Gas-flow optimization studies on brass samples using closed and open types of laser ablation cells in inductively coupled plasma mass spectrometry

2012 ◽  
Vol 68 ◽  
pp. 46-57 ◽  
Author(s):  
Tibor Kántor ◽  
Edit Király ◽  
Éva Bertalan ◽  
András Bartha
Keyword(s):  
Mass Spectrometry ◽  
Laser Ablation ◽  
Inductively Coupled Plasma ◽  
Gas Flow ◽  
Flow Optimization ◽  
Inductively Coupled ◽  
Plasma Mass Spectrometry

Neon Inductively Coupled Plasma for Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry

2002 ◽  
Vol 56 (5) ◽  
pp. 658-664 ◽  
Author(s):  
Caroline M. Petibon ◽  
Henry P. Longerich ◽  
Ingo Horn ◽  
Mike N. Tubrett
Keyword(s):  
Mass Spectrometry ◽  
Laser Ablation ◽  
Inductively Coupled Plasma ◽  
Gas Flow ◽  
Concentration Data ◽  
Inductively Coupled ◽  
Icp Ms ◽  
Plasma Mass Spectrometry ◽  
Sensitivity Data ◽  
Varying Mass

The use of a neon inductively coupled plasma (Ne ICP) in place of an argon inductively coupled plasma (Ar ICP) for laser ablation microprobe-inductively coupled plasma-mass spectrometry (LAM-ICP-MS) is demonstrated. Gas blank mass spectra were obtained comparing the signals obtained with an Ar ICP with the Ne ICP. Sensitivity (signal/concentration) data were also obtained for a number of analytes using solid reference materials. The sensitivity data is complicated by significant changes in optimum Ne ICP parameters (especially nebulizer gas flow) for analytes of varying mass. The sensitivity of the Ne ICP is in general also lower than that obtained for the Ar ICP. The potential for the Ne ICP to reduce the formation of argides, both in the background and from sample induced interferences, is demonstrated. Clearly shown is the reduction of the interferences of 63Cu40Ar and 65Cu40Ar on 103Rh and 105Pd in a Cu2S sample, as well as the reduction of the interferences of 58Ni40Ar and 60Ni40Ar on 98Ru and 100Ru in a NiS sample.

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