Amperometric sensing of chemical oxygen demand at glassy carbon and silicon electrodes modified with boron-doped diamond

2013 ◽  
Vol 189 ◽  
pp. 30-36 ◽  
Author(s):  
R. Bogdanowicz ◽  
J. Czupryniak ◽  
M. Gnyba ◽  
J. Ryl ◽  
T. Ossowski ◽  
...  
2007 ◽  
Vol 9 (9) ◽  
pp. 2280-2285 ◽  
Author(s):  
Hongbin Yu ◽  
Hua Wang ◽  
Xie Quan ◽  
Shuo Chen ◽  
Yaobin Zhang

Coatings ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 1097
Author(s):  
Chang Weon Song ◽  
Mi Young You ◽  
Jae Myung Lee ◽  
Dae-Seung Cho ◽  
Pung Keun Song

In this study, boron-doped diamond (BDD) film was deposited by hot-filament chemical vapor deposition (HFCVD) using acetone as the carbon source and trimethyl borate (TMB) as the boron source with the aim of lowering the manufacturing cost of BDD electrodes. The BDD film was deposited for 12 and 60 h to observe changes in the morphological behavior of the film as well as subsequent changes in the electrochemical properties. The morphology of the BDD film was not affected by the deposition time, but the thickness increased with increasing deposition time. As the deposition time increased, the deposition rate of the BDD film did not increase or decrease; rather, it remained constant at 100 nm/h. As the thickness of the BDD film increased, an increase in the potential window was observed. On the other hand, no distinct change was observed in the electrochemical activation and catalytic activity depending on the thickness, and there were not many differences. Chemical oxygen demand (COD) was measured to determine the practical applicability of the deposited BDD film. Unlike the potential window, the COD removal rate was almost the same and was not affected by the increase in the thickness of the BDD film. Both films under the two deposition conditions showed a high removal rate of 90% on average. This study confirms that BDD electrodes are much more useful for water treatment than the existing electrodes.


2018 ◽  
Vol 2018 ◽  
pp. 1-12 ◽  
Author(s):  
Alejandra Sánchez-Sánchez ◽  
Moisés Tejocote-Pérez ◽  
Rosa María Fuentes-Rivas ◽  
Ivonne Linares-Hernández ◽  
Verónica Martínez-Miranda ◽  
...  

The removal of pollutants from textile wastewater via electrochemical oxidation and a coupled system electrooxidation—Salix babylonica, using boron-doped diamond electrodes was evaluated. Under optimal conditions of pH 5.23 and 3.5 mA·cm−2 of current density, the electrochemical method yields an effective reduction of chemical oxygen demand by 41.95%, biochemical oxygen demand by 83.33%, color by 60.83%, and turbidity by 26.53% at 300 minutes of treatment. The raw and treated wastewater was characterized by infrared spectroscopy to confirm the degradation of pollutants. The wastewater was oxidized at 15-minute intervals for one hour and was placed in contact with willow plants for 15 days. The coupled system yielded a reduction of the chemical oxygen demand by 14%, color by 85%, and turbidity by 93%. The best efficiency for the coupled system was achieved at 60 minutes, at which time the plants achieved more biomass and photosynthetic pigments.


2012 ◽  
Vol 47 ◽  
pp. 1117-1120 ◽  
Author(s):  
R. Bogdanowicz ◽  
J. Czupryniak ◽  
M. Gnyba ◽  
J. Ryl ◽  
T. Ossowski ◽  
...  

2018 ◽  
Vol 18 (7) ◽  
pp. 4551-4558 ◽  
Author(s):  
Paulo Vinicius F. da Costa ◽  
Rejane Maria P. da Silva ◽  
Hugo B Suffredini ◽  
Wendel A Alves

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