scholarly journals Sorption Recovery of Platinum Metals from Compound Solutions

2016 ◽  
Vol 152 ◽  
pp. 8-12 ◽  
Author(s):  
A.A. Miroshnichenko
2017 ◽  
Vol 62 (14) ◽  
pp. 1797-1818 ◽  
Author(s):  
H. V. Ehrlich ◽  
T. M. Buslaeva ◽  
T. A. Maryutina

Metals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 569
Author(s):  
Georgiy Petrov ◽  
Irina Zotova ◽  
Tatiana Nikitina ◽  
Svetlana Fokina

This paper discusses the scientific rationale for methods of platinum metals sorption centralization from saturated solutions with a high content of macrocomponents. Methods of sorption centralization of platinum and iridium using local anionites such as AH-31, AB-17-8, Purolite S985 are described. The sorbents used were conditioned to remove organic and mineral impurities. The sorption isotherms of platinum group metals 1/EC=f(1/Cp) at a temperature of 20 °C and a duration of 24 h were plotted. The data on the sorption recovery of platinum and iridium from individual and combined sulfate-chloride solutions were determined. Isotherms of iridium sorption from sulfate-chloride solution are formed. Results of the apparent sorption equilibrium constant and values of standard Gibbs energy (ΔG, kJ/mol) of ion exchange for sorption of platinum and iridium from individual and combined sulfate-chloride solutions are presented. Linearized isotherms and kinetic curves of joint sorption of platinum and iridium from sulfate-chloride solution are described. Comparative sorption of the platinum-group metals (PGM) by anionites AB-17-8 and Purolite S985 from sulfate-chloride solutions is shown. The sorption diagram of platinum and iridium from sulfate-chloride product solutions is presented. It has been revealed that complete recovery is achieved using chelation ion-exchange resin Purolite S985, with recovery of Pt up to 95% and Ir more than 73%. The sorption process is accompanied by intradiffusion constraints that are confirmed by the analysis of kinetic curves using Schmukler and Boyd–Adams models.


1983 ◽  
Vol 22 (24) ◽  
pp. 3497-3502 ◽  
Author(s):  
Linda K. Bell ◽  
Joan Mason ◽  
D. Michael P. Mingos ◽  
David G. Tew
Keyword(s):  

Polyhedron ◽  
1994 ◽  
Vol 13 (2) ◽  
pp. 175-179 ◽  
Author(s):  
Terry Clark ◽  
Stephen D. Robinson ◽  
Muhammed A. Mazid ◽  
Michael B. Hursthouse

2003 ◽  
Vol 191 (2) ◽  
pp. 289-294 ◽  
Author(s):  
Robert A.W Johnstone ◽  
Jun-Yao Liu ◽  
Ling Lu ◽  
David Whittaker
Keyword(s):  

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