scholarly journals Calculating the magnetocaloric effect in second-order-type material by micromagnetic simulations: A case study on Co2B

2020 ◽  
Vol 177 ◽  
pp. 218-222
Author(s):  
Dominik Ohmer ◽  
Min Yi ◽  
Maximilian Fries ◽  
Oliver Gutfleisch ◽  
Bai-Xiang Xu
Crystals ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 694
Author(s):  
Abdul Rashid Abdul Rahman ◽  
Muhamad Faiz Md Din ◽  
Jianli Wang ◽  
Nur Sabrina Suhaimi ◽  
Nurul Hayati Idris ◽  
...  

MnCoGe-based compounds have been increasingly studied due to their possible large magnetocaloric effect correlated to the magnetostructural coupling. In this research, a comprehensive study of structure, magnetic phase transition, magnetocaloric effect and thermomechanical properties for MnCoGe1−xSix is reported. Room temperature X-ray diffraction indicates that the MnCoGe1−xSix (x = 0, 0.05, 0.1, 0.15 and 0.2) alloys have a major phase consisting of an orthorhombic TiNiSi-type structure with increasing lattice parameter b and decreasing others (a and c) with increasing Si concentration. Along with M-T and DSC measurements, it is indicated that the Tc value increased with higher Si concentration and decreased for structural transition temperature Tstr. The temperature dependence of the magnetization curves overlaps completely, indicating that there is no thermal hysteresis, and it is shown that the transition is the second-order type. It is also shown that the decreased magnetization on the replacement of Si for Ge decreases the value of −ΔSM from −ΔSM~8.36 J kg−1 K−1 at x = 0 to −ΔSM~5.49 J kg−1 K−1 at x = 0.2 with 5 T applied field. The performed Landau theory has confirmed the second-order transition in this study, which is consistent with the Banerjee criterion. The magnetic measurement and thermomechanical properties revealed the structural transition that takes place with Si substitution of Ge.


1987 ◽  
Author(s):  
Moideen P Jamaluddin

Platelet aggregation kinetics, according to the particle collision theory, generally assumed to apply, ought to conform to a second order type of rate law. But published data on the time-course of ADP-induced single platelet recruitment into aggregates were found not to do so and to lead to abnormal second order rate constants much larger than even their theoretical upper bounds. The data were, instead, found to fit a first order type of rate law rather well with rate constants in the range of 0.04 - 0.27 s-1. These results were confirmed in our laboratory employing gelfiltered calf platelets. Thus a mechanism much more complex than hithertofore recognized, is operative. The following kinetic scheme was formulated on the basis of information gleaned from the literature.where P is the nonaggregable, discoid platelet, A the agonist, P* an aggregable platelet form with membranous protrusions, and P** another aggregable platelet form with pseudopods. Taking into account the relative magnitudes of the k*s and assuming aggregation to be driven by hydrophobic interaction between complementary surfaces of P* and P** species, a rate equation was derived for aggregation. The kinetic scheme and the rate equation could account for the apparent first order rate law and other empirical observations in the literature.


Axioms ◽  
2021 ◽  
Vol 10 (2) ◽  
pp. 102
Author(s):  
Maya Briani ◽  
Emiliano Cristiani ◽  
Paolo Ranut

In this paper, we propose two models describing the dynamics of heavy and light vehicles on a road network, taking into account the interactions between the two classes. The models are tailored for two-lane highways where heavy vehicles cannot overtake. This means that heavy vehicles cannot saturate the whole road space, while light vehicles can. In these conditions, the creeping phenomenon can appear, i.e., one class of vehicles can proceed even if the other class has reached the maximal density. The first model we propose couples two first-order macroscopic LWR models, while the second model couples a second-order microscopic follow-the-leader model with a first-order macroscopic LWR model. Numerical results show that both models are able to catch some second-order (inertial) phenomena such as stop and go waves. Models are calibrated by means of real data measured by fixed sensors placed along the A4 Italian highway Trieste–Venice and its branches, provided by Autovie Venete S.p.A.


Author(s):  
Evan Barba

Second-order effects refer to changes within a system that are the result of changes made somewhere else in the system (the first-order effects). Second-order effects can occur at different spatial, temporal, or organizational scales from the original interventions, and are difficult to control. Some organizational theorists suggest that careful management of feedback processes can facilitate controlled change from one organizational configuration to another. Recognizing that skill in managing feedback processes is a core competency of design suggests that design skills are potentially useful tools in achieving organizational change. This paper describes a case study in which a co-design methodology was used to control the second-order effects resulting from a classroom intervention to create organizational change. This approach is then theorized as the Instigator Systems approach.


Sign in / Sign up

Export Citation Format

Share Document