A multistep methodology based on developed Takayanagi, Paul and Ouali models for tensile modulus of polymer/carbon nanotubes nanocomposites above percolation threshold assuming the contribution of interphase regions

2018 ◽  
Vol 69 ◽  
pp. 1-8 ◽  
Author(s):  
Navid Jamalzadeh ◽  
Sahar Heidary ◽  
Yasser Zare ◽  
Kyong Yop Rhee
Keyword(s):  
Carbon Nanotubes ◽  
Percolation Threshold ◽  
Tensile Modulus

An Innovative Method to Reduce Percolation Threshold of Carbon Nanotubes Filled Nylon6/Polystyrene Blends

2012 ◽  
Vol 557-559 ◽  
pp. 654-658
Author(s):  
Chang Lu ◽  
Xin Hui Huang ◽  
Jia Xi Wang ◽  
Xiao Ning Hu
Keyword(s):  
Carbon Nanotubes ◽  
Maleic Anhydride ◽  
Percolation Threshold ◽  
Polymer Blend ◽  
Immiscible Polymer Blend ◽  
Innovative Method ◽  
Immiscible Polymer ◽  
Selective Localization

Selective localization of carbon nanotubes (CNTs) at the interface of immiscible polymer blend was achieved by the method that poly(styrene-co-maleic anhydride) (SMA) was first reacted with CNTs, and then blended with nylon6/polystyrene (PA6/PS). In the PA6/PS blends, CNTs was localized in PA6 phase and the percolation threshold was 2wt%. However, for the PA6/PS/(SMA- CNTs) composites, TEM results showed that most of CNTs were selectively localized in matrix, but some of tubes were induced by SMA to disperse at the interface. The localization of CNTs at the interface caused the percolation threshold of PA6/PS/(SMA- CNTs) was only 0.33 wt%, which is much lower than that of PA6/PS/ CNTs.

SILK FIBROIN FILMS CRYSTALLIZED BY MULTIWALLED CARBON NANOTUBES

2008 ◽  
Vol 22 (09n11) ◽  
pp. 1807-1812 ◽  
Author(s):  
H.-S. KIM ◽  
W.-I. PARK ◽  
Y. KIM ◽  
H.-J. JIN
Keyword(s):  
Electron Microscopy ◽  
Carbon Nanotubes ◽  
Multiwalled Carbon Nanotubes ◽  
Silk Fibroin ◽  
Composite Films ◽  
Tensile Modulus ◽  
Multiwalled Carbon ◽  
Regenerated Silk Fibroin ◽  
Silk Films ◽  
Β Sheet

Silk films prepared from regenerated silk fibroin are normally stabilized by β-sheet formation through the use of solvents (methanol, water etc.). Herein, we report a new method of preparing water-stable films without a β-sheet conformation from regenerated silk fibroin solutions by incorporating a small amount (0.2 wt%) of multiwalled carbon nanotubes (MWCNTs). To extend the biomaterial utility of silk proteins, forming water-stable silk-based materials with enhanced mechanical properties is essential. Scanning electron microscopy and transmission electron microscopy were used to observe the morphology of the MWCNT-incorporated silk films. The wide-angle X-ray diffraction provided clear evidence of the crystallization of the silk fibroin induced by MWCNT in the composite films without any additional annealing processing. The tensile modulus and strength of the composite films were improved by 108% and 51%, respectively, by the incorporation of 0.2 wt% of MWCNTs, as compared with those of the pure silk films. The method described in this study will provide an alternative means of crystallizing silk fibroin films without using an organic solvent or blending with any other polymers, which may be important in biomedical applications.

scholarly journals Advanced Models for Modulus and Strength of Carbon-Nanotube-Filled Polymer Systems Assuming the Networks of Carbon Nanotubes and Interphase Section

Mathematics ◽  
2021 ◽  
Vol 9 (9) ◽  
pp. 990
Author(s):  
Yasser Zare ◽  
Kyongyop Rhee
Keyword(s):  
Carbon Nanotubes ◽  
Shear Strength ◽  
Carbon Nanotube ◽  
Interfacial Shear Strength ◽  
Tensile Modulus ◽  
Interfacial Shear ◽  
Filled Polymer ◽  
Polymer Systems

This study focuses on the simultaneous stiffening and percolating characteristics of the interphase section in polymer carbon nanotubes (CNTs) systems (PCNTs) using two advanced models of tensile modulus and strength. The interphase, as a third part around the nanoparticles, influences the mechanical features of such systems. The forecasts agree well with the tentative results, thus validating the advanced models. A CNT radius of >40 nm and CNT length of <5 μm marginally improve the modulus by 70%, while the highest modulus development of 350% is achieved with the thinnest nanoparticles. Furthermore, the highest improvement in nanocomposite’s strength (350%) is achieved with the CNT length of 12 μm and interfacial shear strength of 8 MPa. Generally, the highest ranges of the CNT length, interphase thickness, interphase modulus and interfacial shear strength lead to the most desirable mechanical features.

Properties of poly(lactic acid)/montmorillonite/carbon nanotubes nanocomposites: determination of percolation threshold

2021 ◽  
Author(s):  
Olawale Monsur Sanusi ◽  
Abdelkibir Benelfellah ◽  
Lazaros Papadopoulos ◽  
Zoe Terzopoulou ◽  
Dimitrios N. Bikiaris ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Lactic Acid ◽  
Percolation Threshold ◽  
Poly Lactic Acid

Dielectric and Thermomechanical Properties of Polypropylene/Multi-Walled Carbon Nanotubes Nanocomposites

2007 ◽  
Vol 1056 ◽  
Author(s):  
A. Kanapitsas ◽  
E. Logakis ◽  
C. Pandis ◽  
I. Zuburtikudis ◽  
P. Pissis ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Percolation Threshold ◽  
Mechanical Analysis ◽  
Thermomechanical Properties ◽  
Dielectric Relaxation Spectroscopy ◽  
Melt Mixing ◽  
Polypropylene Nanocomposites ◽  
Multi Walled Carbon Nanotubes ◽  
Permittivity Measurements ◽  
Walled Carbon Nanotubes

ABSTRACTThe purpose of this work is to examine the dielectric, electrical and thermo-mechanical properties of multi-walled carbon nanotubes (MWCNT) filled polypropylene nanocomposites formed by melt-mixing. To that aim dielectric relaxation spectroscopy (DRS) and dymamic mechanical analysis (DTMA) were employed. The results are discussed in terms of nucleating action of MWCNT and interfacial polymer-filler interactions. Special attention is paid to percolation aspects by both ac conductivity measurements for the samples which are above the percolation threshold and permittivity measurements for the samples which are below percolation threshold.

Terahertz Transmission Limiters Using Randomly Oriented Carbon Nanotubes Network Near Percolation Threshold

2020 ◽  
Vol 97 (7) ◽  
pp. 329-335
Author(s):  
Junsung Park ◽  
Jin Ho Kim ◽  
Jimmy Xu ◽  
Michael Shur
Keyword(s):  
Carbon Nanotubes ◽  
Percolation Threshold ◽  
Terahertz Transmission
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