scholarly journals Contribution of point sources to trace metal levels in urban areas surrounded by industrial activities in the Cantabria Region (Northern Spain)

2011 ◽  
Vol 4 ◽  
pp. 76-86 ◽  
Author(s):  
S. Ruiz ◽  
A. Arruti ◽  
I. Fernández-Olmo ◽  
J.A. Irabien
Keyword(s):  
Trace Metal ◽  
Urban Areas ◽  
Point Sources ◽  
Northern Spain ◽  
Industrial Activities ◽  
Metal Levels

scholarly journals Variations in time and space of trace metal aerosol concentrations in urban areas and their surroundings

2011 ◽  
Vol 11 (5) ◽  
pp. 14747-14776
Author(s):  
T. Moreno ◽  
X. Querol ◽  
A. Alastuey ◽  
C. Reche ◽  
M. Cusack ◽  
...  
Keyword(s):  
Trace Metal ◽  
Urban Areas ◽  
Urban Pollution ◽  
Sea Breeze ◽  
Point Sources ◽  
Fuel Oil ◽  
Physical Parameters ◽  
Spatial And Temporal Variability ◽  
Metal Concentrations ◽  
The City

Abstract. Using an unprecedentedly large geochemical database, we compare temporal and spatial variations in inhalable trace metal background concentrations in a major city (Barcelona, Spain) and at a nearby mountainous site (Montseny) affected by the urban plume. Both sites are contaminated by technogenic metals, with V, Pb, Cu, Zn, Mn, Sn, Bi, Sb and Cd all showing upper continental crust (UCC) normalised values >1 in broadly increasing order. The highest metal concentrations usually occur during winter at Barcelona and summer in Montseny. This seasonal difference was especially marked at the remote mountain site in several elements such as Ti and Rare Earth Elements, which recorded campaign maxima, exceeding PM10 concentrations seen in Barcelona. The most common metals were Zn, Ti, Cu, Mn, Pb and V. Both V and Ni show highest concentrations in summer, and preferentially fractionate into the finest PM sizes (PM1/PM10 > 0.5) especially in Barcelona, this being attributed to regionally dispersed contamination from fuel oil combustion point sources. Within the city, hourly metal concentrations are controlled either by traffic (rush hour double peak for Cu, Sb, Sn, Ba) or industrial plumes (morning peak of Ni, Mn, Cr generated outside the city overnight), whereas at Montseny metal concentrations rise during the morning to a single, prolonged afternoon peak as contaminated air transported by the sea breeze moves into the mountains. Our exceptional database, which includes hourly measurements of chemical concentrations, demonstrates in more detail than previous studies the spatial and temporal variability of urban pollution by trace metals in a given city. Technogenic metalliferous aerosols are commonly fine in size and therefore potentially bioavailable, emphasising the case for basing urban background PM characterisation not only on physical parameters such as mass but also on sample chemistry and with special emphasis on trace metal content.

scholarly journals Environmental issues due to organohalogenated compounds diffuse pollution in groundwater. Emerging issue in the Roman area?

2017 ◽  
Vol 6 (2) ◽  
Author(s):  
Isidoro Bonfà ◽  
Francesco La Vigna ◽  
Simona Martelli ◽  
Lucilla Ticconi
Keyword(s):  
Urban Areas ◽  
Industrial Development ◽  
Environmental Issues ◽  
Point Sources ◽  
Multiple Point ◽  
Industrial Activities ◽  
Clear Point ◽  
Source Contamination ◽  
The City ◽  
Very High

Most of the large urban areas, especially those with a strong industrial vocation, present important contamination of organohlaogenated compunds. Even in the City of Rome, although it has a very limited industrial development, some sites interested by this kind of contamination have been notified in recent years. The distribution of these sites is prevalent in the eastern sector of the city where the few industrial activities present are also located. Concentrations are varied and show both cases of clear point source contamination, where values are very high, and cases where a possible contamination from multiple point sources can be hypothesized. The sites reported fall into a crucial area for the hydrogeology of Rome, that is the "Paleotiber Graben" aquifer, exploited for various uses. To date, there is no proven diffuse contamination of organohalogenated compounds in Rome, nevertheless the purpose of this work is to frame this emerging issue on the basis of the available data.

Effects of moderate pollution on toxic and trace metal levels in calves from a polluted area of northern Spain

2005 ◽  
Vol 31 (4) ◽  
pp. 543-548 ◽  
Author(s):  
M. Miranda ◽  
M. López-Alonso ◽  
C. Castillo ◽  
J. Hernández ◽  
J.L. Benedito
Keyword(s):  
Trace Metal ◽  
Polluted Area ◽  
Northern Spain ◽  
Metal Levels

scholarly journals Variations in time and space of trace metal aerosol concentrations in urban areas and their surroundings

