A high-temperature shock tube kinetic study for the branching ratios of isobutene + OH reaction

2017 ◽  
Vol 36 (1) ◽  
pp. 265-272 ◽  
Author(s):  
Fethi Khaled ◽  
Binod Raj Giri ◽  
Aamir Farooq
1986 ◽  
Vol 39 (5) ◽  
pp. 723 ◽  
Author(s):  
CY Lin ◽  
CY Lin ◽  
MC Lin ◽  
MC Lin

The kinetics and mechanism of the CH3+C6H5O reaction have been examined by means of the RRKM theory and kinetic modelling . Both the high temperature shock tube data for the production of cresols and the low temperature branching ratios (for production of cresols against methylcyclohexadienones , CH3C6H5O) derived from Mulcahy and Williams's data1 on the pyrolysis of di -t-butyl peroxide and phenol mixtures could be reasonably accounted for by the mechanism: ���������� CH3+C6H5O → CH3C6H5O → o- and p-CH3C6H4OH+M→ CH3C6H5OThe energy barrier for the thermal isomerization of CH3C6H5O to cresols was estimated to be ~ 132 kJ mol-1.


2020 ◽  
Author(s):  
Samuel J. Petter ◽  
Kyle P. Lynch ◽  
Paul Farias ◽  
Seth Spitzer ◽  
Thomas Grasser ◽  
...  

2010 ◽  
Vol 24 (11) ◽  
pp. 5834-5843 ◽  
Author(s):  
Khalid Emilio Noorani ◽  
Benjamin Akih-Kumgeh ◽  
Jeffrey M. Bergthorson

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