scholarly journals On-line monitoring of parylene film deposition with quartz crystal microbalance (QCM)

2011 ◽  
Vol 25 ◽  
pp. 321-324 ◽  
Author(s):  
Ga-Yeon Lee ◽  
Hyuk Ko ◽  
Ha-Wook Jung ◽  
Suk-Jin Ye ◽  
Moo-Hwan Kim ◽  
...  
2019 ◽  
Vol 23 (11n12) ◽  
pp. 1495-1504 ◽  
Author(s):  
Mariya V. Tesakova ◽  
Sergey M. Kuzmin ◽  
Vladimir I. Parfenyuk

The process of 5,10,15,20-tetrakis(4-hydroxyphenyl)porphyrin electropolymerization has been studied by the quartz crystal microbalance method in different electrodeposition conditions. The films were deposited in two modes: in potentiostatic conditions (at the potential of [Formula: see text]2 V) and in potentiodynamic conditions (CV with the potential scan rate of 20 mV/s). The effect of electrolysis parameters on 5,10,15,20-tetrakis(4-hydroxyphenyl)porphyrin electropolymerization has been studied by obtaining films in two modes and using two supporting electrolytes: tetrabutylammonium perchlorate or tetrabutylammonium hexafluorophosphate. The biggest film mass gain was observed on a clean electrode surface. At further film deposition on the polyporphyrin-coated electrode, the film mass growth stopped. The electrodeposition effectiveness was somewhat higher in the potentiodynamic conditions, with the formation of a looser film. The nature of the supporting electrolyte did not have a significant effect on the electrodeposition process. A significant contribution to the deposition was made by the electrode material. The film thickness was 25–80 nm. The films possessed [Formula: see text]-type conductivity; and the flat-band potential for poly-H[Formula: see text]T(4-OHPh)P obtained in potentiodynamic conditions was 0.33 V, for poly-H[Formula: see text]T(4-OHPh)P obtained in potentiostatic conditions it was 0.16 V.


1993 ◽  
Vol 65 (1) ◽  
pp. 65-69 ◽  
Author(s):  
David E. Nivens ◽  
James Q. Chambers ◽  
Tina R. Anderson ◽  
David C. White

2000 ◽  
Vol 239 (1-2) ◽  
pp. 121-124 ◽  
Author(s):  
Shiming Lin ◽  
Chih-Cheng Lu ◽  
Hsiung-Fei Chien ◽  
Su-Ming Hsu

Sign in / Sign up

Export Citation Format

Share Document