Polymer nanocomposites with improved mechanical and thermal properties by magnetically aligned carbon nanotubes

Polymer ◽  
2019 ◽  
Vol 166 ◽  
pp. 81-87 ◽  
Author(s):  
Mingrui Liu ◽  
Hammad Younes ◽  
Haiping Hong ◽  
G.P. Peterson
Keyword(s):  
Carbon Nanotubes ◽  
Thermal Properties ◽  
Polymer Nanocomposites ◽  
Mechanical And Thermal Properties ◽  
Aligned Carbon Nanotubes ◽  
Magnetically Aligned

COMPUTATIONAL DESCRIPTION OF THE GEOMETRY OF ALIGNED CARBON NANOTUBES IN POLYMER NANOCOMPOSITES

2021 ◽  
Author(s):  
STEPAN V. LOMOV ◽  
JEONYOON LEEJEONYOON LEE ◽  
BRIAN L. WARDLE ◽  
NIKITA A. GUDKOV ◽  
ISKANDER S. AKHATOV ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Polymer Nanocomposites ◽  
Finite Element Modelling ◽  
Volume Fraction ◽  
Voronoi Tessellation ◽  
Geometrical Model ◽  
Limiting Factor ◽  
Full Paper ◽  
Aligned Carbon Nanotubes ◽  
Curvature And Torsion

The paper considers nanocomposites, reinforced with aligned carbon nanotubes (A- CNTs). Nominally aligned, the CNTs in the forest are wavy, which has important consequences in downgraded mechanical properties, and influences electric and thermal performance. The most detailed geometrical model of A-CNTs was proposed by Stein and Wardle (Nanotechnology, 27:035701, 2015). It creates a centerline trajectory of a CNT in steps, each step defining a section of the CNT, growing in the alignment direction with certain deviations. The paper, starting from this framework, formulates a model of the CNT geometry, which is based on the concept of correlation length of the CNT waviness and maximum admissible CNT curvature and torsion. The value of the maximum curvature can be linked to the buckling criteria for CNTs, or derived from ab initio and finite element modelling. It is used as a limiting factor for the growth, defining the waviness and tortuosity of the CNTs. The CNTs in the forest are placed in a random non-regular way, using Voronoi tessellation. The full paper includes investigation of the proposed algorithm for several values of the CNT volume fraction (in the range 0.5%…8%), the dependency of the modelled geometry on the curvature, and the apparent twist of the CNT centerlines. The modelling results are compared with experimental observations in 3D TEM imaging.

Irradiation of poly(l-lactide) biopolymer reinforced with functionalized MWCNTs

RSC Advances ◽  
2015 ◽  
Vol 5 (68) ◽  
pp. 55544-55549 ◽  
Author(s):  
Ali Nabipour Chakoli ◽  
Jinmei He ◽  
Maryam Amirian Chayjan ◽  
Yudong Huang ◽  
Baode Zhang
Keyword(s):  
Carbon Nanotubes ◽  
Thermal Properties ◽  
Melting Point ◽  
Irradiation Effect ◽  
Mechanical And Thermal Properties ◽  
Functionalized Carbon Nanotubes ◽  
Functionalized Mwcnts

The γirradiation increases the modulus and strength, decreases the melting point of poly(l-lactide) during sterilization. The functionalized carbon nanotubes accelerate the irradiation effect on mechanical and thermal properties of poly(l-lactide).

Mechanical and thermal properties of polyoxymethylene-matrix composites filled with multi-walled carbon nanotubes-coated milled glass fiber

2019 ◽  
Vol 54 (15) ◽  
pp. 1961-1976
Author(s):  
Xu Xiangmin ◽  
Hongxiang Zhang ◽  
Tong Beibei ◽  
Li Binjie ◽  
Yudong Zhang
Keyword(s):  
Carbon Nanotubes ◽  
Thermal Stability ◽  
Thermal Properties ◽  
Electron Microscope ◽  
Glass Fiber ◽  
Crystallization Temperature ◽  
High Performance ◽  
Multiwall Carbon Nanotubes ◽  
Fiber Surface ◽  
Mechanical And Thermal Properties

The advanced multifunctional filler has become one of the main challenges in developing high-performance polymer composites. In this study, the acid-treated multiwall carbon nanotubes (MWCNTs) were adhered to the surface of milled glass fiber under the combined effect of 3-aminopropyltriethyloxy silane and tetraethyl orthosilicate to fabricate a hierarchical fiber (MWCNTs-MGF). The morphologies of the hierarchical fibers were characterized using field-emission scanning electron microscope and transmission electron microscope, which showed evidence of a coating layer of MWCNTs on each fiber surface. The MWCNTs-MGF was employed as a multifunctional filler to prepare polyoxymethylene-based composites using a twin-screw extruder by melt blending. The obtained composites exhibited improved mechanical and thermal properties. The composite tensile strength and notched impact strength and Young's modulus increased by 10%, 32%, and 32%, respectively, as the MWCNTs-MGF content varies from 0 to 10 wt.%. Meanwhile, the reinforcing and toughing mechanisms of MWCNTs-MGF were also elaborated by analyzing the interfacial adhesion and fracture morphologies of the composites. Moreover, the study on thermal stability and crystallization behavior indicated that the polyoxymethylene/MWCNTs-MGF composites had higher thermal stability, crystallization temperature, and crystallinity as compared to the polymer matrix. The improvement of thermal stability originates from the unique surface structure of MWCNTs-MGF, while the increase in crystallization temperature and crystallinity is due to the strong heterogeneous nucleation ability of the hierarchical fibers.

In-situ probing the electrical, mechanical, and thermal properties of individual carbon nanotubes and nanowires by using a TEM-SPM platform

2008 ◽  
Vol 14 (S2) ◽  
pp. 398-399
Author(s):  
J-Y Huang
Keyword(s):  
Carbon Nanotubes ◽  
Thermal Properties ◽  
New Mexico ◽  
Mechanical And Thermal Properties

Extended abstract of a paper presented at Microscopy and Microanalysis 2008 in Albuquerque, New Mexico, USA, August 3 – August 7, 2008

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