scholarly journals A comparative study on extrudate swell ratio of polystyrene in a capillary rheometer and a single screw extruder

2005 ◽  
Vol 24 (8) ◽  
pp. 948-952 ◽  
Author(s):  
N. Sombatsompop ◽  
N.-T. Intawong
2011 ◽  
Vol 194-196 ◽  
pp. 1506-1509 ◽  
Author(s):  
Hong Wang ◽  
Jing Guo ◽  
Xi Yang He

The polypropylene (PP)/ poly(phenylene sulfide) (PPS) in-situ microfibrillar composites were prepared by the melt blending technology using a single screw extruder. Maleic anhydride grafted polypropylene (PP-g-MAH) is used as the compatibilizer. The rheology was characterized on capillary rheometer, and thermal behaviors of the PP/PPS were investigated by DSC. The experiment results reveal that the melting PP/PPS composites conform to the law of Non-Newton and show typical shear-thinning behavior. The viscosity of PP/PPS composites is nearly independent of the PPS concentration at 270°С and 280°С , respectively. However, the contents of PPS have an influence on shear viscosity of the PP/PPS at 290С and 300°С . The DSC results exhibit that the crystallization temperatures (TC) of PP in the composites are higher than that of the pure PP, and the TCof PP increases slightly with increasing PP content in the composites. Moreover, the melting temperature of PPS in the composites decreases slightly with increasing PP content.


2012 ◽  
Vol 550-553 ◽  
pp. 1513-1521
Author(s):  
Sirirat Thothong ◽  
Klanarong Sriroth ◽  
Rattana Tantatherdtam ◽  
Amnat Jarerat

To improve the miscibility of native rice starch granules and poly(butylene adipate-co-terephthalate)(PBAT), rice starch was hydrolyzed by a mixture of α-amylase and amyloglucosidase. The obtained porous rice granular starch was then mechanically blended with PBAT by single screw extruder. Many pits and holes on the surface of starch granules were observed by scanning electron microscopy (SEM). The rough surface of the rice starch granules improved the compatibility of the polymers in the blends, which consequently increased the tensile strength and the elongation at break. In addition, SEM also revealed that the porous granules were homogeneously distributed in the polymer matrix with no appearance of gaps.


2018 ◽  
Vol 204 ◽  
pp. 00008
Author(s):  
Heru Suryanto ◽  
Alfian Widi Rahmawan ◽  
Solichin ◽  
Sahana Rizki Tata ◽  
Uun Yanuhar

The development of materials engineering has led to many significant discoveries one of which is biocomposite with its diverse applications. The addition of reinforcing materials in biopolymers improves the composite properties. This study aimed at investigating the effect of adding nanoclay on the tensile strength, morphology, functional group, and structure of extruded biocomposites with cassava starch matrix. This experimental research involved different concentrations of nanoclay i.e. 0%, 2.5%, 5%, 7.5%. The extrusion process was performed using a single screw extruder at 120°C. The samples were characterized by tensile testing, XRD, and SEM. The biocomposite reinforced with 5% nanoclay had the highest tensile strength of 10.8 MPa. The highest diffraction peak at 2θ of 19.4° appeared in the sample added with 5% nanoclay. The addition of excessive amounts of nanoclay can hinder the formation of exfoliated structures.


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