Spectral image analysis for the absorption bands of the β-methallyl free radical in the vapor phase

2007 ◽  
Vol 67 (5) ◽  
pp. 1276-1280 ◽  
Author(s):  
Fuat Bayrakçeken ◽  
Ziya Telatar ◽  
Fikret Arı ◽  
Aykut B. Bayrak
1988 ◽  
Vol 42 (1) ◽  
pp. 101-108 ◽  
Author(s):  
W. M. Coleman ◽  
Bert M. Gordon

Matrix isolation Fourier transform spectral evidence is presented that documents the isolation of rotational isomers in an argon matrix. The spectral evidence is based on the presence of split carbonyl absorption bands in the spectra of selected derivatives of methyl acetate which do not vary in intensity with changes in the matrix-to-eluate ratios. The results compare very favorably with FT-IR data on the identical compounds obtained in the vapor phase. The low temperature of the matrix isolation experiment (10 K) allows for the observance of rotational isomers not seen at the high temperatures of the vapor-phase experiment (500 K). The presence of multiple carbonyl absorption bands dictates that careful attention must be paid to spectral/structure correlations employing MI/FT-IR data.


Geoderma ◽  
1992 ◽  
Vol 53 (3-4) ◽  
pp. 341-355 ◽  
Author(s):  
Stewart J. Sweeney ◽  
Richard Protz ◽  
Catherine A. Fox

2016 ◽  
Vol 33 (8) ◽  
pp. 1476 ◽  
Author(s):  
Shoji Tominaga ◽  
Keiji Kato ◽  
Keita Hirai ◽  
Takahiko Horiuchi

1967 ◽  
Vol 45 (12) ◽  
pp. 4103-4111 ◽  
Author(s):  
A. J. Merer

The flash photolysis of diazopropyne (HC2∙CHN2) provides a particularly strong absorption spectrum of the free C3 radical. About 40 μs after the photolysis flash, the appearance of the [Formula: see text] (4 050 Å) system of C3 is similar to that obtained in the flash photolysis of diazomethane by Gausset, Herzberg, Lagerqvist, and Rosen, though much more intense. The intensity of the spectrum has permitted a study of the l-type doubling effect in the ground-state level 6ν2, of which the [Formula: see text] component has been found to lie at 458.2 cm−1. At shorter time delays [Formula: see text] the spectrum is complicated by bands arising from the levels ν1″ (1 224.5 cm−1) and 2ν1″ (2 436.0 cm−1).Below 3 700 Å the C3 spectrum is overlapped by absorption bands belonging to a new free radical, which has been identified from the intensity alternation in the rotational structure as the HCCCH radical. The vibrational structure of this system is exceptionally complex, and analysis has not been possible. The bands extend to about 3 100 Å, but are predissociated below 3 450 Å.


2009 ◽  
Author(s):  
William Glass ◽  
Michael J. Duggin ◽  
Raymond A. Motes ◽  
Keith A. Bush ◽  
Meiling Klein

1992 ◽  
Vol 24 (3) ◽  
pp. 159
Author(s):  
S. Toyooka ◽  
S. Izawa ◽  
N. Hayasaka ◽  
H. Kadono ◽  
T. Jaaskelainen

2011 ◽  
Vol 79A (4) ◽  
pp. 293-305 ◽  
Author(s):  
Edmond Kahn ◽  
Mauhamad Baarine ◽  
Aurélien Dauphin ◽  
Kévin Ragot ◽  
Nicolas Tissot ◽  
...  

2002 ◽  
Vol 8 (S02) ◽  
pp. 1554-1555
Author(s):  
P.G. Kotula ◽  
P.F. Hlava ◽  
M.R. Keenan

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