Effect of supercritical carbon dioxide-assisted nano-scale dispersion of nucleating agents on the crystallization behavior and properties of polypropylene

2008 ◽  
Vol 44 (3) ◽  
pp. 446-456 ◽  
Author(s):  
Bin Li ◽  
Guo Hua Hu ◽  
Gui Ping Cao ◽  
Tao Liu ◽  
Ling Zhao ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Carbon Dioxide ◽  
Crystallization Behavior ◽  
Nucleating Agents ◽  
Nano Scale ◽  
Supercritical Carbon

Study on the Crystallization Behavior of PAN Fibers during Hot-Drawing Process in Supercritical Carbon Dioxide Fluid with Different Strain

2020 ◽  
Vol 976 ◽  
pp. 84-89
Author(s):  
Meng Meng Qiao ◽  
Hai Juan Kong ◽  
Xiao Ma Ding ◽  
Zhi Feng Hu ◽  
Mu Huo Yu
Keyword(s):  
Mechanical Properties ◽  
Carbon Dioxide ◽  
Supercritical Carbon Dioxide ◽  
Carbon Fibers ◽  
Crystallization Behavior ◽  
Strength Analysis ◽  
Drawing Process ◽  
Hot Drawing ◽  
Pan Fibers ◽  
Supercritical Carbon

Hot-drawing of polyacrylonitrile (PAN) fibers is an important step in the production of carbon fibers. In this article, we investigated the effect of strain on the crystallization behavior and mechanical properties of PAN fibers treated in supercritical carbon dioxide (Sc-CO2) fluid. We mainly used the methods of X-ray diffraction (XRD), monofilament strength analysis and differential scanning calorimeter (DSC) to study the crystallization behavior, mechanical properties and thermal behavior of PAN fibers during hot-drawing process. The experimental results showed that the crystallinity and mechanical properties of PAN fibers both increased a lot under the action of strain during hot-drawing in Sc-CO2 fluid. This provides an important method for preparation of higher performance PAN precursor for PAN-based carbon fibers.

Synthesis of nylon 1 in supercritical carbon dioxide and its crystallization behavior effect on nylon 11

CrystEngComm ◽  
2018 ◽  
Vol 20 (32) ◽  
pp. 4676-4684 ◽  
Author(s):  
Dandan Yuan ◽  
Jianxu Bao ◽  
Ying Ren ◽  
Wenmin Li ◽  
Lei Huang ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Carbon Dioxide ◽  
Crystallization Behavior ◽  
Nylon 11 ◽  
Supercritical Carbon

Nylon-1, with the highest density of dipoles among odd-numbered nylons, was synthesized through urea in supercritical CO2.

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