2011 ◽  
Vol 11 (17) ◽  
pp. 9415-9430 ◽  
Author(s):  
T. Moreno ◽  
X. Querol ◽  
A. Alastuey ◽  
C. Reche ◽  
M. Cusack ◽  
...  
Keyword(s):  
Trace Metal ◽  
Urban Areas ◽  
Urban Pollution ◽  
Sea Breeze ◽  
Point Sources ◽  
Fuel Oil ◽  
Physical Parameters ◽  
Spatial And Temporal Variability ◽  
Metal Concentrations ◽  
The City

Abstract. Using an unprecedentedly large geochemical database, we compare temporal and spatial variations in inhalable trace metal background concentrations in a major city (Barcelona, Spain) and at a nearby mountainous site (Montseny) affected by the urban plume. Both sites are contaminated by technogenic metals, with V, Pb, Cu, Zn, Mn, Sn, Bi, Sb and Cd all showing upper continental crust (UCC) normalised values >1 in broadly increasing order. The highest metal concentrations usually occur during winter at Barcelona and summer in Montseny. This seasonal difference was especially marked at the remote mountain site in several elements such as Ti and Rare Earth Elements, which recorded campaign maxima, exceeding PM10 concentrations seen in Barcelona. The most common metals were Zn, Ti, Cu, Mn, Pb and V. Both V and Ni show highest concentrations in summer, and preferentially fractionate into the finest PM sizes (PM1/PM10 > 0.5) especially in Barcelona, this being attributed to regionally dispersed contamination from fuel oil combustion point sources. Within the city, hourly metal concentrations are controlled either by traffic (rush hour double peak for Cu, Sb, Sn, Ba) or industrial plumes (morning peak of Ni, Mn, Cr generated outside the city overnight), whereas at Montseny metal concentrations rise during the morning to a single, prolonged afternoon peak as contaminated air transported by the sea breeze moves into the mountains. Our exceptional database, which includes hourly measurements of chemical concentrations, demonstrates in more detail than previous studies the spatial and temporal variability of urban pollution by trace metals in a given city. Technogenic metalliferous aerosols are commonly fine in size and therefore potentially bioavailable, emphasising the case for basing urban background PM characterisation not only on physical parameters such as mass but also on sample chemistry and with special emphasis on trace metal content.

scholarly journals Urinary Concentrations of Metals and Metalloids in Malaysian Adults

2021 ◽  
Author(s):  
Zurahanim Fasha Anual ◽  
Noraishah Mohammad Sham ◽  
Rashidah Ambak ◽  
Fatimah Othman ◽  
Rafiza Shaharudin
Keyword(s):  
Rural Areas ◽  
Urban Areas ◽  
Inductively Coupled Plasma ◽  
Geometric Mean ◽  
Urine Samples ◽  
Cross Sectional ◽  
Metals And Metalloids ◽  
High Exposure ◽  
Academic Qualification ◽  
Metal Levels

AbstractExposure to environmental pollutants in humans can be conducted through direct measurement of biological media such as blood, urine or hair. Assessment studies of metals and metalloids in Malaysia is very scarce although cross-sectional nationwide human biomonitoring surveys have been established by the USA, Canada, Germany, Spain, France, and Korea. This study aims to assess urinary metal levels namely cadmium (Cd), nickel (Ni), lead (Pb) and arsenic (As) among Malaysian adults. This was a cross-sectional study involving 1440 adults between the age of 18 and 88 years old. After excluding those with 24 h urine samples of less than 500 ml, urine creatinine levels < 0.3 or > 3.0 g/L and those who refuse to participate in the study, a total of 817 respondents were included for analysis. A questionnaire with socio-demographic information such as age, gender, occupation, ethnic, academic qualification and medical history was administered to the respondents. Twenty-four-hour urine samples were collected in a container before being transported at 4 °C to the laboratory. Samples were then aliquoted into 15 ml tubes and kept at − 80 °C until further analysis. Urine was diluted ten-fold with ultrapure water, filtered and analysed for metals and metalloids using Inductively Coupled Plasma-Mass Spectrometry (ICP-MS). The geometric mean of urinary As, Ni, Cd and Pb concentrations among adults in Malaysia was 48.21, 4.37, 0.32, and 0.80 µg/L, respectively. Males showed significantly higher urinary metal concentrations compared to females for As, Cd and Pb except for Ni. Those who resided in rural areas exhibited significantly higher As, Cd and Pb urinary concentrations than those who resided in urban areas. As there are no nationwide data on urinary metals, findings from this study could be used to identify high exposure groups, thus enabling policy makers to improve public health strategically.

scholarly journals Evaluation of Trace Metal Levels in Tissues of Two Commercial Fish Species in Kapar and Mersing Coastal Waters, Peninsular Malaysia

2012 ◽  
Vol 2012 ◽  
pp. 1-10 ◽  
Author(s):  
Fathi Alhashmi Bashir ◽  
Mohammad Shuhaimi-Othman ◽  
A. G. Mazlan
Keyword(s):  
Trace Metal ◽  
Fish Species ◽  
Coastal Waters ◽  
Positive Association ◽  
Peninsular Malaysia ◽  
International Standards ◽  
Metal Concentrations ◽  
Commercial Fish ◽  
Metal Levels ◽  
The Relationship

