Proton conductivity and diffusion in molten phosphinic acid (H3PO2): The last member of the phosphorus oxoacid proton conductor family

2012 ◽  
Vol 212 ◽  
pp. 6-9 ◽  
Author(s):  
Linas Vilčiauskas ◽  
Carla C. de Araujo ◽  
Klaus-Dieter Kreuer
Keyword(s):  
Proton Conductivity ◽  
Phosphinic Acid ◽  
Proton Conductor ◽  
And Diffusion

scholarly journals Arrangement of water molecules and high proton conductivity of tunnel structure phosphates, KMg1−xH2x(PO3)3·yH2O

RSC Advances ◽  
2020 ◽  
Vol 10 (13) ◽  
pp. 7803-7811 ◽  
Author(s):  
Yasuaki Matsuda ◽  
Kousei Funakoshi ◽  
Ryosuke Sebe ◽  
Genki Kobayashi ◽  
Masao Yonemura ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Gas Flow ◽  
Proton Conductor ◽  
Water Molecules ◽  
Tunnel Structure ◽  
Fast Proton ◽  
High Proton Conductivity ◽  
High Proton ◽  
Ar Gas

A fast proton conductor exhibiting high proton conductivity of 7.0 × 10−3 S cm−1 at 200 °C in a dry Ar gas flow was developed by designing water chains in a rigid tunnel framework.

Dielectric response and anhydrous proton conductivity in a chiral framework containing a non-polar molecular rotor

2015 ◽  
Vol 44 (48) ◽  
pp. 20822-20825 ◽  
Author(s):  
Shan-Shan Yu ◽  
Shao-Xian Liu ◽  
Hai-Bao Duan
Keyword(s):  
High Temperature ◽  
Proton Conductivity ◽  
Dielectric Response ◽  
Proton Conductor ◽  
Molecular Rotor ◽  
3D Framework

A chiral 3D framework containing a nonpolar rotor shows two dielectric anomalies and can serve as a proton conductor under high-temperature and anhydrous conditions.

Acceptor doping in the proton conductor SrZrO3

2017 ◽  
Vol 19 (18) ◽  
pp. 11485-11491 ◽  
Author(s):  
Leigh Weston ◽  
A. Janotti ◽  
X. Y. Cui ◽  
C. Stampfl ◽  
C. G. Van de Walle
Keyword(s):  
Proton Conductivity ◽  
Proton Conductor ◽  
Acceptor Doping ◽  
Proton Conducting ◽  
Conducting Oxides

Acceptor dopants in proton-conducting oxides act as proton traps, or can accidentally incorporate as donors, reducing proton conductivity.

Synthesis, structure and proton conductivity of 2,4,5-trimethylbenzenesulfonic acid dihydrate

2018 ◽  
Vol 42 (9) ◽  
pp. 7428-7438 ◽  
Author(s):  
A. V. Pisareva ◽  
G. V. Shilov ◽  
A. I. Karelin ◽  
R. V. Pisarev ◽  
I. A. Shilova ◽  
...  
Keyword(s):  
Polymer Electrolyte ◽  
Proton Conductivity ◽  
Proton Conductor ◽  
Electrochemical Devices

2,4,5-Trimethylbenzenesulfonic acid dihydrate is a good proton conductor and has potential as a polymer electrolyte for different electrochemical devices.

Suppression of methanol cross-over in novel composite membranes for direct methanol fuel cells

2009 ◽  
Vol 81 (12) ◽  
pp. 2309-2316 ◽  
Author(s):  
Yong Fang ◽  
Ruiying Miao ◽  
Tongtao Wang ◽  
Xindong Wang
Keyword(s):  
Fuel Cells ◽  
Proton Conductivity ◽  
Direct Methanol Fuel Cells ◽  
Base Material ◽  
Proton Conductor ◽  
Composite Membranes ◽  
Methanol Permeability ◽  
Poly Vinyl Alcohol ◽  
Direct Methanol ◽  
Methanol Fuel Cells

A series of novel composite membranes was prepared by using poly(vinyl alcohol) (PVA) with polyimide (PI) as base material and 8-trimethoxysilylpropyl glycerine ether-1,3,6-pyrenetrisulfonic acid (TSGEPS) as proton conductor for direct methanol fuel cells (DMFCs). The parameters of membranes, including water sorption, hydrolysis stability, dimensional stability, proton conductivity, and methanol permeability were studied. The proton conductivity of the membranes is in the order of 10–2 S/cm, and the membranes show better resistance to methanol permeability (1.51 × 10–7 cm2 s–1) and better selectivity (20.6 × 104 S cm–3 s) than those of Nafion115 under the same measurement conditions.

scholarly journals Yttrium and hydrogen superstructure and correlation of lattice expansion and proton conductivity in the BaZr0.9Y0.1O2.95 proton conductor

2009 ◽  
Vol 95 (22) ◽  
pp. 224103 ◽  
Author(s):  
A. Braun ◽  
A. Ovalle ◽  
V. Pomjakushin ◽  
A. Cervellino ◽  
S. Erat ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Proton Conductor ◽  
Lattice Expansion
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