Solubility of carbon monoxide in methyl methacrylate at high pressures

2013 ◽  
Vol 73 ◽  
pp. 138-140
Author(s):  
Sona Raeissi ◽  
Louw J. Florusse ◽  
Cor J. Peters
Keyword(s):  
Carbon Monoxide ◽  
Methyl Methacrylate ◽  
High Pressures

scholarly journals The structure of the high pressure carbon bands and the swan system

1929 ◽  
Vol 124 (795) ◽  
pp. 668-688 ◽  
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
High Pressure ◽  
High Pressures ◽  
Carbon Electrodes ◽  
High Dispersion ◽  
Pressure System ◽  
True Nature ◽  
Discharge Tubes ◽  
Condensed Discharge

The so-called high pressure “ CO ” bands—or high pressure carbon bands, as they are better called—were first found by Fowler* in 1910 in tubes containing carbon monoxide at relatively high pressures. The system was described as consisting of some six apparently double-headed bands degraded to the violet, their wave-lengths being approximately at— 6441 6420 } 5897 5878 } 5431 5413 } 5030 5015 } 4679 4663 } 4365 4353 } Å. U. In 1923 the conditions of production of this spectrum were further investigated by Merton and Johnson who obtained the bands with considerable strength by condensed discharges in capillary tubes fitted with carbon electrodes, and containing CO at pressures of 5 mm. and more. It was found that while the high pressure bands and the Swan bands were mingled in the light from the capillary of the tube, the former bands were isolated in bluish jets where the two ends of the capillary merged into the wider parts of the tube. Further observations indicated that the introduction of a little C0 2 destroyed the bands, but that the system re-apppeared after a few minutes, in which time presumably the carbon dioxide had been reduced to monoxide by the carbon electrodes. A reproduction of these bands photographed under low dispersion is given in the above-mentioned paper. No further experimental work appears to have been done on this system, and it has not been correlated with any other band system or assigned any place in the system of electronic levels of the CO molecule. We have therefore made an attempt to photograph the system under high dispersion with a view to fine structure analysis and identification of the molecular emitter. For this purpose large discharge tubes having a bore of about 15 to 20 mm. and a length of 60 or 70 cm. were used. These had at least one of the electrodes made of carbon and were fitted with side bulbs containing caustic potash and phosphorus pentoxide and a palladium regulator. The tubes were filled with carbon monoxide to such a pressure (probably 20-40 mm.) that a condensed discharge could just be forced through by the ¼ kilowatt 15,000 volt transformer used. Some of the tubes had large side flasks attached to them, increasing thereby the volume of gas in the tube, and giving the tubes a life of 4 to 6 hours during which the high pressure bands were emitted strongly. After some such period the pressure fell below the optimum value, and deposits of carbon had accumulated on the walls of the tube. Impurities such as hydrogen, carbon dioxide, and water-vapour were found to inhibit formation of the high pressure bands, and the tube always attained its best condition after running for about an hour (removing meanwhile any little hydrogen present through the regulator). Under these conditions the wide bore is practically filled with light, and presents a remarkable appearance, as of dense pale blue puffs of smoke (showing the high pressure system), threaded by a narrow green ribbon (showing the Swan system). If side tubes having a fair capacity ( e . g ., flasks) are attached to the discharge tube the high pressure glow is capable of diffusion into these. The appearance is suggestive of an afterglow emitter, but if this is its true nature it is of very short duration. Photographs of the H. P. bands were taken in times varying from 4 to 10 hours in the first order of a 21-foot grating. The green band in the neighbourhood of λ 5000 is exceedingly faint and was not attempted. Before considering the results -obtained it will be an advantage to summarise our present knowledge of the Swan spectrum and its emitter, with which it will subsequently be shown that the high pressure carbon system is intimately related.

scholarly journals Gaseous combustion at high pressures. Part IV.—The influence of varying initial pressures upon the rate of pressure development and the activation of nitrogen in carbon monoxide-air explosions

1924 ◽  
Vol 105 (732) ◽  
pp. 406-433
Keyword(s):  
Carbon Monoxide ◽  
High Pressures ◽  
Vibrational Energy ◽  
Initial Pressure ◽  
Maximum Pressure ◽  
Time Interval ◽  
Pressure Development ◽  
The One ◽  
Air Explosion ◽  
Energy Absorbing

