Fire behavior of flame retarded unsaturated polyester resin with high nitrogen content additives

2020 ◽  
Vol 84 ◽  
pp. 106379 ◽  
Author(s):  
Kamila Salasinska ◽  
Maciej Celiński ◽  
Mateusz Barczewski ◽  
Michał K. Leszczyński ◽  
Monika Borucka ◽  
...  
Molecules ◽  
2021 ◽  
Vol 26 (4) ◽  
pp. 932
Author(s):  
Kamila Sałasińska ◽  
Maciej Celiński ◽  
Kamila Mizera ◽  
Mateusz Barczewski ◽  
Paweł Kozikowski ◽  
...  

In this paper, the fire behavior of unsaturated polyester resin (UP) modified with L-histidinium dihydrogen phosphate-phosphoric acid (LHP), being a novel intumescent fire retardant (IFR), was investigated. Thermal and thermomechanical properties of the UP with different amounts of LHP (from 10 to 30 wt. %) were determined by thermogravimetric analysis (TG) as well as dynamic mechanical thermal analysis (DMTA). Reaction to small flames was studied by horizontal burning (HB) test, while fire behavior and smoke emission were investigated with the cone calorimeter (CC) and smoke density chamber. Further, the analysis of volatile products was conducted (TGA/FT-IR). It was observed that the addition of LHP resulted in the formation of carbonaceous char inhibiting the thermal decomposition, burning rate and smoke emission. The most promising results were obtained for the UP containing 30 wt. % of LHP, for which the highest reduction in maximum values of heat release rate (200 kW/m2) and total smoke release (3535 m2/m2) compared to unmodified polymer (792 kW/m2 and 6895 m2/m2) were recorded. However, some important disadvantage with respect to water resistance was observed.


EDIS ◽  
2013 ◽  
Vol 2013 (11) ◽  
Author(s):  
Michael A. Davis ◽  
Doug R. Sloan ◽  
Gerald Kidder ◽  
R. D. Jacobs

Animal manures have been used as natural crop fertilizers for centuries. Because of poultry manure’s high nitrogen content, it has long been recognized as one of the most desirable manures. Besides fertilizing crops, manures also supply other essential plant nutrients and serve as a soil amendment by adding organic matter, which helps improve the soil’s moisture and nutrient retention. Organic matter persistence will vary with temperature, drainage, rainfall, and other environmental factors. This 2-page fact sheet was written by Michael A. Davis, D.R. Sloan, Gerald Kidder, and R.D. Jacobs, and published by the UF Department of Animal Science, November 2013. http://edis.ifas.ufl.edu/aa205


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