Bio-based polylactide/epoxidized natural rubber thermoplastic vulcanizates with a co-continuous phase structure

2017 ◽  
Vol 64 ◽  
pp. 200-206 ◽  
Author(s):  
Daosheng Yuan ◽  
Jianping Ding ◽  
Wenjie Mou ◽  
Yanpeng Wang ◽  
Yukun Chen
Keyword(s):  
Natural Rubber ◽  
Phase Structure ◽  
Continuous Phase ◽  
Epoxidized Natural Rubber ◽  
Thermoplastic Vulcanizates

Co-Continuous Phase Structure and Properties of Poly(vinylidene Fluoride)/Epoxidized Natural Rubber Blends

2012 ◽  
Vol 626 ◽  
pp. 71-74 ◽  
Author(s):  
Subhan Salaeh ◽  
Charoen Nakason ◽  
Gisèle Boiteux ◽  
Philippe Cassagnau
Keyword(s):  
Dielectric Properties ◽  
Natural Rubber ◽  
Phase Structure ◽  
Vinylidene Fluoride ◽  
Grain Morphology ◽  
Continuous Phase ◽  
Epoxidized Natural Rubber ◽  
Morphological Properties ◽  
Blending Method ◽  
Poly Vinylidene Fluoride

Thermoplastic elastomer based on poly (vinylidene fluoride) (PVDF) and epoxidized natural rubber (ENR) blends at 50/50 by weight with different type of ENR (i.e., ENR with 25 and 50 mol% epoxide which are called as ENR-25 and ENR-50, respectively) has been prepared by melt blending method. Difference content of epoxide groups in ENR molecules on dynamic mechanical properties, dielectric properties and morphological properties of blends were investigated. The morphology reveals the co-continuous phase structure of PVDF and ENR phases. Furthermore, ENR-50/PVDF blend showed finer grain morphology and the glass transition (Tg) of the rubber phase was shifted to lower temperature. The structure of the blends correlated well with permittivity (ε) in dielectric properties with the permittivity of PVDF/ENR-50 higher than that of PVDF/ENR-25.

Mixing Methods Influencing on Properties of Epoxidized Natural Rubber/Polypropylene Thermoplastic Vulcanizates

2013 ◽  
Vol 844 ◽  
pp. 109-112 ◽  
Author(s):  
Chesidi Hayichelaeh ◽  
Charoen Nakason ◽  
Anoma Thitithammawong
Keyword(s):  
Mechanical Properties ◽  
Natural Rubber ◽  
Dynamic Mechanical Properties ◽  
Epoxidized Natural Rubber ◽  
Melt Mixing ◽  
Dynamic Mechanical ◽  
Thermoplastic Vulcanizates ◽  
Mixing Method ◽  
Internal Mixer

Epoxidized natural rubber (ENR)/Polypropylene (PP) thermoplastic vulcanizates were prepared by melt mixing method in an internal mixer. Influences of different mixing methods for incorporation of processing oil into the TPVs on tensile and dynamic mechanical properties of the TPVs and crystallinity of the PP were investigated. Results show that distribution of processing oil in the ENR/PP TPV is important due to the processing oil can promote and in the same time can interrupt an improvement in elastomeric properties of the TPV. Incorporation of processing oil into the ENR phase by preparation of oil extended ENR (the mixing method 1) before mixing with the PP was the better way to produce the TPV. It promoted the TPV with superior tensile and dynamic mechanical properties than the TPVs prepared from the mixing method 2 and 3 in which the processing oil was directly added into the PP phase. Furthermore, the TPV from the mixing method 1 had less effect of processing oil on the PP crystallization.

Effect of Curing System on Morphological, Rheological, Thermal and Mechanical Properties of Thermoplastic Vulcanizates Based on Epoxidized Natural Rubber and Polypropylene

2012 ◽  
Vol 602-604 ◽  
pp. 690-695
Author(s):  
Hua Dong Wang ◽  
Rui Wang ◽  
Mao Fang Huang ◽  
Qi Yang
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Tensile Strength ◽  
Natural Rubber ◽  
Epoxidized Natural Rubber ◽  
Thermal And Mechanical Properties ◽  
Rheological Analysis ◽  
Elongation At Break ◽  
Thermoplastic Vulcanizates ◽  
Internal Mixer

Thermoplastic vulcanizates (TPVs) based on epoxidized natural rubber (ENR) and polypropylene (PP) were prepared in an internal mixer at 180°C. The effects of curing systems (i.e., sulfur and peroxide) on morphological, rheological, thermal and mechanical properties were studied. It is found that the sulfur cured TPVs show higher tensile strength, tear strength and elongation at break than those cured with the DCP systems. The rheological analysis indicates that TPVs cured with DCP system show lower apparent shear viscosity than those with sulfur system. SEM studies show that TPVs vulcanized with DCP system exhibit smaller and finely dispersed rubber domains, which provides it higher thermal stability than sulfur cured TPVs.

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