High-pressure binary phase equilibria, density and dynamic viscosity of 100 & 200 cSt polydimethylsiloxane (PDMS) with supercritical CO2

2018 ◽  
Vol 139 ◽  
pp. 1-7 ◽  
Author(s):  
H.H. Franken ◽  
J.H. Knoetze ◽  
C.E Schwarz
Keyword(s):  
High Pressure ◽  
Phase Equilibria ◽  
Dynamic Viscosity ◽  
Supercritical Co2 ◽  
Binary Phase

High Pressure Phase Equilibria of the Related Substances in the Limonene Oxidation in Supercritical CO2

2003 ◽  
Vol 48 (2) ◽  
pp. 354-358 ◽  
Author(s):  
Marcos L. Corazza ◽  
Lúcio C. Filho ◽  
Octávio A. C. Antunes ◽  
Cláudio Dariva
Keyword(s):  
High Pressure ◽  
Phase Equilibria ◽  
Supercritical Co2 ◽  
High Pressure Phase ◽  
Related Substances ◽  
Pressure Phase ◽  
Limonene Oxidation

Correlations for binary phase equilibria in high-pressure carbon dioxide

2005 ◽  
Vol 238 (2) ◽  
pp. 174-179 ◽  
Author(s):  
Sujit Kumar Jha ◽  
Giridhar Madras
Keyword(s):  
Carbon Dioxide ◽  
High Pressure ◽  
Phase Equilibria ◽  
Binary Phase

High-pressure binary phase equilibria of aromatic hydrocarbons with carbon dioxide and ethane

1989 ◽  
Vol 34 (4) ◽  
pp. 391-395 ◽  
Author(s):  
Choon Ho Kim ◽  
Angela B. Clark ◽  
P. Vimalchand ◽  
Marc D. Donohue
Keyword(s):  
Carbon Dioxide ◽  
High Pressure ◽  
Phase Equilibria ◽  
Aromatic Hydrocarbons ◽  
Binary Phase

scholarly journals Phase Stability of Iron Nitride Fe4N at High Pressure—Pressure-Dependent Evolution of Phase Equilibria in the Fe–N System

Materials ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 3963
Author(s):  
Marius Holger Wetzel ◽  
Tina Trixy Rabending ◽  
Martin Friák ◽  
Monika Všianská ◽  
Mojmír Šob ◽  
...  
Keyword(s):  
High Pressure ◽  
Phase Equilibria ◽  
Phase Stability ◽  
Polymorphic Transition ◽  
Ex Situ ◽  
Stable Phase ◽  
Iron Nitride ◽  
Phase System ◽  
Target Composition ◽  
Heat Treated

Although the general instability of the iron nitride γ′-Fe4N with respect to other phases at high pressure is well established, the actual type of phase transitions and equilibrium conditions of their occurrence are, as of yet, poorly investigated. In the present study, samples of γ′-Fe4N and mixtures of α Fe and γ′-Fe4N powders have been heat-treated at temperatures between 250 and 1000 °C and pressures between 2 and 8 GPa in a multi-anvil press, in order to investigate phase equilibria involving the γ′ phase. Samples heat-treated at high-pressure conditions, were quenched, subsequently decompressed, and then analysed ex situ. Microstructure analysis is used to derive implications on the phase transformations during the heat treatments. Further, it is confirmed that the Fe–N phases in the target composition range are quenchable. Thus, phase proportions and chemical composition of the phases, determined from ex situ X-ray diffraction data, allowed conclusions about the phase equilibria at high-pressure conditions. Further, evidence for the low-temperature eutectoid decomposition γ′→α+ε′ is presented for the first time. From the observed equilibria, a P–T projection of the univariant equilibria in the Fe-rich portion of the Fe–N system is derived, which features a quadruple point at 5 GPa and 375 °C, above which γ′-Fe4N is thermodynamically unstable. The experimental work is supplemented by ab initio calculations in order to discuss the relative phase stability and energy landscape in the Fe–N system, from the ground state to conditions accessible in the multi-anvil experiments. It is concluded that γ′-Fe4N, which is unstable with respect to other phases at 0 K (at any pressure), has to be entropically stabilised in order to occur as stable phase system. In view of the frequently reported metastable retention of the γ′ phase during room temperature compression experiments, energetic and kinetic aspects of the polymorphic transition γ′⇌ε′ are discussed.

Influences of dynamic entrainer-blended supercritical CO2 fluid exposure on high-pressure methane adsorption on coals

2019 ◽  
Vol 66 ◽  
pp. 180-191 ◽  
Author(s):  
Dengfeng Zhang ◽  
Chao Li ◽  
Jin Zhang ◽  
Zengmin Lun ◽  
Shuaiqiu Jia ◽  
...  
Keyword(s):  
High Pressure ◽  
Supercritical Co2 ◽  
Methane Adsorption ◽  
Supercritical Co2 Fluid
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