scholarly journals Role of Grain Boundaries in diffusional Phenomena during Gas Nitriding of Pure Iron

2011 ◽  
Vol 10 ◽  
pp. 2943-2948 ◽  
Author(s):  
S. Fare ◽  
N. Lecis ◽  
E. Brescia ◽  
M. Mazzola
Keyword(s):  
Grain Boundaries ◽  
Pure Iron ◽  
Gas Nitriding

Elucidation of block boundaries as the dissolution channels in hydrated cement

1978 ◽  
Vol 36 (1) ◽  
pp. 484-485
Author(s):  
N.V. Belov ◽  
U.I. Papiashwili ◽  
B.E. Yudovich
Keyword(s):  
Liquid Phase ◽  
Grain Boundaries ◽  
Benzoyl Peroxide ◽  
Phase Contrast ◽  
Active Role ◽  
Point Of View ◽  
Hardened Cement ◽  
Hydrated Cement ◽  
Hardened Cement Paste

It has been almost universally adopted that dissolution of solids proceeds with development of uniform, continuous frontiers of reaction.However this point of view is doubtful / 1 /. E.g. we have proved the active role of the block (grain) boundaries in the main phases of cement, these boundaries being the areas of hydrate phases' nucleation / 2 /. It has brought to the supposition that the dissolution frontier of cement particles in water is discrete. It seems also probable that the dissolution proceeds through the channels, which serve both for the liquid phase movement and for the drainage of the incongruant solution products. These channels can be appeared along the block boundaries.In order to demonsrate it, we have offered the method of phase-contrast impregnation of the hardened cement paste with the solution of methyl metacrylahe and benzoyl peroxide. The viscosity of this solution is equal to that of water.

Carbide precipitation and chromium depletion on coherent twin boundaries in deformed 304 stainless steels

1992 ◽  
Vol 50 (2) ◽  
pp. 1216-1217
Author(s):  
A.H. Advani ◽  
L.E. Murr ◽  
D.J. Matlock ◽  
W.W. Fisher ◽  
P.M. Tarin ◽  
...  
Keyword(s):  
Grain Boundaries ◽  
Stainless Steels ◽  
Interfacial Free Energy ◽  
Carbide Precipitation ◽  
Twin Boundaries ◽  
Invariant Structure ◽  
Heat Treated ◽  
Constant Structure ◽  
Cr Depletion

Coherent annealing-twin boundaries are constant structure and energy interfaces with an average interfacial free energy of ∼19mJ/m2 versus ∼210 and ∼835mJ/m2 for incoherent twins and “regular” grain boundaries respectively in 304 stainless steels (SS). Due to their low energy, coherent twins form carbides about a factor of 100 slower than grain boundaries, and limited work has also shown differences in Cr-depletion (sensitization) between twin versus grain boundaries. Plastic deformation, may, however, alter the kinetics and thermodynamics of twin-sensitization which is not well understood. The objective of this work was to understand the mechanisms of carbide precipitation and Cr-depletion on coherent twin boundaries in deformed SS. The research is directed toward using this invariant structure and energy interface to understand and model the role of interfacial characteristics on deformation-induced sensitization in SS. Carbides and Cr-depletion were examined on a 20%-strain, 0.051%C-304SS, heat treated to 625°C-4.5h, as described elsewhere.

scholarly journals Internal melt figures in ice by rapid adiabatic compression

1994 ◽  
Vol 40 (134) ◽  
pp. 132-134
Author(s):  
R.E. Gagnon ◽  
C. Tulk ◽  
H. Kiefte
Keyword(s):  
Phase Transformations ◽  
Grain Boundaries ◽  
Single Crystals ◽  
Adiabatic Compression ◽  
Air Bubbles ◽  
Water Ice ◽  
Deep Focus ◽  
And Behavior ◽  
First Time

AbstractSingle crystals and bicrystals of water ice have been adiabatically pressurized to produce, and clearly illustrate, two types of internal melt figures: (1) dendritic figures that grow from nucleation imperfections on the specimen’s surface, or from air bubbles at grain boundaries, into the ice as pressure is elevated; and (2) compression melt fractures, flat liquid-filled disks, that nucleate at imperfections in the crystal and grow with the application of pressure eventually to sprout dendritic fingers at the periphery. The transparency of the ice permitted visualization of the growth and behavior of the figures, and this could be an important tool in understanding the role of phase transformations in deep-focus earthquakes. Correlation between figure size and pressure is noted for the first time.

