Surface and transport properties of Au–In liquid alloys

2006 ◽  
Vol 600 (23) ◽  
pp. 5051-5061 ◽  
Author(s):  
R. Novakovic ◽  
E. Ricci ◽  
F. Gnecco
2015 ◽  
Vol 20 (2) ◽  
pp. 140-144
Author(s):  
Bhrigunandan Prasad Singh ◽  
Ishwar Koirala

We have used a formalism that connects thermodynamic and transport properties. The formalism has been used to calculate the Gibb’s free energy of mixing, concentration fluctuations in the long wavelength limit, diffusion coefficients and viscosity in Cu-Tl, Cu-Pb and Sn-Tl binary liquid alloys at 1573K, 1473K and 723K respectively with aid of size effect and no size effect. Our calculations show that appreciable size ratio has more effects on the transport properties as compared to thermodynamic properties of homo-coordinated liquid alloys Cu-Tl, Cu-Pb and Sn-Tl.Journal of Institute of Science and Technology, 2015, 20(2): 140-144  


2021 ◽  
Vol 328 ◽  
pp. 115393
Author(s):  
S.O. Ogundeji ◽  
O.E. Awe ◽  
C.A. Madu ◽  
B.C. Anusionwu

2005 ◽  
Vol 576 (1-3) ◽  
pp. 175-187 ◽  
Author(s):  
R. Novakovic ◽  
E. Ricci ◽  
D. Giuranno ◽  
A. Passerone

2008 ◽  
Vol 602 (11) ◽  
pp. 1957-1963 ◽  
Author(s):  
R. Novakovic ◽  
D. Giuranno ◽  
E. Ricci ◽  
T. Lanata

BIBECHANA ◽  
2014 ◽  
Vol 12 ◽  
pp. 96-103
Author(s):  
B. P. Singh ◽  
B. K. Singh ◽  
I. S. Jha ◽  
G. K. Shrestha ◽  
I. Koirala ◽  
...  

We report a formalism that connects thermodynamics and transport properties such as viscosity and diffusion coefficient which has been used to calculate the concentration dependence of free energy of mixing, concentration-concentration fluctuations in the long wavelength limit and concentration dependence of diffusion and viscosity in Cu-Sb and Cu-Sn binary liquid alloys at 1190K and 1400K respectively with aid of size effect and no size effect. Our calculations show that a reasonable degree of chemical order exists in both alloys system. It can be concluded that size mismatch has more effects on the transport properties of Cu-Sb hetero-coordinated system with greater size ratio than Cu-Sn hetero-coordinated system.DOI: http://dx.doi.org/10.3126/bibechana.v12i0.11781BIBECHANA 12 (2015) 96-103


Rare Metals ◽  
2006 ◽  
Vol 25 (5) ◽  
pp. 457-468 ◽  
Author(s):  
R NOVAKOVIC ◽  
E RICCI ◽  
S AMORE ◽  
T LANATA

BIBECHANA ◽  
2014 ◽  
Vol 11 ◽  
pp. 70-78
Author(s):  
I Koirala ◽  
IS Jha ◽  
BP Singh

Experimental determination of thermo-physical mixing properties of binary liquid alloys is a long and expensive task that becomes more complicated for some system which may be chemically active or radioactive or even may contain scarce components. Theoretical method, on the other hand reduces the time and efforts required, and are of great importance in predicting the properties. Now we have focused on theoretical model to study of the alloying behaviour of Cd-Bi alloys in the molten state at 773K. We have used simple statistical model to report the ordering nature of Cd-Bi liquid alloys through the study of surface properties, transport properties and various thermodynamic and microscopic functions. The knowledge of surface phenomena like surface segregation and surface tension is essential for the processing of materials and productions in the metallurgical industry. At the microscopic level, transport properties such as viscosity and diffusion coefficient help to understand about the mixing behaviour of the alloys forming molten metals. Thermodynamic properties provide information on the interaction, stability and bonding strength among the constituent atoms in the alloys. The microscopic properties are useful in obtaining the microscopic information on structure of molten alloys. Our theoretical analysis gives the negative energy parameter, which is found to be temperature dependent. Negative deviation from Raoultian behaviour is observed in the computed surface tension, thermodynamic and structural parameters of the alloys. But in case of viscosity isotherm positive deviation from ideality is observed. The computed results are in good agreement with experimental data. The analysis concluded that the alloy is of weakly interacting and heterocoordinating system. DOI: http://dx.doi.org/10.3126/bibechana.v11i0.10382 BIBECHANA 11(1) (2014) 70-78


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