Laser Ablation Molecular Isotopic Spectrometry: Parameter influence on boron isotope measurements

2011 ◽  
Vol 66 (8) ◽  
pp. 604-609 ◽  
Author(s):  
Xianglei Mao ◽  
Alexander A. Bol'shakov ◽  
Dale L. Perry ◽  
Osman Sorkhabi ◽  
Richard E. Russo
Keyword(s):  
Laser Ablation ◽  
Boron Isotope ◽  
Parameter Influence ◽  
Isotope Measurements

Accurate correction for the matrix interference on laser ablation MC-ICPMS boron isotope measurements in CaCO3 and silicate matrices

2021 ◽  
Author(s):  
David Evans ◽  
Axel Gerdes ◽  
Horst R. Marschall ◽  
Douglas Coenen ◽  
Wolfgang Müller
Keyword(s):  
High Temperature ◽  
Laser Ablation ◽  
Isotopic Composition ◽  
Boron Isotope ◽  
Matrix Interference ◽  
The Matrix ◽  
Silicate Matrices ◽  
Isotope Measurements ◽  
Boron Isotopic Composition

Knowledge of the boron isotopic composition of natural samples has found wide ranging application in both low and high temperature geochemistry. More recently, the development of boron isotope measurements using...

In situ boron isotope measurements of natural geological materials by LA-MC-ICP-MS

2010 ◽  
Vol 55 (29) ◽  
pp. 3305-3311 ◽  
Author(s):  
KeJun Hou ◽  
YanHe Li ◽  
YingKai Xiao ◽  
Feng Liu ◽  
YouRong Tian
Keyword(s):  
Boron Isotope ◽  
Geological Materials ◽  
Icp Ms ◽  
Isotope Measurements

Boron isotope analysis of coral skeletons by laser ablation MC-ICP-MS: new insights into calcification and environmental reconstruction at high temporal resolution

2020 ◽  
Author(s):  
Gavin L. Foster ◽  
Thomas B. Chalk ◽  
Christopher D. Standish
Keyword(s):  
Laser Ablation ◽  
Trace Element ◽  
Temporal Resolution ◽  
Isotope Analysis ◽  
Coral Skeleton ◽  
Boron Isotope ◽  
High Temporal Resolution ◽  
Carbonate System ◽  
Seawater Ph ◽  
Icp Ms

<p>Despite being some of the largest bio-constructions on the planet, coral reefs are made by many millions of cm- to mm-sized polyps of Scleractinian corals. Calcification occurs in a micron sized space sandwiched between the coral animal and the existing skeleton, known as the extra cellular medium (ECM). The coral animal has a tight control on the carbonate system in this space through deploying enzymatic pumps (e.g. Ca-ATPase) and secreting acidic-rich proteins. Tracking the state of the carbonate system in the ECM is therefore key to forming a mechanistic understanding of how environmental change, such as ocean acidification, influences skeletal formation and ultimately the growth and resilience of these important ecosystems.</p><p>Traditional means to examine ECM composition is through the use of micro-electrodes. While these approaches have revealed many key insights they are, by their nature, invasive.  They also only provide snap shots of information for corals grown in the laboratory. The boron isotopic composition of the coral skeleton and its boron content (expressed as B/Ca ratio) have recently emerged as a viable alternative approach to fully characterise the carbonate system in the ECM.  However, most studies employ bulk sampling techniques which require averaging across both structural elements of the coral skeleton and many months to years of growth. Laser ablation MC-ICP-MS approaches are now available as an alternative sampling protocol (e.g. Standish et al. 2019), and along with B/Ca (and other trace element) measurements this not only allows a reconstruction of the full carbonate system of the ECM from an analysis of the skeleton of any coral (cultured or wild) at unprecedented spatial and temporal resolution, but it also allows an examination of the influence of the carbonate system in the ECM on trace element incorporation. </p><p>Here we present boron isotope and trace element analyses of several tropical, reef-building, corals to examine the nature and magnitude of fine scale variation in ECM composition.  By studying corals from locations where external seawater is well known we also gain insights into trace element incorporation and whether external seawater pH can be accurately reconstructed from the boron-based proxies at weekly (or better) resolution. </p><p> </p><p>Standish, C.D., Chalk, T.B., Babila, T.L., Milton, J.A., Palmer, M.R., Foster, G.L. (2019) The effect of matrix interferences in situ boron isotope analysis by laser ablation MC-ICP-MS, Rapid Communications in Mass Spectrometry 33: 959–968 https://doi.org/10.1002/rcm.8432</p>

Improved time control on Cretaceous coastal deposits: new results from Sr isotope measurements using laser ablation

Terra Nova ◽  
2009 ◽  
Vol 21 (5) ◽  
pp. 401-409 ◽  
Author(s):  
Stefan Burla ◽  
Felix Oberli ◽  
Ulrich Heimhofer ◽  
Uwe Wiechert ◽  
Helmut Weissert
Keyword(s):  
Laser Ablation ◽  
Sr Isotope ◽  
Time Control ◽  
Coastal Deposits ◽  
Isotope Measurements

Accurate and precise microscale measurements of boron isotope ratios in calcium carbonates using laser ablation multicollector-ICPMS

2019 ◽  
Vol 34 (3) ◽  
pp. 550-560 ◽  
Author(s):  
Aleksey Sadekov ◽  
Nicholas S. Lloyd ◽  
Sambuddha Misra ◽  
Julie Trotter ◽  
Juan D'Olivo ◽  
...  
Keyword(s):  
Laser Ablation ◽  
Isotope Ratios ◽  
Boron Isotope ◽  
Carbonate Chemistry ◽  
Calcium Carbonates ◽  
Seawater Ph ◽  
Invaluable Tool ◽  
Biogenic Carbonates

The boron isotope compositions (δ11B) of biogenic carbonates have proven to be an invaluable tool for investigating changes in ocean carbonate chemistry, especially the impacts of declining seawater pH due to rising levels of atmospheric CO2.

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