Microstructure of Polycrystalline MgO Penetrated by a Silicate Liquid

1996 ◽  
Vol 2 (3) ◽  
pp. 113-128 ◽  
Author(s):  
Sundar Ramamurthy ◽  
Michael P. Mallamaci ◽  
Catherine M. Zimmerman ◽  
C. Barry Carter ◽  
Peter R. Duncombe ◽  
...  
Keyword(s):  
Grain Boundaries ◽  
Grain Growth ◽  
Glassy Phase ◽  
Silicate Liquid ◽  
Two Phase ◽  
The Matrix ◽  
Devitrification Process ◽  
Phase Mixture

Dense, polycrystalline MgO was infiltrated with monticellite (CaMgSiO4) liquid to study the penetration of liquid along the grain boundaries of MgO. Grain growth was found to be restricted with increasing amounts of liquid. The inter-granular regions were generally found to be comprised of a two-phase mixture: crystalline monticellite and a glassy phase rich in the impurities present in the starting MgO material. MgO grains act as seeding agents for the crystallization of monticellite. The location and composition of the glassy phase with respect to the MgO grains emphasizes the role of intergranular liquid during the devitrification process in “snowplowing” impurities present in the matrix.

Role of the solid/liquid interface faceting in rapid penetration of a liquid phase along grain boundaries

2001 ◽  
Vol 49 (7) ◽  
pp. 1123-1128 ◽  
Author(s):  
D. Chatain ◽  
E. Rabkin ◽  
J. Derenne ◽  
J. Bernardini
Keyword(s):  
Liquid Phase ◽  
Grain Boundaries ◽  
Liquid Interface ◽  
Solid Liquid Interface ◽  
Solid Liquid

scholarly journals Quantification of electron accumulation at grain boundaries in perovskite polycrystalline films by correlative infrared-spectroscopic nanoimaging and Kelvin probe force microscopy

2021 ◽  
Vol 10 (1) ◽  
Author(s):  
Ting-Xiao Qin ◽  
En-Ming You ◽  
Mao-Xin Zhang ◽  
Peng Zheng ◽  
Xiao-Feng Huang ◽  
...  
Keyword(s):  
Solar Cell ◽  
Grain Boundaries ◽  
Cell Performance ◽  
Kelvin Probe Force Microscopy ◽  
Light Illumination ◽  
Kelvin Probe ◽  
Solar Cell Performance ◽  
Force Microscopy ◽  
Infrared Spectroscopic

AbstractOrganic–inorganic halide perovskites are emerging materials for photovoltaic applications with certified power conversion efficiencies (PCEs) over 25%. Generally, the microstructures of the perovskite materials are critical to the performances of PCEs. However, the role of the nanometer-sized grain boundaries (GBs) that universally existing in polycrystalline perovskite films could be benign or detrimental to solar cell performance, still remains controversial. Thus, nanometer-resolved quantification of charge carrier distribution to elucidate the role of GBs is highly desirable. Here, we employ correlative infrared-spectroscopic nanoimaging by the scattering-type scanning near-field optical microscopy with 20 nm spatial resolution and Kelvin probe force microscopy to quantify the density of electrons accumulated at the GBs in perovskite polycrystalline thin films. It is found that the electron accumulations are enhanced at the GBs and the electron density is increased from 6 × 1019 cm−3 in the dark to 8 × 1019 cm−3 under 10 min illumination with 532 nm light. Our results reveal that the electron accumulations are enhanced at the GBs especially under light illumination, featuring downward band bending toward the GBs, which would assist in electron-hole separation and thus be benign to the solar cell performance.

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