Plasma polymerization mediated construction of surface ion-imprinted polypropylene fibers for the selective adsorption of Cr(VI)

2020 ◽  
Vol 150 ◽  
pp. 104552 ◽  
Author(s):  
Zhengwei Luo ◽  
Mulin Guo ◽  
Hui Jiang ◽  
Wenhua Geng ◽  
Wuji Wei ◽  
...  
Polymers ◽  
2019 ◽  
Vol 11 (9) ◽  
pp. 1508 ◽  
Author(s):  
Zhengwei Luo ◽  
Jiahuan Xu ◽  
Dongmei Zhu ◽  
Dan Wang ◽  
Jianjian Xu ◽  
...  

To improve the adsorption selectivity towards hexavalent chromium anion (Cr(VI)), surface Cr(VI)-imprinted polypropylene (PP) fibers were fabricated by the plasma-mediated grafting strategy. Hence, a non-thermal Rradio frequency discharge plasma irradiation followed by a gaseous phase grafting was used to load acrylic acid (AA) onto PP fibers, which was afterwards amidated with triethylenetetramine and subjected to imprinting with a Cr(VI) template. The plasma irradiation conditions, i.e., gas species, output power, pressure, and time, were optimized and then the influence of grafting time, pressure, and temperature on the grafting degree of AA was investigated. Scanning electron microscopy and Fourier transform infrared spectroscopy were used for the characterization of pristine and modified fibers and to confirm the synthesis success. The hydrophilicity of modified fibers was greatly improved compared with pristine PP fibers. The adsorption thermodynamics and kinetics of Cr(VI) were investigated, as well as the elution efficiency and reusability. The prepared imprinted fibers showed superior adsorption selectivity to Cr(VI) compared with non-imprinted fibers. Finally, the stability of the imprinted fibers against the oxidation ability of Cr(VI) is discussed.


2020 ◽  
Vol 317 ◽  
pp. 114246 ◽  
Author(s):  
Mohsen Sadani ◽  
Tayebeh Rasolevandi ◽  
Hossein Azarpira ◽  
Amir Hossein Mahvi ◽  
Mansour Ghaderpoori ◽  
...  

2017 ◽  
Vol 189 ◽  
pp. 288-295 ◽  
Author(s):  
Enli Liu ◽  
Xuechao Xu ◽  
Xudong Zheng ◽  
Fusheng Zhang ◽  
Enxiu Liu ◽  
...  

2013 ◽  
Vol 807-809 ◽  
pp. 461-465 ◽  
Author(s):  
Dao Bo Zhou ◽  
En Qi Liu ◽  
Shang Long Chen ◽  
Shi Rong Tang

A new Cd (II) ion-imprinted polymer (Cd (II)-IIP), which can be used for selective adsorption of Cd (II) from aqueous solutions, was successfully prepared based on silica gel particles with the help of surface molecular imprinting technology. The adsorption kinetic curve, adsorption isotherm and selective adsorption were measured by static method. The adsorption kinetics of IIPs for Cd (II) reached the equilibrium at about 10 min. The maximum adsorption capacity was 29.36 mg/g, and the IIPs had much higher adsorption quantity than NIPs. Competitive adsorption studies showed that Cd (II)-IIP offers the advantages of selectivity toward targeted Cd (II) compared with NIP in the presence other metal ions. The results showed that the IIPs possessed good specific adsorption capacity and selectivity for Cd (II).


2014 ◽  
Vol 2 (42) ◽  
pp. 17952-17961 ◽  
Author(s):  
Zhongqi Ren ◽  
Delong Kong ◽  
Keyuan Wang ◽  
Weidong Zhang

To achieve a fast adsorption rate and a high adsorption capacity in the selective adsorption of Cr(vi) from wastewater, a novel Cr(vi) ion imprinted polymer (Cr(vi)-IIP) was synthesized by bulk polymerization with 4-vinyl pyridine (4-VP) as a functional monomer.


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