Multi-walled carbon nanotubes/electro-copolymerized cobalt nanoparticles-poly(pivalic acid) composite film coated glassy carbon electrode for the determination of methimazole

2012 ◽  
Vol 171-172 ◽  
pp. 1216-1221 ◽  
Author(s):  
Aysegul Kutluay ◽  
Mehmet Aslanoglu
Keyword(s):  
Carbon Nanotubes ◽  
Composite Film ◽  
Glassy Carbon Electrode ◽  
Glassy Carbon ◽  
Pivalic Acid ◽  
Cobalt Nanoparticles ◽  
Carbon Electrode ◽  
Multi Walled Carbon Nanotubes ◽  
Walled Carbon Nanotubes

The Application of Glassy Carbon Electrode Modified by Multi-Walled Carbon Nanotubes for the Fast Determination of Hydroquinone in Wastewater

2014 ◽  
Vol 955-959 ◽  
pp. 1160-1166
Author(s):  
Shao Hua Li ◽  
Ying Ying Zhao ◽  
Jun Qing Yang ◽  
Guo Yan Zhang ◽  
Ju Rui Qi
Keyword(s):  
Carbon Nanotubes ◽  
Glassy Carbon Electrode ◽  
Glassy Carbon ◽  
Phosphate Buffer Solution ◽  
Differential Pulse ◽  
Carbon Electrode ◽  
Buffer Solution ◽  
Multi Walled Carbon Nanotubes ◽  
Walled Carbon Nanotubes

A novel multi-walled carbon nanotubes (MWCNTs)-modified glassy carbon electrode (GCE) with excellent stability, repeatability and anti-interference was synthesized and it exhibited an electrocatalytic signal for hydroquinone (HQ) compared to bare GCE, which suggested that the presence of MWCNTs efficiently enhances electron transfer. Various parameters such as pH, modifier volume, and scan rate were optimized using cyclic voltammetry (CV) and differential pulse voltammetry (DPV) methods. Under optimum conditions, linear responses for HQ in 0.1mol·L-1 phosphate buffer solution of pH 6.0 were obtained in the range of 5×10-6 mol·L-1 to 2×10-4 mol·L-1 with detection limits of 2.7×10-6 mol·L-1 (signal-to-noise ratio of 3). Such MWCNTs-modified GCE was successfully applied for the determination of hydroquinone in simulated water samples and can be developed for the the detection of HQ.

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