This study is focused on evaluating the trace metal levels in water and tissues of two commercial fish species Arius thalassinus and Pennahia anea that were collected from Kapar and Mersing coastal waters. The concentrations of Fe, Zn, Al, As, Cd and Pb in these coastal waters and muscle, liver and gills tissues of the fishes were quantified. The relationship among the metal concentrations and the height and weight of the two species were also examined. Generally, the iron has the highest concentrations in both water and the fish species. However, Cd in both coastal waters showed high levels exceeding the international standards. The metal level concentration in the sample fishes are in the descending order livers > gills > muscles. A positive association between the trace metal concentrations and weight and length of the sample fishes was investigated. Fortunately the level of these metal concentrations in fish has not exceeded the permitted level of Malaysian and international standards.

scholarly journals Trace Metal Contamination Characteristics and Health Risks Assessment ofCommelina africanaL. and Psammitic Sandflats in the Niger Delta, Nigeria

2016 ◽  
Vol 2016 ◽  
pp. 1-14 ◽  
Author(s):  
Nsikak U. Benson ◽  
Paul A. Enyong ◽  
Omowunmi H. Fred-Ahmadu
Keyword(s):  
Trace Metal ◽  
Niger Delta ◽  
Anthropogenic Activities ◽  
Hazard Quotient ◽  
Risk Index ◽  
Sediment Quality ◽  
Hazard Index ◽  
Adult Males ◽  
Metal Concentrations ◽  
Metal Levels

The purpose of this study was to investigate and quantify trace metal concentrations inCommelina africanaL. and psammitic sandflats from an intertidal coastal ecosystem in Niger Delta, Nigeria, and to evaluate their spatial distribution, degree of contamination, and source apportionment. The environmental risks associated with soil contamination were elaborately assessed using potential ecological risk index, sediment quality guidelines, and enrichment relative to background levels. The mean concentrations of Cd, Cr, Ni, Pb, and Zn in sandflat soil samples are0.76±9.0×10-2,7.39±8.7×10-1,2.28±0.35,0.024±4.0×10-3, and74.51±2.55 mg/kg, respectively. Metal levels indicate strong variability with sampling sites. The order of trace metal concentrations in theCommelina africanaL. samples isZn>Ni>Cr>Pb>Cd. The concentrations varied with the sample locations; and the levels of Pb (0.05 to 0.08 mg/kg) at all locations are found to be significantly below permissible level of 0.3 mg/kg. Potential sources of metal loadings may be associated with localised or diffused anthropogenic activities. The average carcinogenic risks are below1.0×10-6threshold values, and the sandflat soils are not considered to pose significant health effects to children and adult males and females. However, the carcinogenicity and noncarcinogenicity risks ranking decrease following the orderchildren>adult  males>adult  females. Comparatively, the hazard quotient and hazard index indicate that the psammitic sandflats might pose a health risk to children in future.

scholarly journals Modelling constraints on the emission inventory and on vertical dispersion for CO and SO<sub>2</sub> in the Mexico City Metropolitan Area using Solar FTIR and zenith sky UV spectroscopy

2007 ◽  
Vol 7 (3) ◽  
pp. 781-801 ◽  
Author(s):  
B. de Foy ◽  
W. Lei ◽  
M. Zavala ◽  
R. Volkamer ◽  
J. Samuelsson ◽  
...  
Keyword(s):  
Power Plant ◽  
Mexico City ◽  
Urban Areas ◽  
Emission Inventory ◽  
Uv Spectroscopy ◽  
Transport Processes ◽  
Point Sources ◽  
Large Power ◽  
Vertical Dispersion ◽  
Current Emission

Abstract. Emissions of air pollutants in and around urban areas lead to negative health impacts on the population. To estimate these impacts, it is important to know the sources and transport mechanisms of the pollutants accurately. Mexico City has a large urban fleet in a topographically constrained basin leading to high levels of carbon monoxide (CO). Large point sources of sulfur dioxide (SO2) surrounding the basin lead to episodes with high concentrations. An Eulerian grid model (CAMx) and a particle trajectory model (FLEXPART) are used to evaluate the estimates of CO and SO2 in the current emission inventory using mesoscale meteorological simulations from MM5. Vertical column measurements of CO are used to constrain the total amount of emitted CO in the model and to identify the most appropriate vertical dispersion scheme. Zenith sky UV spectroscopy is used to estimate the emissions of SO2 from a large power plant and the Popocatépetl volcano. Results suggest that the models are able to identify correctly large point sources and that both the power plant and the volcano impact the MCMA. Modelled concentrations of CO based on the current emission inventory match observations suggesting that the current total emissions estimate is correct. Possible adjustments to the spatial and temporal distribution can be inferred from model results. Accurate source and dispersion modelling provides feedback for development of the emission inventory, verification of transport processes in air quality models and guidance for policy decisions.

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