Destructive ◽  
Kinetics Of ◽  
Good Agreement

Abstract. The degree of cross-linking and curing is one of the most important values concerning the quality of cross-linked polyethylene (PE-X) and the functionality of adhesives and resin-based components. Up to now, the measurement of this property has mostly been time-consuming and usually destructive. Within the shown work the feasibility of single-sided nuclear magnetic resonance (NMR) for the non-destructive determination of the degree of cross-linking and curing as process monitoring was investigated. First results indicate the possibility of distinguishing between PE-X samples with different degrees of cross-linking. The homogeneity of the samples and the curing kinetics of adhesives can also be monitored. The measurements show good agreement with reference tests (wet chemical analysis, differential scanning calorimetry, dielectric analysis). Furthermore, the influence of sample temperature on the characteristic relaxation times can be observed.

scholarly journals Improvement of recovered activity and stability of the Aspergillus oryzae β-galactosidase immobilized on duolite A568 by combination of immobilization methods

2017 ◽  
Vol 23 (4) ◽  
pp. 495-506 ◽  
Author(s):  
Larissa Falleiros ◽  
Bruna Cabral ◽  
Janaína Fischer ◽  
Carla Guidini ◽  
Vicelma Cardoso ◽  
...  
Keyword(s):  
Activation Energy ◽  
Aspergillus Oryzae ◽  
Physical Adsorption ◽  
Cross Linking ◽  
Thermal Deactivation ◽  
Order Model ◽  
First Order ◽  
Immobilized Biocatalyst ◽  
The Stability ◽  
Kinetics Of

The immobilization and stabilization of Aspergillus oryzae ?-galactosidase on Duolite??A568 was achieved using a combination of physical adsorption, incubation step in buffer at pH 9.0 and cross-linking with glutaraldehyde and in this sequence promoted a 44% increase in enzymatic activity as compared with the biocatalyst obtained after a two-step immobilization process (adsorption and cross-linking). The stability of the biocatalyst obtained by three-step immobilization process (adsorption, incubation in buffer at pH 9.0 and cross-linking) was higher than that obtained by two-steps (adsorption and cross-linking) and for free enzyme in relation to pH, storage and reusability. The immobilized biocatalyst was characterized with respect to thermal stability in the range 55-65 ?C. The kinetics of thermal deactivation was well described by the first-order model, which resulted in the immobilized biocatalyst activation energy of thermal deactivation of 71.03 kcal/mol and 5.48 h half-life at 55.0 ?C.

Cure Kinetics of Epoxy Resin System Toughened by Polyhexamethylene Carbonate Diol

1997 ◽  
Vol 13 (09) ◽  
pp. 848-852
Author(s):  
Chen Tong-Hui ◽  
◽  
Bai Yao-Wen ◽  
Sun Ren-Hui
Keyword(s):  
Epoxy Resin ◽  
Cure Kinetics ◽  
Resin System ◽  
Epoxy Resin System ◽  
Kinetics Of
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