Photoionization mass spectrometry and modeling study of premixed flames of three unsaturated C5H8O2 esters

2013 ◽  
Vol 34 (1) ◽  
pp. 443-451 ◽  
Author(s):  
B. Yang ◽  
C.K. Westbrook ◽  
T.A. Cool ◽  
N. Hansen ◽  
K. Kohse-Höinghaus
Keyword(s):  
Mass Spectrometry ◽  
Premixed Flames ◽  
Photoionization Mass Spectrometry ◽  
Modeling Study

scholarly journals Photoionization mass spectrometry and modeling study of a low-pressure premixed flame of ethyl pentanoate (ethyl valerate)

2017 ◽  
Vol 36 (1) ◽  
pp. 1185-1192 ◽  
Author(s):  
D.A. Knyazkov ◽  
I.E. Gerasimov ◽  
N. Hansen ◽  
A.G. Shmakov ◽  
O.P. Korobeinichev
Keyword(s):  
Mass Spectrometry ◽  
Low Pressure ◽  
Premixed Flame ◽  
Photoionization Mass Spectrometry ◽  
Modeling Study

scholarly journals An Experimental and Master-Equation Modeling Study of the Kinetics of the Reaction between Resonance-Stabilized (CH3)2CCHCH2 Radical and Molecular Oxygen

2021 ◽  
Author(s):  
Satya Joshi ◽  
Timo Pekkanen ◽  
Prasenjit Seal ◽  
Raimo Timonen ◽  
Arkke Eskola
Keyword(s):  
Mass Spectrometry ◽  
Master Equation ◽  
Molecular Oxygen ◽  
Equation Modeling ◽  
Photoionization Mass Spectrometry ◽  
Kinetics Of ◽  
Modeling Study

The kinetics of the reaction between resonance stabilized (CH3)2CCHCH2 radical (R) and O2 has been investigated using photoionization mass spectrometry, and master equation (ME) simulations were performed to support experimental...

Understanding the Homogeneous Reactions of Primary Tar from Biomass Pyrolysis by Means of Photoionization Mass Spectrometry

2020 ◽  
Vol 34 (10) ◽  
pp. 12678-12687 ◽  
Author(s):  
Ke Yang ◽  
Jiahao Wang ◽  
Jiahui Huang ◽  
Jiuzhong Yang ◽  
Yang Pan ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Biomass Pyrolysis ◽  
Photoionization Mass Spectrometry ◽  
Homogeneous Reactions

Analysis of neonicotinoids from plant material by desorption atmospheric pressure photoionization-mass spectrometry

2015 ◽  
Vol 29 (5) ◽  
pp. 424-430 ◽  
Author(s):  
Anu Vaikkinen ◽  
Henning S. Schmidt ◽  
Iiro Kiiski ◽  
Sari Rämö ◽  
Kati Hakala ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Atmospheric Pressure ◽  
Plant Material ◽  
Atmospheric Pressure Photoionization ◽  
Photoionization Mass Spectrometry

Thermochemistry of Organic and Heteroorganic Species. Part IX. Photoionization Studies of Isomerization and Fragmentation of Polysubstituted Cyclopropenes: Phenyl-Substituted Cyclopropenes

2000 ◽  
Vol 6 (1) ◽  
pp. 53-64 ◽  
Author(s):  
V.V. Takhistov ◽  
I.N. Domnin ◽  
D.A. Ponomarev
Keyword(s):  
Mass Spectrometry ◽  
Enthalpy Of Formation ◽  
Good Alternative ◽  
Enthalpies Of Formation ◽  
Isodesmic Reactions ◽  
Ion Structure ◽  
Photoionization Mass Spectrometry ◽  
General Methodology ◽  
Fragment Ions ◽  
The Enthalpy Of Formation

Ionization and appearance energies of some fragment ions from 1,2,3-trimethy1-3-phenyl-, 3-methyl-1,2,3-triphenyl-, 1,2-diphenyl-3-methoxycarbonyl-, 1,2,3-triphenyl-3-methoxycarbonyl- and 1,3,3-triphenyl-2-methoxycarbonyl-cyclopropenes were measured by photoionization mass spectrometry. It was shown that in none of these compounds did the fragment ions possess the expected stable substituted cyclopropenium ion structure. Accordingly, possible schemes of molecular ion isomerization are given. The enthalpies of formation of nearly 50 substituted cyclopropenium ions, and ions of related structure, were estimated using series of isodesmic reactions. This publication, together with the previous works of the authors in this Journal, demonstrates the general methodology for estimation of the enthalpy of formation for even-electron ions. It is suggested that the present methodology can provide a good alternative to other estimation or computation procedures applied to the thermochemistry of ions.

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