Rapid detection of chlorpyrifos pesticide residue in tea using surface-enhanced Raman spectroscopy combined with chemometrics

Author(s):  
Xiaoyu Zhu ◽  
Wenjin Li ◽  
Ruimei Wu ◽  
Peng Liu ◽  
Xiao Hu ◽  
...  
Sensors ◽  
2019 ◽  
Vol 19 (3) ◽  
pp. 506 ◽  
Author(s):  
Shizhuang Weng ◽  
Wenxiu Zhu ◽  
Ronglu Dong ◽  
Ling Zheng ◽  
Fang Wang

Pesticide residue in paddy water is one of the main factors affecting the quality and safety of rice, however, the negative effect of this residue can be effectively prevented and reduced through early detection. This study developed a rapid detection method for fonofos, phosmet, and sulfoxaflor in paddy water through chemometric methods and surface-enhanced Raman spectroscopy (SERS). Residue from paddy water samples was directly used for SERS measurement. The obtained spectra from the SERS can detect 0.5 mg/L fonofos, 0.25 mg/L phosmet, and 1 mg/L sulfoxaflor through the appearance of major characteristic peaks. Then, we used chemometric methods to develop models for the intelligent analysis of pesticides, alongside the SERS spectra. The classification models developed by K-nearest neighbor identified all of the samples, with an accuracy of 100%. For the quantitative analysis, the partial least squares regression models obtained the best predicted performance for fonofos and sulfoxaflor, and the support vector machine model provided optimal results, with a root-mean-square error of validation of 0.207 and a coefficient of determination of validation of 0.99952, for phosmet. Experiments for actual contaminated samples also showed that the above models predicted the pesticide residue values with high accuracy. Overall, using SERS with chemometric methods provided a simple and convenient approach for the detection of pesticide residues in paddy water.


2016 ◽  
Vol 8 (7) ◽  
pp. 1602-1608 ◽  
Author(s):  
Shintaro Pang ◽  
Lili He

Aptamer–gold nanoparticle (AuNP) based colorimetric assays have become increasingly popular as viable rapid detection methods, but the molecular interactions governing the mechanism and successful interpretation of color changes have not been explored well.


2020 ◽  
Vol 6 (5) ◽  
pp. 947-953 ◽  
Author(s):  
Yen Lynn Wong ◽  
Wei Cherng Malvin Kang ◽  
Miguel Reyes ◽  
Jeanette Woon Pei Teo ◽  
James Chen Yong Kah

2005 ◽  
Vol 127 (12) ◽  
pp. 4484-4489 ◽  
Author(s):  
Xiaoyu Zhang ◽  
Matthew A. Young ◽  
Olga Lyandres ◽  
Richard P. Van Duyne

ACS Nano ◽  
2013 ◽  
Vol 7 (8) ◽  
pp. 7157-7164 ◽  
Author(s):  
Chrysafis Andreou ◽  
Mehran R. Hoonejani ◽  
Meysam R. Barmi ◽  
Martin Moskovits ◽  
Carl D. Meinhart

2012 ◽  
Vol 234 (6) ◽  
pp. 1091-1098 ◽  
Author(s):  
Yunfei Xie ◽  
Godelieve Mukamurezi ◽  
Yingying Sun ◽  
Heya Wang ◽  
He Qian ◽  
...  

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