Surface modification effect of carbon molecular sieve (CMS) on the morphology and separation performance of mixed matrix membranes

2019 ◽  
Vol 80 ◽  
pp. 106152 ◽  
Author(s):  
Amelia S. Wiryoatmojo ◽  
Hafiz Abdul Mannan ◽  
Rizwan Nasir ◽  
Hilmi Mukhtar ◽  
Dzeti Farhah Mohshim ◽  
...  
Keyword(s):  
Surface Modification ◽  
Molecular Sieve ◽  
Mixed Matrix Membranes ◽  
Separation Performance ◽  
Mixed Matrix ◽  
Carbon Molecular Sieve ◽  
Modification Effect ◽  
Matrix Membranes

Surface modification of molecular sieve fillers for mixed matrix membranes

2018 ◽  
Vol 538 ◽  
pp. 333-342 ◽  
Author(s):  
Giovanni Golemme ◽  
Alfonso Policicchio ◽  
Eloisa Sardella ◽  
Giuseppina De Luca ◽  
Beatrice Russo ◽  
...  
Keyword(s):  
Surface Modification ◽  
Molecular Sieve ◽  
Mixed Matrix Membranes ◽  
Mixed Matrix ◽  
Matrix Membranes

Composite mixed matrix membranes incorporating microporous carbon molecular sieve as filler in polyethersulfone for CO 2 /CH 4 separation

2019 ◽  
Vol 137 (12) ◽  
pp. 48476 ◽  
Author(s):  
Mohamed Janshir Bin Gulam Mohamed ◽  
Hafiz Abdul Mannan ◽  
Rizwan Nasir ◽  
Dzeti Farhah Mohshim ◽  
Hilmi Mukhtar ◽  
...  
Keyword(s):  
Molecular Sieve ◽  
Microporous Carbon ◽  
Mixed Matrix Membranes ◽  
Mixed Matrix ◽  
Carbon Molecular Sieve ◽  
Matrix Membranes

Effect of Carbon Molecular Sieve (CMS) Concentration on Mixed Matrix Membranes (MMMs) Performance for Carbon Dioxide Removal

2015 ◽  
Vol 754-755 ◽  
pp. 869-873 ◽  
Author(s):  
Rizwan Nasir ◽  
Hilmi Mukhtar ◽  
Maizatul Shima Shaharun ◽  
Zakaria Man
Keyword(s):  
Molecular Sieve ◽  
Gas Permeation ◽  
Polymer Chains ◽  
Mixed Matrix Membranes ◽  
Size Discrimination ◽  
Mixed Matrix ◽  
Carbon Molecular Sieve ◽  
Solution Casting Method ◽  
Pes Membrane ◽  
Matrix Membranes

Different compositions of carbon molecular sieve (CMS) were incorporated in polyethersulfone (PES) matrix to fabricate mixed matrix membranes (MMMs) by solution casting method. The characterization was carried out using field emission scanning electron microscopy (FESEM) analysis to investigate the morphology of membrane. FESEM images showed acceptable contacts between the filler particles and the polymer chains. The performance of the developed membrane is analyzed by single gas permeation measurement of high purity CO2 and CH4. Both CO2 permeance and CO2/CH4 selectivity increased with CMS loadings as compared to pure PES membrane. Experimental results showed that the highest value of CO2 permeance (66.71 GPU) and CO2/CH4 selectivity (10.94) can be achieved with 30 wt. % loading of CMS particles. This can be credited to size discrimination of CMS pores that falls between CO2 and CH4 kinetic diameters.

scholarly journals Physical aging in glassy mixed matrix membranes; tuning particle interaction for mechanically robust nanocomposite films

2016 ◽  
Vol 4 (27) ◽  
pp. 10627-10634 ◽  
Author(s):  
Stefan J. D. Smith ◽  
Cher Hon Lau ◽  
James I. Mardel ◽  
Melanie Kitchin ◽  
Kristina Konstas ◽  
...  
Keyword(s):  
Physical Aging ◽  
Particle Interaction ◽  
Nanocomposite Films ◽  
Mixed Matrix Membranes ◽  
Separation Performance ◽  
Mixed Matrix ◽  
Membrane Technologies ◽  
Matrix Membranes

Addressing the mechanical weakness and physical aging of glassy mixed matrix membranes to realise their potential for enhancing the separation performance of current membrane technologies.

scholarly journals THE EFFECT OF TYPE ZEOLITE ON THE GAS TRANSPORT PROPERTIES OF POLYIMIDE-BASED MIXED MATRIX MEMBRANES

REAKTOR ◽  
2008 ◽  
Vol 12 (2) ◽  
pp. 68 ◽  
Author(s):  
Tutuk Djoko Kusworo ◽  
Ahmad Fauzi Ismail ◽  
Azeman Mustafa ◽  
Kang Li
Keyword(s):  
Mixed Matrix Membranes ◽  
Mixed Matrix Membrane ◽  
Separation Performance ◽  
Mixed Matrix ◽  
Scanning Calorimetry ◽  
Zeolite 4A ◽  
Intensity Changes ◽  
Zeolite Type ◽  
Type Zeolite ◽  
Matrix Membranes

The permeation rates of O2, N2, CO2 and CH4 has been studied for polyimide-polyethersulfone (PI/PES) blends-zeolite mixed matrix membranes synthesized in our laboratory. The study investigated the effect of zeolite loading and different zeolite type on the gas separation performance of these mixed matrix membranes. Frequency shifts and absorption intensity changes in the FTIR spectra of the PI/PES blends as compared with those of the pure polymers indicate that there is a mixing of polymer blends at the molecular level. Differential scanning calorimetry measurements of pure and PI/PES blends membranes have showed one unique glass transition temperature that supports the miscible character of the PI/PES mixture. The PI/PES-zeolite 4A mixed matrix membrane with 25 wt % zeolite loading produced the highest O2/N2 and CO2/CH4 selectivity of around 7.45 and 46.05, respectively.

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