l-Arginine trifluoroacetate salt bridges in its solid state compound: The low-temperature three dimensional structural determination of l-arginine bis(trifluoroacetate) crystal and its vibrational spectral analysis

Author(s):  
Z.H. Sun ◽  
W.M. Sun ◽  
C.T. Chen ◽  
G.H. Zhang ◽  
X.Q. Wang ◽  
...  
Author(s):  
Frances Jurnak ◽  
Michelle Nelson ◽  
Marilyn Yoder ◽  
Susan Heffron ◽  
Suet Miu

Author(s):  
Jared T. Stritzinger ◽  
Janelle E. Droessler ◽  
Brian L. Scott ◽  
George S. Goff

The structural determination of the ionic liquid, caesium bis[(trifluoromethyl)sulfonyl]imide or poly[[μ4-bis[(trifluoromethyl)sulfonyl]imido]caesium(I)], Cs[N(SO2CF3)2] or Cs[Tf2N], reveals a second polymorph that also crystallizes in a layer structure possessing monoclinic P21/c symmetry at 120 K instead of C2/c for the known polymorph [Xue et al. (2002). Solid State Sci. 4, 1535–1545]. The caesium ions in the cationic layers are coordinated by the sulfonyl groups of the bistriflimide molecules from anion layers while the trifluoromethyl groups are oriented in the opposite direction, forming a non-polar surface separating the layers. The layer direction is (100).


2018 ◽  
Vol 6 (24) ◽  
pp. 11405-11415 ◽  
Author(s):  
L. Q. Lu ◽  
N. Schriever ◽  
J. Th. M. De Hosson ◽  
Y. T. Pei

In this work we developed a solid-state-growth approach for the synthesis of 3D interconnected bicontinuous nanoporous graphene (NPG) with the aid of nanoporous Ni templates at low temperatures (below 800 °C).


2013 ◽  
Vol 88 (10) ◽  
Author(s):  
Chun Zhu ◽  
Chien-Chun Chen ◽  
Jincheng Du ◽  
Michael R. Sawaya ◽  
M. C. Scott ◽  
...  

1994 ◽  
Vol 366 ◽  
Author(s):  
F. W. Deeg ◽  
M. Ehrl ◽  
C. Bräuchle

ABSTRACTWe have used low-temperature optical spectroscopy to characterize the guest/host interaction of thiazine and oxazine dyes encapsulated in the three-dimensional pore structure of faujasite cages. The system thionine in dehydrated zeolite-Y exhibits a thermal and optical equilibrium between two spectroscopically distinguishable species. Temperature-dependent measurements allow the determination of the energy difference and barrier between these two forms as 170 cm−1 and 120 cm−1, respectively. The two forms are associated with two different locations/conformations of the chromophore within the faujasite pore structure. The degree of freedom responsible for the interconversion of the two forms is extremely sensitive to the relationship between molecular size and form of the void.


2011 ◽  
Vol 40 (17) ◽  
pp. 4605 ◽  
Author(s):  
Olivier J. Hernandez ◽  
Cédric Tassel ◽  
Kunihiro Nakano ◽  
Werner Paulus ◽  
Clemens Ritter ◽  
...  

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