In the previous paper of this series it was shown :— (1) that when nitrogen is added as a diluent to a mixture of 2CO+O 2 undergoing combustion in a bomb at an initial pressure of 50 atmospheres, it exerts a peculiar energy-absorbing influence upon the system, far beyond that of other diatomic gases, or of argon; (2) that by virtue of such influence, it retards the attainment of maximum pressure in a much greater degree than can be accounted for on the supposition of its acting merely as a diatomic diluent; (3) that the energy so absorbed by the nitrogen during the combustion period, which extends right up to the attainment of maximum pressure, is slowly liberated thereafter as the system cools down ; and that consequently the rate of cooling is greatly retarded for a considerable time interval after the attainment of maximum pressure; (4) that there is no such energy-absorbing effect ( i. e ., other than a purely "diluent" one) when nitrogen is present in a 2H 2 +O 2 mixture similarly undergoing combustion ; but that, on the contrary, the presence of hydrogen in a CO-air mixture undergoing combustion at such high pressures so strongly counteracts the said " energy-absorbing " influence of the nitrogen, that it must be excluded as far as possible from the system before any large nitrogen-effect can be observed. These facts were explained on the supposition that there is some constitutional correspondence between CO and N 2 molecules (whose densities are identical) whereby the vibrational energy (radiation) emitted when the one burns is of such a quality as can be readily absorbed by the other, the two thus acting in resonance. It was further supposed that, in consequence of such resonance, nitrogen becomes chemically " activated " when present during the combustion of carbon monoxide at such high pressures ; and in conformity with this supposition, it was shown that such "activated" nitrogen is able to combine with oxygen more readily than does nitrogen which has merely been raised to a correspondingly high temperature in a hydrogen-air explosion.

scholarly journals Gaseous combustion at high pressures. Part II. — The explosion of hydrogen-air and carbon monoxide-air mixtures

1921 ◽  
Vol 100 (702) ◽  
pp. 67-84 ◽  
Keyword(s):  
Carbon Monoxide ◽  
High Pressures ◽  
Maximum Pressure ◽  
Chemical Affinity ◽  
Actual Rate ◽  
Sensible Heat ◽  
Direct Relation ◽  
Explosive Mixture ◽  
The Subject ◽  
Time Required

In a previous paper upon the subject, the question was propounded whether or no there is any direct relation between the actual rate at which the potential energy of an explosive mixture is transferred on explosion as sensible heat to its products and the magnitude of the chemical affinity between its combining constituents. As the result of an experimental enquiry into the matter, it was proved:– ( a ) that, whereas the affinity for oxygen of methane is at least twenty to thirty times greater than that of hydrogen, the time required for the attainment of maximum pressure in the case of the primary methane-air mixture (CH 4 + O 2 + 4N 2 ) is at least some five to eight times as long as that required in the case of the primary hydrogen-air mixture (2H 2 + O 2 + 4N 2 );

An IUPAC Task Group Study: The Solubility of Carbon Monoxide in [hmim][Tf2N] at High Pressures

2011 ◽  
Vol 56 (12) ◽  
pp. 4797-4799 ◽  
Author(s):  
L. J. Florusse ◽  
S. Raeissi ◽  
C. J. Peters
Keyword(s):  
Carbon Monoxide ◽  
High Pressures ◽  
Task Group

Line mixing and broadening in the v(1→3) first overtone bandhead of carbon monoxide at high temperatures and high pressures

2019 ◽  
Vol 239 ◽  
pp. 106636 ◽  
Author(s):  
Fabio A. Bendana ◽  
Daniel D. Lee ◽  
Chuyu Wei ◽  
Daniel I. Pineda ◽  
R. Mitchell Spearrin
Keyword(s):  
Carbon Monoxide ◽  
High Temperatures ◽  
High Pressures ◽  
Line Mixing

scholarly journals Mo(CO)5Py as an Initiator of Polymerization

1967 ◽  
Vol 22 (6) ◽  
pp. 580-586 ◽  
Author(s):  
C. H. Bamford ◽  
R. Denyer ◽  
G. C. Eastmond
Keyword(s):  
Carbon Monoxide ◽  
Free Radical ◽  
Methyl Methacrylate ◽  
Vinyl Monomer ◽  
Radical Formation ◽  
Organic Halide ◽  
Organic Halides ◽  
Free Radical Formation ◽  
Molybdenum Carbonyl ◽  
Kinetics Of

In a series of publications we have described the kinetics of free-radical formation from molybdenum carbonyl in association with organic halides in a number of electron-donating solvents. Radical formation involves the displacement of carbon monoxide from the carbonyl by the solvent or vinyl monomer in a rate-determining process giving rise to complexes of the type Mo (CO)5L (where L represents the solvent or monomer) which then react directly with the halide. This paper describes a study of the behaviour of Mo (CO)5Py in association with organic halides in methyl methacrylate solution. The results show that Mo (CO)5Py does not react directly with the halide but first undergoes activation by reaction with monomer, mainly with displacement of pyridine. The relative reactivities of complexes of the type Mo (CO)5L are discussed.The mechanism previously proposed to account for the inhibition processes observed in Mo (CO) 6-organic halide systems satisfactorily explains the extensive inhibition observed in the present work.

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